A route to explain water anomalies from results on an aqueous solution of salt

In this paper we investigate the possibility to detect the hypothesized liquid-liquid critical point of water in supercooled aqueous solutions of salts. Molecular dynamics computer simulations are conducted on bulk TIP4P water and on an aqueous solution of sodium chloride in TIP4P water, with concentration c = 0.67 mol/kg. The liquid-liquid critical point is found both in the bulk and in the solution. Its position in the thermodynamic plane shifts to higher temperature and lower pressure for the solution. Comparison with available experimental data allowed us to produce the phase diagrams of both bulk water and the aqueous solution as measurable in experiments. Given the position of the liquid-liquid critical point in the solution as obtained from our simulations, the experimental determination of the hypothesized liquid-liquid critical point of water in aqueous solutions of salts appears possible.Comment: 5 pages, 6 figures. Accepted for publication on the Journal of Chemical Physics (2010)

Structural Properties of High and Low Density Water in a Supercooled Aqueous Solution of Salt

We consider and compare the structural properties of bulk TIP4P water and of a sodium chloride aqueous solution in TIP4P water with concentration c = 0.67 mol/kg, in the metastable supercooled region. In a previous paper [D. Corradini, M. Rovere and P. Gallo, J. Chem. Phys. 132, 134508 (2010)] we found in both systems the presence of a liquid-liquid critical point (LLCP). The LLCP is believed to be the end point of the coexistence line between a high density liquid (HDL) and a low density liquid (LDL) phase of water. In the present paper we study the different features of water-water structure in HDL and LDL both in bulk water and in the solution. We find that the ions are able to modify the bulk LDL structure, rendering water-water structure more similar to the bulk HDL case. By the study of the hydration structure in HDL and LDL, a possible mechanism for the modification of the bulk LDL structure in the solution is identified in the substitution of the oxygen by the chloride ion in oxygen coordination shells.Comment: 10 pages, 10 figures, 2 tables. Accepted for publication on J. Phys. Chem

Hierarchical models for service-oriented systems

We present our approach to the denotation and representation of hierarchical graphs: a suitable algebra of hierarchical graphs and two domains of interpretations. Each domain of interpretation focuses on a particular perspective of the graph hierarchy: the top view (nested boxes) is based on a notion of embedded graphs while the side view (tree hierarchy) is based on gs-graphs. Our algebra can be understood as a high-level language for describing such graphical models, which are well suited for defining graphical representations of service-oriented systems where nesting (e.g. sessions, transactions, locations) and linking (e.g. shared channels, resources, names) are key aspects

Topological properties of the bond-modulated honeycomb lattice

We study the combined effects of lattice deformation, e-e interaction and spin-orbit coupling in a two-dimensional (2D) honeycomb lattice. We adopt different kinds of hopping modulation--generalized dimerization and a Kekule distortion--and calculate topological invariants for the non-interacting system and for the interacting system. We identify the parameter range (Hubbard U, hopping modulation, spin-orbit coupling) where the 2D system behaves as a trivial insulator or Quantum Spin Hall Insulator.Comment: 8 pages, 4 figures: discussion improved, typos corrected, references updated. Matches version published in PR

On the low energy limit of one loop photon-graviton amplitudes

We present first results of a systematic study of the structure of the low energy limit of the one-loop photon-graviton amplitudes induced by massive scalars and spinors. Our main objective is the search of KLT-type relations where effectively two photons merge into a graviton. We find such a relation at the graviton-photon-photon level. We also derive the diffeomorphism Ward identity for the 1PI one graviton - N photon amplitudes.Comment: 14 pages, 1 figure. Final version to be published in Physics Letters

Dwelling or duelling in possibilities: how (Ir)relevant are African feminisms?

In its four decades of rebirth, the world has debated (enough) the relevance of feminism, but there is, surprisingly, refreshingly emergent dimensions at the turn of the twenty-first century: feminisms from feminism flowing from Africa. The theories or models of Womanism, Stiwanism, Motherism, and Nego-feminism, with their underlying assumptions and values,were all born at various end times of the twentieth century with a common objective of seeking gender justice. This paper examines the crucial question of how relevant these models are to the global practice of woman as human. What propels their separateness, and why didn‘t they combine to make a more solid stance on the plight of the African woman? In fact, why can‘t they simply identify with the general feminism? Put differently, are they dwelling in the same terrain or are they separable and easily recognisable discourses duelling in possibilities for the woman in Africa in particular and the woman of the globe in general? More specifically, how (ir)relevant are African feminisms?In trying to answer these questions, the paper presents a critical review of the afore-mentioned theories of African feminisms with the goal of providing readers an understanding of what is new in each model, and what is similar or different between the various strands of African feminisms. The paper concludes with the author‘s analysis of the model that holds the best promise or possibilities for African feminism to achieve its seemingly elusive goal of gender equality

Topological invariants in interacting Quantum Spin Hall: a Cluster Perturbation Theory approach

Using Cluster Perturbation Theory we calculate Green's functions, quasi-particle energies and topological invariants for interacting electrons on a 2-D honeycomb lattice, with intrinsic spin-orbit coupling and on-site e-e interaction. This allows to define the parameter range (Hubbard U vs spin-orbit coupling) where the 2D system behaves as a trivial insulator or Quantum Spin Hall insulator. This behavior is confirmed by the existence of gapless quasi-particle states in honeycomb ribbons. We have discussed the importance of the cluster symmetry and the effects of the lack of full translation symmetry typical of CPT and of most Quantum Cluster approaches. Comments on the limits of applicability of the method are also provided.Comment: 7 pages, 7 figures: discussion improved, one figure added, references updated. Matches version published in New J. Phy

Kinematic and Dynamic Study of Cam Mechanisms for Bottling Machines

The main objective of this study is to analyze and optimize the cam mechanisms of the cork capper station currently in use for wine bottling machines. For each machine model considered, current cam profiles and corresponding real trajectories performed during operation are analyzed. Subsequently, various alternative laws of motion are tested to implement the same process, respecting the same precision points but modifying other parts of trajectory to improve machine dynamic performances. A series of tests carried out on a reconfigurable prototype and using different types of cork have made it possible to verify the effectiveness of the new laws of motion and to obtain the load acting on the machine at different operating speeds