272 research outputs found
N=4 supersymmetric Eguchi-Hanson sigma model in d=1
We show that it is possible to construct a supersymmetric mechanics with four
supercharges possessing not conformally flat target space. A general idea of
constructing such models is presented. A particular case with Eguchi--Hanson
target space is investigated in details: we present the standard and quotient
approaches to get the Eguchi--Hanson model, demonstrate their equivalence, give
a full set of nonlinear constraints, study their properties and give an
explicit expression for the target space metric.Comment: LaTeX, 9 page
The Void Abundance with Non-Gaussian Primordial Perturbations
We use a Press-Schechter-like calculation to study how the abundance of voids
changes in models with non-Gaussian initial conditions. While a positive
skewness increases the cluster abundance, a negative skewness does the same for
the void abundance. We determine the dependence of the void abundance on the
non-Gaussianity parameter fnl for the local-model bispectrum-which approximates
the bispectrum in some multi-field inflation models-and for the equilateral
bispectrum, which approximates the bispectrum in e.g. string-inspired DBI
models of inflation. We show that the void abundance in large-scale-structure
surveys currently being considered should probe values as small as fnl < 10 and
fnl^eq < 30, over distance scales ~10 Mpc.Comment: Submitted to JCA
Syntheses, X-ray structures and characterisation of luminescent chromium(III) complexes incorporating 8-quinolinato ligands
A series of six coordinate homoleptic and heteroleptic Cr(III) complexes have been formed that incorporate 8-quinolinato ligands. Three classes of complex have been synthesised and characterised: (i) [Cr(Q)3]; (ii) [Cr(Q)2(H2O)2]Cl; (iii) [Cr(Q)(N^N)2](PF6)2 (where Q is a ligand, 8-hydroxyquinoline, 8-hydroxy-2-methyl-quinoline, or 8-hydroxy-5-nitroquinoline; N^N = 1,10-phenanthroline or 2,2′-bipyridine). Single crystal X-ray structures were obtained for four complexes giving examples of [Cr(Q)2(H2O)2]Cl, two [Cr(Q)(bipy)2](PF6)2 and [Cr(Q)(phen)2](PF6)2. Each complex shows the ligands in the expected coordination mode with a distorted octahedral geometry evident at the metal centre. The UV–Vis. absorption data allowed assignments of the quinolinato-centred electronic transitions together with a much weaker spin allowed d–d transition (4A2 → 4T2) around 550 nm. Each complex was found to be luminescent in aerated MeCN solution at room temperature, which was attributed to a ligand-centred fluorescence based on the coordinated quinolinato ligand
Aryl, bi-functionalised imidazo[4,5-f]-1,10-phenanthroline ligands and their luminescent rhenium(I) complexes
Five new imidazo[4,5-f]-1,10-phenanthroline based ligands (1–5) have been synthesised and characterised. The facile synthesis of 1–5 allows two regiochemical points of structural variety allowing highly conjugated and bulky aryl groups of varying functionalities, including azobenzene, trityl and terpyridine constituents, to be attached to the ligand core. 1–5 are fluorescent (λem = 410–415 nm), and react readily with [ReBr(CO)5] in toluene to give neutral coordination complexes of the form fac-[ReBr(CO)3(1–5)]. The series of complexes was characterised using a variety of spectroscopic and analytical techniques. Two examples of this series were characterised in the solid state using single crystal X-ray diffraction which confirmed the octahedral geometry and formulation. Photophysical studies showed that fac-[ReBr(CO)3(1–5)] are phosphorescent in solution under ambient conditions, revealing visible emission (558–585 nm) in aerated solution with corresponding lifetimes in the range 149–267 ns. These attributes are consistent with a triplet metal to ligand charge transfer (3MLCT) emitting state
Erasmus Language students in a British University – a case study
Students’ assessment of their academic experience is actively sought by Higher Education institutions, as evidenced in the National Student Survey introduced in 2005. Erasmus students, despite their growing numbers, tend to be excluded from these satisfaction surveys, even though they, too, are primary customers of a University. This study aims to present results from bespoke questionnaires and semi-structured interviews with a sample of Erasmus students studying languages in a British University. These methods allow us insight into the experience of these students and their assessment as a primary customer, with a focus on language learning and teaching, university facilities and student support. It investigates to what extent these factors influence their levels of satisfaction and what costs of adaptation if any, they encounter. Although excellent levels of satisfaction were found, some costs affect their experience. They relate to difficulties in adapting to a learning methodology based on a low number of hours and independent learning and to a guidance and support system seen as too stifling. The results portray this cohort’s British University as a well-equipped and well-meaning but ultimately overbearing institution, which may indicate that minimising costs can eliminate some sources of dissatisfaction
Dual visible/NIR emission from organometallic iridium(III) complexes
A series of four substituted benzo[g]quinoxaline species have been synthesised and utilised as cyclometalating ligands for iridium(III). The ligands (L1-L4) were synthesised and isolated in good yield following the condensation of 2,3-diaminonaphthalene with benzil and three of its derivatives. The substituent modulated electronic properties of L1-L4 were dominated by intraligand π−π* transitions, with the fluorescence profile demonstrating vibronic features attributed to the highly conjugated nature of the chromophore. Iridium(III) complexes of the form [Ir(L)2(bipy)]PF6 were synthesised from L1-L4 in two steps. The electronic properties of the complexes reveal absorption in the UV-vis. region with spin forbidden metal-to-ligand charge transfer (MLCT) transitions possibly contributing at longer wavelengths to ca. 600 nm. Steady state luminescence (aerated, room temperature) on solutions of the complexes showed dual emissive properties in the visible and near-infra red (NIR) regions. Firstly, a vibronically structured emission in the visible region (ca. 525 nm) was attributed to ligand centred fluorescence (lifetime < 10 ns). Secondly, a broad emission peak in the NIR (ca. 950 nm) which extended to around 1200 nm was observed with corresponding lifetimes of 116–162 ns, indicative of triplet excited state emission
Search for supersymmetry with a dominant R-parity violating LQDbar couplings in e+e- collisions at centre-of-mass energies of 130GeV to 172 GeV
A search for pair-production of supersymmetric particles under the assumption
that R-parity is violated via a dominant LQDbar coupling has been performed
using the data collected by ALEPH at centre-of-mass energies of 130-172 GeV.
The observed candidate events in the data are in agreement with the Standard
Model expectation. This result is translated into lower limits on the masses of
charginos, neutralinos, sleptons, sneutrinos and squarks. For instance, for
m_0=500 GeV/c^2 and tan(beta)=sqrt(2) charginos with masses smaller than 81
GeV/c^2 and neutralinos with masses smaller than 29 GeV/c^2 are excluded at the
95% confidence level for any generation structure of the LQDbar coupling.Comment: 32 pages, 30 figure
Detector Description and Performance for the First Coincidence Observations between LIGO and GEO
For 17 days in August and September 2002, the LIGO and GEO interferometer
gravitational wave detectors were operated in coincidence to produce their
first data for scientific analysis. Although the detectors were still far from
their design sensitivity levels, the data can be used to place better upper
limits on the flux of gravitational waves incident on the earth than previous
direct measurements. This paper describes the instruments and the data in some
detail, as a companion to analysis papers based on the first data.Comment: 41 pages, 9 figures 17 Sept 03: author list amended, minor editorial
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Separating the Early Universe from the Late Universe: cosmological parameter estimation beyond the black box
We present a method for measuring the cosmic matter budget without
assumptions about speculative Early Universe physics, and for measuring the
primordial power spectrum P*(k) non-parametrically, either by combining CMB and
LSS information or by using CMB polarization. Our method complements currently
fashionable ``black box'' cosmological parameter analysis, constraining
cosmological models in a more physically intuitive fashion by mapping
measurements of CMB, weak lensing and cluster abundance into k-space, where
they can be directly compared with each other and with galaxy and Lyman alpha
forest clustering. Including the new CBI results, we find that CMB measurements
of P(k) overlap with those from 2dF galaxy clustering by over an order of
magnitude in scale, and even overlap with weak lensing measurements. We
describe how our approach can be used to raise the ambition level beyond
cosmological parameter fitting as data improves, testing rather than assuming
the underlying physics.Comment: Replaced to match accepted PRD version. Refs added. Combined CMB data
and window functions at http://www.hep.upenn.edu/~max/pwindows.html or from
[email protected]. 18 figs, 19 journal page
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