1,036 research outputs found
Dielectric spectra analysis: reliable parameter estimation using interval analysis
Dielectric spectroscopy is an extremely versatile method for characterizing the molecular dynamics over a large range of time scales. Unfortunately, the extraction of model parameters by data fitting is still a crucial problem which is now solved by our program S.A.D.E. S.A.D.E. is based on the algorithm S.I.V.I.A. which was proposed and implemented by Jaulin in order to solve constraint satisfaction problems. The problem of dielectric data analysis is reduced to a problem of choosing the appropriate physical model. In this article, Debye relaxations were used and validated to fit the relaxations of a DGEBA prepolymer and the polarization of the spectrometer electrodes. The conductivity was evaluated too
SyPRID sampler: A large-volume, high-resolution, autonomous, deep-ocean precision plankton sampling system
AbstractThe current standard for large-volume (thousands of cubic meters) zooplankton sampling in the deep sea is the MOCNESS, a system of multiple opening–closing nets, typically lowered to within 50m of the seabed and towed obliquely to the surface to obtain low-spatial-resolution samples that integrate across 10s of meters of water depth. The SyPRID (Sentry Precision Robotic Impeller Driven) sampler is an innovative, deep-rated (6000m) plankton sampler that partners with the Sentry Autonomous Underwater Vehicle (AUV) to obtain paired, large-volume plankton samples at specified depths and survey lines to within 1.5m of the seabed and with simultaneous collection of sensor data. SyPRID uses a perforated Ultra-High-Molecular-Weight (UHMW) plastic tube to support a fine mesh net within an outer carbon composite tube (tube-within-a-tube design), with an axial flow pump located aft of the capture filter. The pump facilitates flow through the system and reduces or possibly eliminates the bow wave at the mouth opening. The cod end, a hollow truncated cone, is also made of UHMW plastic and includes a collection volume designed to provide an area where zooplankton can collect, out of the high flow region. SyPRID attaches as a saddle-pack to the Sentry vehicle. Sentry itself is configured with a flight control system that enables autonomous survey paths to low altitudes. In its verification deployment at the Blake Ridge Seep (2160m) on the US Atlantic Margin, SyPRID was operated for 6h at an altitude of 5m. It recovered plankton samples, including delicate living larvae, from the near-bottom stratum that is seldom sampled by a typical MOCNESS tow. The prototype SyPRID and its next generations will enable studies of plankton or other particulate distributions associated with localized physico-chemical strata in the water column or above patchy habitats on the seafloor
Rediscovering hermaphroditism in Grammatidae with the description of the testicular gland in Brazilian Basslet Gramma brasiliensis
To wet or not to wet: that is the question
Wetting transitions have been predicted and observed to occur for various
combinations of fluids and surfaces. This paper describes the origin of such
transitions, for liquid films on solid surfaces, in terms of the gas-surface
interaction potentials V(r), which depend on the specific adsorption system.
The transitions of light inert gases and H2 molecules on alkali metal surfaces
have been explored extensively and are relatively well understood in terms of
the least attractive adsorption interactions in nature. Much less thoroughly
investigated are wetting transitions of Hg, water, heavy inert gases and other
molecular films. The basic idea is that nonwetting occurs, for energetic
reasons, if the adsorption potential's well-depth D is smaller than, or
comparable to, the well-depth of the adsorbate-adsorbate mutual interaction. At
the wetting temperature, Tw, the transition to wetting occurs, for entropic
reasons, when the liquid's surface tension is sufficiently small that the free
energy cost in forming a thick film is sufficiently compensated by the fluid-
surface interaction energy. Guidelines useful for exploring wetting transitions
of other systems are analyzed, in terms of generic criteria involving the
"simple model", which yields results in terms of gas-surface interaction
parameters and thermodynamic properties of the bulk adsorbate.Comment: Article accepted for publication in J. Low Temp. Phy
Magnetic fields and Sunyaev-Zel'dovich effect in galaxy clusters
In this work we study the contribution of magnetic fields to the Sunyaev
Zeldovich (SZ) effect in the intracluster medium. In particular we calculate
the SZ angular power spectrum and the central temperature decrement. The effect
of magnetic fields is included in the hydrostatic equilibrium equation by
splitting the Lorentz force into two terms one being the force due to magnetic
pressure which acts outwards and the other being magnetic tension which acts
inwards. A perturbative approach is adopted to solve for the gas density
profile for weak magnetic fields (< 4 micro G}). This leads to an enhancement
of the gas density in the central regions for nearly radial magnetic field
configurations. Previous works had considered the force due to magnetic
pressure alone which is the case only for a special set of field
configurations. However, we see that there exists possible sets of
configurations of ICM magnetic fields where the force due to magnetic tension
will dominate. Subsequently, this effect is extrapolated for typical field
strengths (~ 10 micro G) and scaling arguments are used to estimate the angular
power due to secondary anisotropies at cluster scales. In particular we find
that it is possible to explain the excess power reported by CMB experiments
like CBI, BIMA, ACBAR at l > 2000 with sigma_8 ~ 0.8 (WMAP 5 year data) for
typical cluster magnetic fields. In addition we also see that the magnetic
field effect on the SZ temperature decrement is more pronounced for low mass
clusters ( ~ 2 keV). Future SZ detections of low mass clusters at few arc
second resolution will be able to probe this effect more precisely. Thus, it
will be instructive to explore the implications of this model in greater detail
in future works.Comment: 20 pages, 8 figure
Threshold criterion for wetting at the triple point
Grand canonical simulations are used to calculate adsorption isotherms of
various classical gases on alkali metal and Mg surfaces. Ab initio adsorption
potentials and Lennard-Jones gas-gas interactions are used. Depending on the
system, the resulting behavior can be nonwetting for all temperatures studied,
complete wetting, or (in the intermediate case) exhibit a wetting transition.
An unusual variety of wetting transitions at the triple point is found in the
case of a specific adsorption potential of intermediate strength. The general
threshold for wetting near the triple point is found to be close to that
predicted with a heuristic model of Cheng et al. This same conclusion was drawn
in a recent experimental and simulation study of Ar on CO_2 by Mistura et al.
These results imply that a dimensionless wetting parameter w is useful for
predicting whether wetting behavior is present at and above the triple
temperature. The nonwetting/wetting crossover value found here is w circa 3.3.Comment: 15 pages, 8 figure
Some remarks on the dynamical systems approach to fourth order gravity
Building on earlier work, we discuss a general framework for exploring the
cosmological dynamics of Higher Order Theories of Gravity. We show that once
the theory of gravity has been specified, the cosmological equations can be
written as a first-order autonomous system and we give several examples which
illustrate the utility of our method. We also discuss a number of results which
have appeared recently in the literature.Comment: 19 pages, LaTe
Vitamin D binding protein genotype is associated with plasma 25OHD concentration in West African children
Vitamin D is well known for its role in promoting skeletal health. Vitamin D status is determined conventionally by circulating 25-dihydroxyvitamin D (25OHD) concentration. There is evidence indicating that circulating 25OHD concentration is affected by variation in Gc, the gene encoding the vitamin D binding protein (DBP). The composite genotype of two single nucleotide polymorphisms (rs7041 and rs4588) results in different DBP isotypes (Gc1f, Gc1s and Gc2). The protein configurational differences among DBP isotypes affect DBP substrate binding affinity. The aims of this study were to determine 1) Gc variant frequencies in a population from an isolated rural region of The Gambia, West Africa (n=3129) with year-round opportunity for cutaneous vitamin D synthesis and 2) the effects of Gc variants on 25OHD concentration (n=237) in a genetically representative sub-group of children (mean (SD) age: 11.9 (4.8) years). The distribution of Gc variants was Gc1f: 0.86, Gc1s: 0.11 and Gc2: 0.03. The mean (SD) concentration of 25OHD was 59.6 (12.9) nmol/L and was significantly higher in those homozygous for Gc1f compared to other Gc variants (60.7 (13.1) vs. 56.6 (12.1) nmol/L, P=0.03). Plasma 25OHD and 1,25(OH)2D concentration was significantly associated with parathyroid hormone in Gc1f-1f but not in the other Gc variants combined. This study demonstrates that different Gc variants are associated with different 25OHD concentrations in a rural Gambian population. Gc1f-1f, thought to have the highest affinity for 25OHD, had the highest 25OHD concentration compared with lower affinity Gc variants. The considerable difference in Gc1f frequency observed in Gambians compared with other non-West African populations and associated differences in plasma 25OHD concentration, may have implications for the way in which vitamin D status should be interpreted across different ancestral groups
The glassy response of solid He-4 to torsional oscillations
We calculated the glassy response of solid He-4 to torsional oscillations
assuming a phenomenological glass model. Making only a few assumptions about
the distribution of glassy relaxation times in a small subsystem of otherwise
rigid solid He-4, we can account for the magnitude of the observed period shift
and concomitant dissipation peak in several torsion oscillator experiments. The
implications of the glass model for solid He-4 are threefold: (1) The dynamics
of solid He-4 is governed by glassy relaxation processes. (2) The distribution
of relaxation times varies significantly between different torsion oscillator
experiments. (3) The mechanical response of a torsion oscillator does not
require a supersolid component to account for the observed anomaly at low
temperatures, though we cannot rule out its existence.Comment: 9 pages, 4 figures, presented at QFS200
Electrode Polarization Effects in Broadband Dielectric Spectroscopy
In the present work, we provide broadband dielectric spectra showing strong
electrode polarization effects for various materials, belonging to very
different material classes. This includes both ionic and electronic conductors
as, e.g., salt solutions, ionic liquids, human blood, and
colossal-dielectric-constant materials. These data are intended to provide a
broad data base enabling a critical test of the validity of phenomenological
and microscopic models for electrode polarization. In the present work, the
results are analyzed using a simple phenomenological equivalent-circuit
description, involving a distributed parallel RC circuit element for the
modeling of the weakly conducting regions close to the electrodes. Excellent
fits of the experimental data are achieved in this way, demonstrating the
universal applicability of this approach. In the investigated ionically
conducting materials, we find the universal appearance of a second dispersion
region due to electrode polarization, which is only revealed if measuring down
to sufficiently low frequencies. This indicates the presence of a second
charge-transport process in ionic conductors with blocking electrodes.Comment: 9 pages, 6 figures, experimental data are provided in electronic form
(see "Data Conservancy"
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