Shock wave study and theoretical modeling of the thermal decomposition of c-C4F8

The thermal dissociation of octafluorocyclobutane, c-C4F8, was studied in shock waves over the range 1150-2300 K by recording UV absorption signals of CF2. It was found that the primary reaction nearly exclusively produces 2 C2F4 which afterwards decomposes to 4 CF2. A primary reaction leading to CF2 + C3F6 is not detected (an upper limit to the yield of the latter channel was found to be about 10 percent). The temperature range of earlier single pulse shock wave experiments was extended. The reaction was shown to be close to its high pressure limit. Combining high and low temperature results leads to a rate constant for the primary dissociation of k1 = 1015.97 exp(-310.5 kJ mol-1/RT) s-1 in the range 630-1330 K, over which k1 varies over nearly 14 orders of magnitude. Calculations of the energetics of the reaction pathway and the rate constants support the conclusions from the experiments. Also they shed light on the role of the 1,4-biradical CF2CF2CF2CF2 as an intermediate of the reaction.Fil: Cobos, Carlos Jorge. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas; ArgentinaFil: Hintzer, K.. Dyneon Gmbh; AlemaniaFil: Sölter, L.. Universität Göttingen; AlemaniaFil: Tellbach, E.. Universität Göttingen; AlemaniaFil: Thaler, A.. Dyneon Gmbh; AlemaniaFil: Troe, J.. Universität Göttingen; Alemania. Max-Planck-Institut fu¨r biophysikalische Chemie; Alemani

Notas corológicas de la provincia de Jaén. III. "Juncaceae"

Se presenta un catálogo de las especies de la familia Juncaceae existentes en la provincia de Jaén (España), que incluye 21 táxones, 6 de los cuales son primera cita provincial.In this paper we present a catalogue of Juncaceae species from the province of Jaén (S. E. Spain) wich includes 21 taxa, 6 are new in the zone

η\eta and η′\eta' mesons in nuclear matter and nuclei

We present updated and extended results for the $\eta$- and $\eta'$-nucleus bound state energies, obtained by solving the Schr\"{o}dinger and Klein-Gordon equations with complex optical potentials, for a wide range of nuclei. The $\eta$ and $\eta'$ nuclear potentials are obtained in the local density approximation from the mass shift of these mesons in nuclear matter, which is calculated within the quark-meson coupling model. Our results show that the $\eta$ and $\eta'$ mesons are expected to form mesic nuclei with all the nuclei considered. However, the signal for the formation of the $\eta$- and $\eta'$-mesic nuclei may be difficult to identify experimentally due to possible large widths.Comment: 11 pages, 4 figures, 6 table