Characterization of Iridium Coated Rhenium Used in High-Temperature, Radiation-Cooled Rocket Thrusters

Materials used for radiation-cooled rocket thrusters must be capable of surviving under extreme conditions of high-temperatures and oxidizing environments. While combustion efficiency is optimized at high temperatures, many refractory metals are unsuitable for thruster applications due to rapid material loss from the formation of volatile oxides. This process occurs during thruster operation by reaction of the combustion products with the material surface. Aerojet Technical Systems has developed a thruster cone chamber constructed of Re coated with Ir on the inside surface where exposure to the rocket exhaust occurs. Re maintains its structural integrity at high temperature and the Ir coating is applied as an oxidation barrier. Ir also forms volatile oxide species (IrO2 and IrO3) but at a considerably slower rate than Re. In order to understand the performance limits of Ir-coated Re thrusters, we are investigating the interdiffusion and oxidation kinetics of Ir/Re. The formation of iridium and rhenium oxides has been monitored in situ by Raman spectroscopy during high temperature exposure to oxygen. For pure Ir, the growth of oxide films as thin as approximately 200 A could be easily detected and the formation of IrO2 was observed at temperatures as low as 600 C. Ir/Re diffusion test specimens were prepared by magnetron sputtering of Ir on Re substrates. Concentration profiles were determined by sputter Auger depth profiles of the heat treated specimens. Significant interdiffusion was observed at temperatures as low as 1000 C. Measurements of the activation energy suggest that below 1350 C, the dominant diffusion path is along defects, most likely grain boundaries, rather than bulk diffusion through the grains. The phases that form during interdiffusion have been examined by x ray diffraction. Analysis of heated test specimens indicates that the Ir-Re reaction produces a solid solution phase of Ir dissolved in the HCP structure of Re

Chemical weathering and provenance evolution of Holocene–Recent sediments from the Western Indus Shelf, Northern Arabian Sea inferred from physical and mineralogical properties

We present a multi-proxy mineral record based on X-ray diffraction and diffuse reflectance spectrophotometry analysis for two cores from the western Indus Shelf in order to reconstruct changing weathering intensities, sediment transport, and provenance variations since 13 ka. Core Indus-10 is located northwest of the Indus Canyon and exhibits fluctuations in smectite/(illite + chlorite) ratios that correlate with monsoon intensity. Higher smectite/(illite + chlorite) and lower illite crystallinity, normally associated with stronger weathering, peaked during the Early–Mid Holocene, the period of maximum summer monsoon. Hematite/goethite and magnetic susceptibility do not show clear co-variation, although they both increase at Indus-10 after 10 ka, as the monsoon weakened. At Indus-23, located on a clinoform just west of the canyon, hematite/goethite increased during a period of monsoon strengthening from 10 to 8 ka, consistent with increased seasonality and/or reworking of sediment deposited prior to or during the glacial maximum. After 2 ka terrigenous sediment accumulation rates in both cores increased together with redness and hematite/goethite, which we attribute to widespread cultivation of the floodplain triggering reworking, especially after 200 years ago. Over Holocene timescales sediment composition and mineralogy in two localities on the high-energy shelf were controlled by varying degrees of reworking, as well as climatically modulated chemical weathering

Tawney and the third way

From the 1920s to the 1950s R. H. Tawney was the most influential socialist thinker in Britain. He articulated an ethical socialism at odds with powerful statist and mechanistic traditions in British socialist thinking. Tawney's work is thus an important antecedent to third way thinking. Tawney's religiously-based critique of the morality of capitalism was combined with a concern for detailed institutional reform, challenging simple dichotomies between public and private ownership. He began a debate about democratizing the enterprise and corporate governance though his efforts fell on stony ground. Conversely, Tawney's moralism informed a whole-hearted condemnation of market forces in tension with both his concern with institutional reform and modern third way thought. Unfortunately, he refused to engage seriously with emergent welfare economics which for many social democrats promised a more nuanced understanding of the limits of market forces. Tawney's legacy is a complex one, whose various elements form a vital part of the intellectual background to current third way thinking

Flysch deposition and preservation of coherent bedding in an accretionary complex: Detrital zircon ages from the Upper Cretaceous Valdez Group, Chugach terrane, Alaska

The Upper Cretaceous Valdez Group represents the flysch facies of the Mesozoic Chugach terrane accretionary complex in southern Alaska. The Valdez Group is dominated by litharenite sandstone and argillite deposited as coherent beds, unlike the older McHugh Complex mélange and massive sandstones. Detrital zircons from five sandstones sampled along an ~55 km transect through the Valdez Group were dated using U-Pb laser ablation-multicollector-inductively coupled plasma-mass spectrometry (LA-MC-ICP-MS). The youngest populations from the two oldest samples, located along strike from each other, were 82-81 Ma. Three samples across strike and outboard of the others are separated by ~50 km, but each has a youngest population dated at ca. 68 Ma. All of these samples have major grain population ages that suggest erosion from the Coast Mountains Batholith, consistent with petrography and grain modes suggesting an arc source. No apparent age gap exists between the youngest McHugh Complex samples and the oldest Valdez Group samples, suggesting continuous deposition despite the different depositional and tectonic style. We propose a model in which the onset of coherently bedded flysch marks the transition from deposition in the trench or trench slope to deposition on the oceanic plate beyond the trench after it was filled at ca. 84 Ma, i.e., the time of the youngest mélange sedimentation. Preservation of coherent bedding resulted as large coherent blocks of Valdez Group rocks were imbricated into the subduction complex during continued subduction in Paleogene time. © 2011 Geological Society of America

A detailed geochemical study of island arc crust : the Talkeetna Arc section, south–central Alaska

Author Posting. © The Author, 2006. This is the author's version of the work. It is posted here by permission of Oxford University Press for personal use, not for redistribution. The definitive version was published in Journal of Petrology 47 (2006): 1051-1093, doi:10.1093/petrology/egl002.The Early to Middle Jurassic Talkeetna Arc section exposed in the Chugach Mountains of south central Alaska is 5-18 km wide and extends for over 150 km. This accreted island arc includes exposures of upper mantle to volcanic upper crust. The section comprises six lithologic units, in order of decreasing depth: (1) residual upper mantle harzburgite (with lesser proportions of dunite); (2) pyroxenite; (3) basal gabbronorite; (4) lower crustal gabbronorite; (5) mid-crustal plutonic rocks; and (6) volcanic rocks. The pyroxenites overlie residual mantle peridotite, with some interfingering of the two along the contact. The basal gabbronorite overlies pyroxenite, again with some interfingering of the two different units along their contact. Lower crustal gabbronorite (≤10 km thick) includes abundant rocks with well developed modal layering. The mid-crustal plutonic rocks include a heterogeneous assemblage of gabbroic rocks, dioritic to tonalitic rocks (30-40% area), and concentrations of mafic dikes and chilled mafic inclusions. The volcanic rocks (~7 km thick) range from basalt to rhyolite. Many of the evolved volcanic compositions are a result of fractional crystallisation processes whose cumulate products are directly observable in the lower crustal gabbronorites. For example, Ti and Eu enrichments in lower crustal gabbronorites are mirrored by Ti and Eu depletions in evolved volcanics. In addition, calculated parental liquids from ion microprobe analyses of clinopyroxene in lower crustal gabbronorites indicate that the clinopyroxenes crystallised in equilibrium with liquids whose compositions were the same as the compositions of volcanic rocks. The compositional variation of the main series of volcanic and chilled mafic rocks can be modeled through fractionation of observed phase compositions and phase proportions in lower crustal gabbronorite (i.e. cumulates). Primary, mantle-derived melts in the Talkeetna Arc underwent fractionation of pyroxenite at the base of the crust. Our calculations suggest that more than 25 wt % of the primary melts crystallised as pyroxenites at the base of the crust. The discrepancy between the observed proportion of pyroxenites (less than 5% of the arc section) and the proportion required by crystal fractionation modeling (more than 25%) may be best understood as the result of gravitational instability, with dense ultramafic cumulates, probably together with dense garnet granulites, foundering into the underlying mantle during the time when the Talkeetna Arc was magmatically active, or in the initial phases of slow cooling (and sub-solidus garnet growth) immediately after the cessation of arc activity.This study was supported by National Science Foundation Grant EAR-9910899

Thermochronology of the modern Indus River bedload: New insight into the controls on the marine stratigraphic record

The Indus River is the only major drainage in the western Himalaya and delivers a long geological record of continental erosion to the Arabian Sea, which may be deciphered and used to reconstruct orogenic growth if the modern bedload can be related to the mountains. In this study we collected thermochronologic data from river sediment collected near the modern delta. U-Pb ages of zircons spanning 3 Gyr show that only ∼5% of the eroding crust has been generated since India-Asia collision. The Greater Himalaya are the major source of zircons, with additional contributions from the Karakoram and Lesser Himalaya. The 39Ar/40Ar dating of muscovites gives ages that cluster between 10 and 25 Ma, differing from those recorded in the Bengal Fan. Biotite ages are generally younger, ranging 0–15 Ma. Modern average exhumation rates are estimated at ∼0.6 km/m.y. or less, and have slowed progressively since the early Miocene (∼20 Ma), although fission track (FT) dating of apatites may indicate a recent moderate acceleration in rates since the Pliocene (∼1.0 km/m.y.) driven by climate change. The 39Ar/40Ar and FT techniques emphasize the dominance of high topography in controlling the erosional flux to the ocean. Localized regions of tectonically driven, very rapid exhumation (e.g., Nanga Parbat, S. Karakoram metamorphic domes) do not dominate the erosional record

Arc–continent collision and the formation of continental crust : a new geochemical and isotopic record from the Ordovician Tyrone Igneous Complex, Ireland

Author Posting. © Geological Society of London, 2009. This is the author's version of the work. It is posted here by permission of Geological Society of London for personal use, not for redistribution. The definitive version was published in Journal of the Geological Society 166 (2009): 485-500, doi:10.1144/0016-76492008-102.Collisions between oceanic island-arc terranes and passive continental margins are thought to have been important in the formation of continental crust throughout much of Earth’s history. Magmatic evolution during this stage of the plate-tectonic cycle is evident in several areas of the Ordovician Grampian-Taconic Orogen, as we demonstrate in the first detailed geochemical study of the Tyrone Igneous Complex, Ireland. New U–Pb zircon dating yields ages of 493 ± 2 Ma from a primitive mafic intrusion, indicating intra-oceanic subduction in Tremadoc time, and 475 ± 10 Ma from a light-rare-earth-element (LREE)-enriched tonalite intrusion that incorporated Laurentian continental material by early Arenig time (Early Ordovician, Stage 2) during arc-continent collision. Notably, LREE enrichment in volcanism and silicic intrusions of the Tyrone Igneous Complex exceeds that of average Dalradian (Laurentian) continental material which would have been thrust under the colliding forearc and potentially recycled into arc magmatism. This implies that crystal fractionation, in addition to magmatic mixing and assimilation, was important to the formation of new crust in the Grampian-Taconic Orogeny. Because similar super-enrichment of orogenic melts occurred elsewhere in the Caledonides in the British Isles and Newfoundland, the addition of new, highly enriched melt to this accreted arc terrane was apparently widespread spatially and temporally. Such super-enrichment of magmatism, especially if accompanied by loss of corresponding lower crustal residues, supports the theory that arc-continent collision plays an important role in altering bulk crustal composition toward typical values for ancient continental crust.This work was supported by the University of Aberdeen. LA-MC-ICPMS dating was conducted at the Arizona LaserChron Center with the assistance of George Gehrels and Victor Valencia and was supported by NSF-EAR 0443387

A systematic quality evaluation and review of nanomaterial genotoxicity studies: a regulatory perspective

The number of publications in the field of nanogenotoxicology and the amount of genotoxicity data on nanomaterials (NMs) in several databases generated by European Union (EU) funded projects have increased during the last decade. In parallel, large research efforts have contributed to both our understanding of key physico-chemical (PC) parameters regarding NM characterization as well as the limitations of toxicological assays originally designed for soluble chemicals. Hence, it is becoming increasingly clear that not all of these data are reliable or relevant from the regulatory perspective. The aim of this systematic review is to investigate the extent of studies on genotoxicity of NMs that can be considered reliable and relevant by current standards and bring focus to what is needed for a study to be useful from the regulatory point of view. Due to the vast number of studies available, we chose to limit our search to two large groups, which have raised substantial interest in recent years: nanofibers (including nanotubes) and metal-containing nanoparticles. Focusing on peer-reviewed publications, we evaluated the completeness of PC characterization of the tested NMs, documentation of the model system, study design, and results according to the quality assessment approach developed in the EU FP-7 GUIDEnano project. Further, building on recently published recommendations for best practices in nanogenotoxicology research, we created a set of criteria that address assay-specific reliability and relevance for risk assessment purposes. Articles were then reviewed, the qualifying publications discussed, and the most common shortcomings in NM genotoxicity studies highlighted. Moreover, several EU projects under the FP7 and H2020 framework set the aim to collectively feed the information they produced into the eNanoMapper database. As a result, and over the years, the eNanoMapper database has been extended with data of various quality depending on the existing knowledge at the time of entry. These activities are highly relevant since negative results are often not published. Here, we have reviewed the NanoInformaTIX instance under the eNanoMapper database, which hosts data from nine EU initiatives. We evaluated the data quality and the feasibility of use of the data from a regulatory perspective for each experimental entry

A combination of surgery, theranostics, and liquid biopsy - a personalised oncologic approach to treatment of patients with advanced metastatic neuroendocrine neoplasms

Rationale: Neuroendocrine neoplasia (NEN) of small bowel (SBNEN) frequently present with metastatic disease. Theranostics (molecular imaging followed by targeting therapy) allow for personalised medicine. Liquid biopsies enable precise identification of residual disease and real-time monitoring of therapeutic response. Our aim was to determine the clinical utility of a combination of surgery, theranostics, and a multigene blood measurement in metastasised SBNEN. Methods: Inclusion criteria were SBNEN, G1/G2 NEN, initial tumour diagnosis, stage IV NEN, positivity on 68Ga somatostatin analogue PET/CT, eligible for surgery, and 177Lu peptide receptor radionuclide therapy (PRRT). Blood samples for NETest were collected longitudinally. Progression-free survival (PFS) and overall survival (OS) were calculated. NETest results were assessed prior to surgery and during clinical follow-up. Results: A surgical cohort of 39 SBNEN patients met eligibility criteria. Thirty-two patients underwent ileal resection and 7 right hemicolectomy. The mean number of 177Lu PRRT cycles was 4. Mortality was nil. Surgical morbidity was 10.3%. Transient grade 1/2 toxicity occurred in 41% (PRRT). NETest scores (n=9 patients) decreased in 100% following treatment and correlated with diminished tumour volume and disease stabilization following surgery and PRRT. Median follow-up: 78 months. Median PFS and OS: 42.7 and 110 months, respectively. Progression-free survival at 1-, 3-, and 5-years was 79.4%, 57.1% and 40.5%, respectively. Overall survival at 1-, 3-, and 5-years was 97.4%, 97.4%, and 94.1%, respectively. Conclusions: Surgery combined with 177Lu PRRT is safe and provides favourable PFS and OS in selected patients with advanced SBNEN. Liquid biopsy (NETest) has the potential to accurately delineate disease status

Seismic volcanostratigraphy of the western Indian rifted margin: The pre-Deccan igneous province

The Indian Plate has been the focus of intensive research concerning the flood basalts of the Deccan Traps. Here we document a volcanostratigraphic analysis of the offshore segment of the western Indian volcanic large igneous province, between the shoreline and the first magnetic anomaly (An 28 ∼63 Ma). We have mapped the different crustal domains of the NW Indian Ocean from stretched continental crust through to oceanic crust, using seismic reflection and potential field data. Two volcanic structures, the Somnath Ridge and the Saurashtra High, are identified, extending ∼305 km NE-SW in length and 155 km NW-SE in width. These show the internal structures of buried shield volcanoes and hyaloclastic mounds, surrounded by mass-wasting deposits and volcanic sediments. The structures observed resemble seismic images from the North Atlantic and northwest Australia, as well as volcanic geometries described for Runion and Hawaii. The geometry and internal seismic facies within the volcanic basement suggest a tholeiitic composition and subaerial to shallow marine emplacement. At the scale of the western Indian Plate, the emplacement of this volcanic platform is constrained by structural lineations associated with rifting. By reviewing the volcanism in the Indian Ocean and plate reconstruction of the area, the timing of the volcanism can be associated with eruption of a pre-Deccan continental flood basalt (∼75-65.5 Ma). The volcanic platform in this study represents an addition of 19-26.5% to the known volume of the West Indian Volcanic Province. Copyright 2011 by the American Geophysical Union