Thin NaCl films on silver (001): island growth and work function

The surface work function (WF) and substrate temperature dependence of the NaCl thin-film growth on Ag(001) have been studied by noncontact atomic force microscopy and Kelvin probe force microscopy. In the sub-monolayer range, the NaCl film is composed of large crystalline islands, which decrease in density and increase in size with increasing temperature during deposition. Each island is composed of a large base island 2 monolayers (ML) thick (for T > 343 K), which collects impinging NaCl molecules that form ad-islands on top. Kelvin probe force microscopy (KPFM) measurements show a reduction of the silver WF by $\Delta \varphi =\varphi _{\mathrm {Ag}}-\varphi _{\mathrm {NaCl/Ag}}=0.69\pm 0.03\, \mathrm {eV}$ with no dependence on the film thickness (1–6 ML), in agreement with recent theoretical calculations. The previously observed nanometer-sized moiré pattern on islands that are 45° rotated with respect to the silver lattice could be observed in the scanning tunneling microscopy mode. However, no contrast could be obtained in KPFM images

KCl ultra-thin films with polar and non-polar surfaces grown on Si(111)7x7

International audienceThe growth of ultra-thin KCl films on the Si(111)7 3 7 reconstructed surface has been investigated as a function of KCl coverage and substrate temperature. The structure and morphology of the films were characterized by means of scanning tunneling microscopy (STM) under ultra-high vacuum (UHV) conditions. Detailed analysis of the atomically resolved STM images of islands grown at room and high temperatures (400 K–430 K) revealed the presence of KCl(001) and KCl(111) islands with the ratio between both structures depending on the growth temperature. At room temperature, the growth of the first layer, which covers the initial Si(111)7 3 7 surface, contains double/triple atomic layers of KCl(001) with a small fraction of KCl(111) islands. The high temperature growth promotes the appearance of large KCl(111) areas, which are built up by three atomic layers. At room and high temperatures, flat and atomically well-defined ultra-thin KCl films can be grown on the Si(111)7 3 7 substrate. The formation of the above mentioned (111) polar films is interpreted as a result of the thermally activated dissociative adsorption of KCl molecules on Si(111)7 3 7, which produces an excess of potassium on the Si surface

Chemical Identification of Ions in Doped NaCl by Scanning Force Microscopy

A quantitative comparison between experiment and theory is presented, which shows that all ions of the Suzuki structure on (001) surfaces of Mg2+ or Cd2+ doped NaCl crystals can be identified despite the tip-surface distance, differences in impurity chemistry, and surface termination. The identification can be used to calibrate the potential of the tip's last atom, and it is proposed to use these surfaces for better characterization of deposited nano-objects.Peer reviewe

Defect mediated manipulation of nanoclusters on an insulator

With modern scanning probe microscopes, it is possible to manipulate surface structures even at the atomic level. However, manipulation of nanoscale objects such as clusters is often more relevant and also more challenging due to the complicated interactions between the surface, cluster and apparatus. We demonstrate the manipulation of nanometer scale gold clusters on the NaCl(001) surface with a non-contact atomic force microscope, and show that the movement of clusters is in certain cases constrained to specific crystallographic directions. First principles calculations explain this kinetic anisotropy as the result of the cluster attaching to surface defects: cation vacancies allow the clusters to bond in such a way that they only move in one direction. Constraining the movement of clusters could be exploited in the construction of nanostructures or nanomechanical devices, and the manipulation signatures may also be used for identifying cluster-defect complexes.Peer reviewe

Inequalities for the Hodge numbers of irregular compact Kaehler manifolds

Based on work of R. Lazarsfeld and M. Popa, we use the derivative complex associated to the bundle of the holomorphic p-forms to provide inequalities for all the Hodge numbers of a special class of irregular compact Kaehler manifolds. For 3-folds and 4-folds we give an asymptotic bound for all the Hodge numbers in terms of the irregularity. As a byproduct, via the BGG correspondence, we also bound the regularity of the exterior cohomology modules of bundles of holomorphic p-forms.Comment: 15 page

A survey of Sierra Nevada magmatism using Great Valley detrital zircon trace-element geochemistry: View from the forearc

The well-characterized Sierra Nevada magmatic arc offers an unparalleled opportunity to improve our understanding of continental arc magmatism, but present bedrock exposure provides an incomplete record that is dominated by Cretaceous plutons, making it challenging to decipher details of older magmatism and the dynamic interplay between plutonism and volcanism. Moreover, the forearc detrital record includes abundant zircon formed during apparent magmatic lulls, suggesting that understanding the long-term history of arc magmatism requires integrating plutonic, volcanic, and detrital records. We present trace-element geochemistry of detrital zircon grains from the Great Valley forearc basin to survey Sierra Nevadan arc magmatism through Mesozoic time. We analyzed 257 previously dated detrital zircon grains from seven sandstone samples of volcanogenic, arkosic, and mixed compositions deposited ca. 145–80 Ma along the length of the forearc basin. Detrital zircon trace-element geochemistry is largely consistent with continental arc derivation and shows similar geochemical ranges between samples, regardless of location along strike of the forearc basin, depositional age, or sandstone composition. Comparison of zircon trace-element data from the forearc, arc, and retroarc regions revealed geochemical asymmetry across the arc that was persistent through time and demonstrated that forearc and retroarc basins sampled different parts of the arc and therefore recorded different magmatic histories. In addition, we identified a minor group of Jurassic detrital zircon grains with oceanic geochemical signatures that may have provenance in the Coast Range ophiolite. Taken together, these results suggest that the forearc detrital zircon data set reveals information different from that gleaned from the arc itself and that zircon compositions can help to identify and differentiate geochemically distinct parts of continental arc systems. Our results highlight the importance of integrating multiple proxies to fully document arc magmatism, demonstrating that detrital zircon geochemical data can enhance understanding of a well-characterized arc, and these data may prove an effective means by which to survey an arc that is inaccessible and therefore poorly characterized

Elliptic curve configurations on Fano surfaces

The elliptic curves on a surface of general type constitute an obstruction for the cotangent sheaf to be ample. In this paper, we give the classification of the configurations of the elliptic curves on the Fano surface of a smooth cubic threefold. That means that we give the number of such curves, their intersections and a plane model. This classification is linked to the classification of the automorphism groups of theses surfaces.Comment: 17 pages, accepted and shortened version, the rest will appear in "Fano surfaces with 12 or 30 elliptic curves

Leveraging Detrital Zircon Geochemistry to Study Deep Arc Processes: REE-Rich Magmas Mobilized by Jurassic Rifting of the Sierra Nevada Arc

Anomalous trace element compositions of Middle to Late Jurassic detrital zircon separated from Sierra Nevada forearc and intra-arc strata reveal processes of differentiation occurring within the deep arc lithosphere. REE-Sc-Nb-Ti-Hf-U-Th covariations define three populations of atypically REE-rich grains that we interpret as crystallizing from (1) differentiates produced by olivine+clinopyroxene+plagioclase+garnet±ilmenite fractionation; (2) mixing between mafic arc magmas and partial melts of Proterozoic Mojave province crust; and (3) compositionally transient, low Gd/Yb magmas generated by hornblende resorption during decompression. We interpret a fourth population of Middle Jurassic to Early Cretaceous zircons having REE contents similar to “typical” arc zircon but with atypically high Gd/Yb ratios as having crystallized from partial melts of recycled arc crust and from deep-arc differentiates that evolved down-temperature through hornblende saturation. We hypothesize that latest Jurassic extension ripped open the arc, facilitating upward migration and eruption of geochemically anomalous zircon-bearing magmas. The anomalous compositions relative to “typical” arc zircon imply that these zircons and their host magmas rarely reach the upper arc crust, where eruption and/or erosion would release their zircon cargo to the clastic system. Focusing on the trace element compositions of zircons of syn-extensional age represents a productive new strategy for learning about deep magmatic reservoirs and early differentiation pathways within the thick lithosphere of continental margin arcs

Role of tip structure and surface relaxation in atomic resolution dynamic force microscopy: CaF2(111) as a reference surface

By combining experimental dynamic scanning force microscope (SFM) images of the CaF2(111) surface with an extensive theoretical modeling, we demonstrate that the two different contrast patterns obtained reproducibly on this surface can be clearly explained in terms of the change of the sign of the electrostatic potential at the tip end. We also present direct theoretical simulations of experimental dynamic SFM images of an ionic surface at different tip-surface distances. Experimental results demonstrate a qualitative transformation of the image pattern, which is fully reproduced by the theoretical modeling and is related to the character of tip-induced displacements of the surface atoms. The modeling of the image transformation upon a systematic reduction of the tip-surface distance with ionic tips allows an estimate of the tip-surface distance present in experiment, where 0.28–0.40 nm is found to be optimal for stable imaging with well-defined atomic contrast. We also compare the modeling with ionic tips to results for a pure silicon tip. This comparison demonstrates that a silicon tip can yield only one type of image contrast and that the tip-surface interaction is not strong enough to explain the image contrast observed experimentally. The proposed interpretation of two types of images for the CaF2(111) surface can also be used to determine the chemical identity of imaged features on other surfaces with similar structure.Peer reviewe