29 research outputs found
Multiband and impurity effects in infrared and optical spectra of MgB2
A short review of the optical and far-infrared measurements on MgB is
given. Multiband and multigap effects are analyzed by comparing optical
properties with other experiments and {\em ab initio} calculations. The covered
topics are: the plasma frequency, electron-phonon interaction, impurity
scattering, the effects of C and Al substitution, interband transitions and the
far-infrared signatures of the superconducting gaps.Comment: For the Special Physica C Issue on MgB2 (2007), 11 pages, 12 figure
Interband transitions in epitaxial ferroelectric films of NaNbO3
The interband optical transitions in cube-on-cube-type epitaxial ferroelectric NaNbO3 thin films and a reference antiferroelectric NaNbO3 crystal are studied in the spectral range of 0.74–9 eV using variable-angle spectroscopic ellipsometry. The energies and the types of the transitions in the films are found to differ significantly from those in the crystal and to vary with epitaxial strain. The results are discussed in terms of epitaxial effects, including higher crystal symmetry, anisotropic lattice strain, and ferroelectric polarization in the NaNbO3 films compared to the crystal.Peer reviewe
Control of Mooij correlations at the nanoscale in the disordered metallic Ta - nanoisland FeNi multilayers
Localisation phenomena in highly disordered metals close to the extreme
conditions determined by the Mott-Ioffe-Regel (MIR) limit when the electron
mean free path is approximately equal to the interatomic distance is a
challenging problem. Here, to shed light on these localisation phenomena, we
studied the dc transport and optical conductivity properties of nanoscaled
multilayered films composed of disordered metallic Ta and magnetic FeNi
nanoisland layers, where ferromagnetic FeNi nanoislands have giant magnetic
moments of 10^3-10^5 Bohr magnetons (\mu_B). In these multilayered structures,
FeNi nanoisland giant magnetic moments are interacting due to the indirect
exchange forces acting via the Ta electron subsystem. We discovered that the
localisation phenomena in the disordered Ta layer lead to a decrease in the
Drude contribution of free charge carriers and the appearance of the low-energy
electronic excitations in the 1-2 eV spectral range characteristic of
electronic correlations, which may accompany the formation of electronic
inhomogeneities. From the consistent results of the dc transport and optical
studies we found that with an increase in the FeNi layer thickness across the
percolation threshold evolution from the superferromagnetic to ferromagnetic
behaviour within the FeNi layer leads to the delocalisation of Ta electrons
from the associated localised electronic states. On the contrary, we discovered
that when the FeNi layer is discontinuous and represented by randomly
distributed superparamagnetic FeNi nanoislands, the Ta layer normalized dc
conductivity falls down below the MIR limit by about 60%. The discovered effect
leading to the dc conductivity fall below the MIR limit can be associated with
non-ergodicity and purely quantum (many-body) localisation phenomena, which
need to be challenged further.Comment: 29 pages, 8 figures. This is a post-peer-review, precopyedit version
of an article published in Scientific Reports. The final authenticated
version is available online at http://dx.doi.org/10.1038/s41598-020-78185-
Controlling the Transverse Magneto-Optical Kerr Effect in Cr/NiFe Bilayer Thin Films by Changing the Thicknesses of the Cr Layer
Here, we demonstrate the impact of ferromagnetic layer coating on controlling the magneto-optical response. We found that the transverse magneto-optical Kerr effect (TMOKE) signal and TMOKE hysteresis loops of Ni80Fe20 thin layers coated with a Cr layer show a strong dependence on the thickness of the Cr layer and the incidence angle of the light. The transmission and reflection spectra were measured over a range of incidence angles and with different wavelengths so as to determine the layers’ optical parameters and to explain the TMOKE behavior. The generalized magneto-optical and ellipsometry (GMOE) model based on modified Abeles characteristic matrices was used to examine the agreement between the experimental and theoretical results. A comprehensive theoretical and experimental analysis reveals the possibility to create a TMOKE suppression/enhancement coating at specific controllable incidence angles. This has potential for applications in optical microscopy and sensors
Localization Phenomena in Disordered Tantalum Films
Using dc transport and wide-band spectroscopic ellipsometry techniques we study localization phenomena in highly disordered metallic β -Ta films grown by rf sputtering deposition. The dc transport study implies non-metallic behavior (d ρ /dT < 0), with negative temperature coefficient of resistivity (TCR). We found that as the absolute TCR value increased, specifying an elevated degree of disorder, the free charge carrier Drude response decreases, indicating the enhanced charge carrier localization. Moreover, we found that the pronounced changes occur at the extended spectral range, involving not only the Drude resonance, but also the higher-energy Lorentz bands, in evidence of the attendant electronic correlations. We propose that the charge carrier localization, or delocalization, is accompanied by the pronounced electronic band structure reconstruction due to many-body effects, which may be the key feature for understanding the physics of highly disordered metals
Aging behaviour of particular stainless-steels and NiFeCr alloy suitable for heat exchangers
This paper deals with the testing of three materials for special heat exchanger for short-time application. Mechanical and microstructural properties after aging at 650 and 850 °C were tested and analysed. The results will serve as an input data for the design and construction of plate heat exchanger
Optical revelation of defects in epitaxial barium titanate films
Abstract
Allying epitaxial strain and synthesis conditions allows for the introduction of specific point defects in perovskite oxide films. In ferroelectric films, such defects lead to essential polar and electronic properties, which can enable advanced applications. Here, to elucidate the nature of the defects, optical constants are investigated in the spectral range of 0.7–8.8 eV in epitaxial ferroelectric BaTiO₃ films, which are synthesized under different conditions. It is demonstrated that oxygen-vacancy-related defects are responsible for a peculiar transition below the bandgap at ∼2.7–2.9 eV and significant blueshifts of ∼0.3–0.4 eV of the gap and the main interband transitions. These observations suggest that the defects are dipolar complexes comprising titanium cations and oxygen vacancies (Ti³⁺–Vₒ)
Effect of epitaxy on interband transitions in ferroelectric KNbO3
| openaire: EC/FP7/307502/EU//E-CONTROLPeer reviewe