Anion emission from water molecules colliding with positive ions: Identification of binary and many-body processes

It is shown that negative ions are ejected from gas-phase water molecules when bombarded with positive ions at keV energies typical of solar-wind velocities. This finding is relevant for studies of planetary and cometary atmospheres, as well as for radiolysis and radiobiology. Emission of both H- and heavier (O- and OH-) anions, with a larger yield for H-, was observed in 6.6-keV 16O+ + H2O collisions. The ex-perimental setup allowed separate identification of anions formed in collisions with many-body dynamics from those created in hard, binary collisions. Most of the ani-ons are emitted with low kinetic energy due to many-body processes. Model calcu-lations show that both nucleus-nucleus interactions and electronic excitations con-tribute to the observed large anion emission yield.Comment: 5 pages, 4 figure

A Young-type experiment using a single-electron source and an independent atomic-size two-center interferometer: the realization of a thought experiment

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Ion induced fragmentation of biomolecular systems at low collision energies

In this paper, we present results of different collision experiments between multiply charged ions at low collision energies (in the keV-region) and biomolecular systems. This kind of interaction allows to remove electrons form the biomolecule without transferring a large amount of vibrational excitation energy. Nevertheless, following the ionization of the target, fragmentation of biomolecular species may occur. It is the main objective of this work to study the physical processes involved in the dissociation of highly electronically excited systems. In order to elucidate the intrinsic properties of certain biomolecules (porphyrins and amino acids) we have performed experiments in the gas phase with isolated systems. The obtained results demonstrate the high stability of porphyrins after electron removal. Furthermore, a dependence of the fragmentation pattern produced by multiply charged ions on the isomeric structure of the alanine molecule has been shown. By considering the presence of other surrounding biomolecules (clusters of nucleobases), a strong influence of the environment of the biomolecule on the fragmentation channels and their modification, has been clearly proven. This result is explained, in the thymine and uracil case, by the formation of hydrogen bonds between O and H atoms, which is known to favor planar cluster geometries.</p

Anion emission from water molecules colliding with positive ions: Identification of binary and many-body processes

It is shown that negative ions are ejected from gas-phase water molecules when bombarded with positive ions at keV energies typical of solar-wind velocities. This finding is relevant for studies of planetary and cometary atmospheres, as well as for radiolysis and radiobiology. Emission of both H- and heavier (O- and OH-) anions, with a larger yield for H-, was observed in 6.6-keV 16O+ + H2O collisions. The ex- perimental setup allowed separate identification of anions formed in collisions with many-body dynamics from those created in hard, binary collisions. Most of the ani- ons are emitted with low kinetic energy due to many-body processes. Model calcu- lations show that both nucleus-nucleus interactions and electronic excitations con- tribute to the observed large anion emission yield

Anion and cation emission from water molecules after collisions with 6.6-keV 16 O+ ions

DOI: https://doi.org/10.1103/PhysRevA.100.032713arXiv link: http://arxiv.org/abs/1910.00657International audienceAnion and cation emission following water dissociation was studied for 6.6-keV $^{16}$O$^{+}$ + H$_{2}$O collisions. Absolute cross sections for the emission of all positively and negatively charged fragments, differential in both energy and observation angle, were measured. The fragments formed in hard, binary collisions appearing in peaks were distinguishable from those created in soft collisions with many-body dynamics that result in a broad energy spectrum. A striking feature is that anions and cations are emitted with similar energy and angular distributions, with a nearly constant ratio of about 1:100 for H$^{-}$ to H$^{+}$. Model calculations were performed at different levels of complexity. Four-body scattering simulations reproduce the measured fragment distributions if adequate kinetic-energy release of the target is taken into account. Providing even further insight into the underlying processes, predictions of a thermodynamic model indicate that transfer ionization at small impact parameters is the dominant mechanism for H$^{+}$ creation. The present findings confirm our earlier observation that in molecular fragmentation induced by slow, singly charged ions, the charge states of the emitted hydrogen fragments follow a simple statistical distribution independent of the way they are formed

Spin density wave dislocation in chromium probed by coherent x-ray diffraction

We report on the study of a magnetic dislocation in pure chromium. Coherent x-ray diffraction profiles obtained on the incommensurate Spin Density Wave (SDW) reflection are consistent with the presence of a dislocation of the magnetic order, embedded at a few micrometers from the surface of the sample. Beyond the specific case of magnetic dislocations in chromium, this work may open up a new method for the study of magnetic defects embedded in the bulk.Comment: 8 pages, 7 figure

Molecular-rotation-induced splitting of the binary ridge in the velocity map of sub-eV H+ ions ejected from H2 molecules by ion impact

In studies of ion-induced molecular fragmentation, the challenging measurement of the velocity distribution of fragments emitted below 1-eV kinetic energy is rarely achieved, although most fragments have an energy below this value. Here, we study H+ fragment emission in collisions of 10-keV O+ ions with H2 molecules using a field-free time-of-flight technique developed specifically to detect sub-eV fragments. We find that, in the velocity map, the binary ridge due to direct H+ knockout is split into two parts arising from the rotational motion of the H2 molecule, and that this split scales with rotational velocity. The velocity distribution of the nuclei in the original molecule is determined and the thermally populated J = 1 rotational level is found to be the dominant contributor, although asymmetry in the split indicates projectile-induced rotational transitions between M sub-levels. These rotation effects influence fragment emission probabilities, thus carrying important consequences for the radiation-induced hydrogen loss and H2 dissociation in the atmospheres or exospheres of planets and moons