Assessing metal contamination and speciation in sewage sludge: implications for soil application and environmental risk

Based on the most recently published data, we definitively estimated that the annual global production of sewage sludge may rise from ~ 53 million tons dry solids currently to ~ 160 million tons if global wastewater were to be treated to a similar level as in the 27 European Union countries/UK. It is widely accepted that the agricultural application is a beneficial way to recycle the abundant organic matter and plant nutrients in sewage sludge. However, land application may need to be limited due to the presence of metals. This work presents a meticulous and systematic review of the sources, concentrations, partitioning, and speciation of metals in sewage sludge in order to determine the impacts of sludge application on metal behavior in soils. It identifies that industrial wastewater, domestic wastewater and urban runoff are main sources of metals in sludge. It shows conventional treatment processes generally result in the partitioning of over 70% of metals from wastewater into primary and secondary sludge. Typically, the order of metal concentrations in sewage sludge is Zn > Cu > Cr ≈ Pb ≈ Ni > Cd. The proportion of these metals that are easily mobilised is highest for Zn and Ni, followed by Cd and Cu, then Pb and Cr. Sludge application to land will lead to elevated metal concentrations, and potentially to short-term changes to the dominant metal species in soils. However, the speciation of sludge-associated metals will change over time due to interactions with plant roots and soil minerals and as organic matter is mineralised by rhizo-microbiome

How palladium inhibits CO poisoning during electrocatalytic formic acid oxidation and carbon dioxide reduction

Catalysis and Surface Chemistr

Measurement of hybrid content of heavy quarkonia using lattice NRQCD

Using lowest-order lattice NRQCD to create heavy meson propagators and applying the spin-dependent interaction, $c_B^{} \frac{-g}{2m_q}\vec\sigma\cdot\vec{B}$, at varying intermediate time slices, we compute the off-diagonal matrix element of the Hamiltonian for the quarkonium-hybrid two-state system. Thus far, we have results for one set of quenched lattices with an interpolation in quark mass to match the bottomonium spectrum. After diagonalization of the two-state Hamiltonian, we find the ground state of the $\Upsilon$ to show a $0.0035(1)c_B^2$ (with $c_B^2 \sim 1.5-3.1$) probability admixture of hybrid, $|b\bar{b}g>$.Comment: 11 pages, 4 figures, to appear in Phys Rev

Effect of Step Density and Orientation on the Apparent pH Dependence of Hydrogen and Hydroxide Adsorption on Stepped Platinum Surfaces

The effect of the alkali-metal cation (Li+, Na+, K+, and Cs+) on the non-Nernstian pH shift of the Pt(554) and Pt(533) step-associated voltammetric peak is elucidated over a wide pH window (1-13), through computation and experiment. In conjunction with our previously reported study on Pt(553), the non-Nernstian pH shift of the step-induced peak is found to be independent of the step density and the step orientation. In our prior work, we explained the sharp peak as due to the exchange between adsorbed hydrogen and hydroxyl along the step and the non-Nernstian shift as a result of the adsorption of an alkali-metal cation and its subsequent weakening of hydroxyl adsorption. Our density functional theory results support this same mechanism on Pt(533) and capture the effect of alkali-metal cation identity and alkali cation coverage well, where increasing electrolyte pH and cation concentration leads to increased cation coverage and a greater weakening effect on hydroxide adsorption. This work paints a consistent picture for the mechanism of these effects, expanding our fundamental understanding of the electrode/electrolyte interface and practical ability to control hydrogen and hydroxyl adsorption thermodynamics via the electrolyte composition, important for improving fuel cell and electrolyzer performance.Catalysis and Surface Chemistr

Four methods for determining the composition of trace radioactive surface contamination of low-radioactivity metal

Four methods for determining the composition of low-level uranium- and thorium-chain surface contamination are presented. One method is the observation of Cherenkov light production in water. In two additional methods a position-sensitive proportional counter surrounding the surface is used to make both a measurement of the energy spectrum of alpha particle emissions and also coincidence measurements to derive the thorium-chain content based on the presence of short-lived isotopes in that decay chain. The fourth method is a radiochemical technique in which the surface is eluted with a weak acid, the eluate is concentrated, added to liquid scintillator and assayed by recording beta-alpha coincidences. These methods were used to characterize two `hotspots' on the outer surface of one of the He-3 proportional counters in the Neutral Current Detection array of the Sudbury Neutrino Observatory experiment. The methods have similar sensitivities, of order tens of ng, to both thorium- and uranium-chain contamination.Comment: 22 pages, 19 figure

Hybrid configuration content of heavy S-wave mesons

We use the non-relativistic expansion of QCD (NRQCD) on the lattice to study the lowest hybrid configuration contribution to the ground state of heavy S-wave mesons. Using lowest-order lattice NRQCD to create the heavy-quark propagators, we form a basis of ``unperturbed'' S-wave and hybrid states. We then apply the lowest-order coupling of the quark spin and chromomagnetic field at an intermediate time slice to create ``mixed'' correlators between the S-wave and hybrid states. From the resulting amplitudes, we extract the off-diagonal element of our two-state Hamiltonian. Diagonalizing this Hamiltonian gives us the admixture of hybrid configuration within the meson ground state. The present effort represents a continuation of previous work: the analysis has been extended to include lattices of varying spacings, source operators having better overlap with the ground states, and the pseudoscalar (along with the vector) channel. Results are presented for bottomonium ($\Upsilon$, $\eta_b^{}$) using three different sets of quenched lattices. We also show results for charmonium ($J/\psi$, $\eta_c^{}$) from one lattice set, although we note that the non-relativistic approximation is not expected to be very good in this case.Comment: 9 pages, 7 figures, version to appear in Phys Rev

Glueball spectrum based on a rigorous three-dimensional relativistic equation for two-gluon bound states I: Derivation of the relativistic equation

A rigorous three-dimensional relativistic equation satisfied by two-gluon bound states is derived from the QCD with massive gluons. With the gluon fields and the quark fields being expanded in terms of the gluon multipole fields and the spherical Dirac spinors respectively, the equation is well established in the angular momentum representation and hence is much convenient for solving the problem of two-gluon glueball spectra. In particular, the interaction kernel in the equation is exactly derived and given a closed expression which includes all the interactions taking place in the two-gluon glueballs. The kernel contains only a few types of Green's functions and commutators. Therefore, it is not only easily calculated by the perturbation method, but also provides a suitable basis for nonperturbative investigations

Kinetic determinants of athletics sprint start performance

The sprint start lays a foundation to a good performance of track athletes. Thus, the aim was to understand the key force production determinants of the athletics sprint start. Eleven male athletes performed normal sprint starts with ground reaction forces collected at 1000 Hz from under each extremity separately. Key kinetic variables were analysed from six starts from each athlete and correlated with the horizontal external power. Several force and timing variables provided statistically significant correlations, but especially the high ratio of forces at 58.9 ± 3.5% with r = .941 (p = .000) demonstrated the importance of horizontal force production during the start. Better performers reached large forces on the blocks quicker, although it was interesting that the actual rate of force production did not statistically significantly correlate with the horizontal external power

Estimating Asian terrestrial carbon fluxes from CONTRAIL aircraft and surface CO2 observations for the period 2006 to 2010

Current estimates of the terrestrial carbon fluxes in Asia show large uncertainties particularly in the boreal and mid-latitudes and in China. In this paper, we present an updated carbon flux estimate for Asia ("Asia" refers to lands as far west as the Urals and is divided into boreal Eurasia, temperate Eurasia and tropical Asia based on TransCom regions) by introducing aircraft CO2 measurements from the CONTRAIL (Comprehensive Observation Network for Trace gases by Airline) program into an inversion modeling system based on the CarbonTracker framework. We estimated the averaged annual total Asian terrestrial land CO2 sink was about -1.56 Pg C yr-1 over the period 2006–2010, which offsets about one-third of the fossil fuel emission from Asia (+4.15 Pg C yr-1). The uncertainty of the terrestrial uptake estimate was derived from a set of sensitivity tests and ranged from -1.07 to -1.80 Pg C yr-1, comparable to the formal Gaussian error of ±1.18 Pg C yr-1 (1-sigma). The largest sink was found in forests, predominantly in coniferous forests (-0.64 ± 0.70 Pg C yr-1) and mixed forests (-0.14 ± 0.27 Pg C yr-1); and the second and third large carbon sinks were found in grass/shrub lands and croplands, accounting for -0.44 ± 0.48 Pg C yr-1 and -0.20 ± 0.48 Pg C yr-1, respectively. The carbon fluxes per ecosystem type have large a priori Gaussian uncertainties, and the reduction of uncertainty based on assimilation of sparse observations over Asia is modest (8.7–25.5%) for most individual ecosystems. The ecosystem flux adjustments follow the detailed a priori spatial patterns by design, which further increases the reliance on the a priori biosphere exchange model. The peak-to-peak amplitude of inter-annual variability (IAV) was 0.57 Pg C yr-1 ranging from -1.71 Pg C yr-1 to -2.28 Pg C yr-1. The IAV analysis reveals that the Asian CO2 sink was sensitive to climate variations, with the lowest uptake in 2010 concurrent with a summer flood and autumn drought and the largest CO2 sink in 2009 owing to favorable temperature and plentiful precipitation conditions. We also found the inclusion of the CONTRAIL data in the inversion modeling system reduced the uncertainty by 11% over the whole Asian region, with a large reduction in the southeast of boreal Eurasia, southeast of temperate Eurasia and most tropical Asian areas

Exploring synergetic effects of dimensionality reduction and resampling tools on hyperspectral imagery data classification

The present paper addresses the problem of the classification of hyperspectral images with multiple imbalanced classes and very high dimensionality. Class imbalance is handled by resampling the data set, whereas PCA and a supervised filter are applied to reduce the number of spectral bands. This is a preliminary study that pursues to investigate the benefits of combining several techniques to tackle the imbalance and the high dimensionality problems, and also to evaluate the order of application that leads to the best classification performance. Experimental results demonstrate the significance of using together these two preprocessing tools to improve the performance of hyperspectral imagery classification. Although it seems that the most effective order corresponds to first a resampling strategy and then a feature (or extraction) selection algorithm, this is a question that still needs a much more thorough investigation in the futureThis work has partially been supported by the Spanish Ministry of Education and Science under grants CSD2007–00018, AYA2008–05965–0596 and TIN2009–14205, the Fundació Caixa Castelló–Bancaixa under grant P1–1B2009–04, and the Generalitat Valenciana under grant PROMETEO/2010/02