Osmotic force resisting chain insertion in a colloidal suspension

We consider the problem of inserting a stiff chain into a colloidal suspension of particles that interact with it through excluded volume forces. The free energy of insertion is associated with the work of creating a cavity devoid of colloid and sufficiently large to accomodate the chain. The corresponding work per unit length is the force that resists the entry of the chain into the colloidal suspension. In the case of a hard sphere fluid, this work can be calculated straightforwardly within the scaled particle theory; for solutions of flexible polymers, on the other hand, we employ simple scaling arguments. The forces computed in these ways are shown, for nanometer chain and colloid diameters, to be of the order of tens of pN for solution volume fraction for biophysical processes such as the ejection of DNA from viral capsids into the cell cytoplasm.Comment: 16 pages,3 figures. Accepted for publication in European Physical Journal

Regional disparities and industrial structure: territorial capital and productivity in Italian firms

We investigate the role of Territorial Capital (TC) on the productivity of Italian firms, constructing indicators for eight dimensions of TC in a first attempt to capture a wide variety of regional resources. When imposing homogeneous TC effects on all firms, we find that technological, social, institutional, financial and infrastructure capital drive productivity. However, only technological and artistic capital contribute to reduce regional disparities. Across industries, financial capital and infrastructure increase productivity in companies operating in a wide range of sectors. Industrial policies should consider sectoral heterogeneity and North-South differences to effectively boost productivity performance

Thermodynamics of micellization of oppositely charged polymers

The complexation of oppositely charged colloidal objects is considered in this paper as a thermodynamic micellization process where each kind of object needs the others to micellize. This requirement gives rise to quantitatively different behaviors than the so-called mixed-micellization where each specie can micellize separately. A simple model of the grand potential for micelles is proposed to corroborate the predictions of this general approach.Comment: 7 pages, 2 figures. Accepted for publication in Europhysics Letter

Public sector reform trajectories: A complexity-embracing perspective

To understand the divergent outcomes of the same centrally-defined reform programme means addressing the complexity of implementation. Italy's local government reform programme highlights the shaping role of contextual elements in the rollout of programmes within multi-level systems. The authors emphasize the need for a pragmatic approach to the 'implementation puzzle'-one that leverages the local variables and that enables self-organized responses. Decision-makers should strategically engage with the complexity of multi-level institutional systems

High temperature onset of field-induced transitions in the spin-ice compound Dy2Ti2O7

We have studied the field-dependent ac magnetic susceptibility of single crystals of Dy2Ti2O7 spin ice along the [111] direction in the temperature range 1.8 K - 7 K. Our data reflect the onset of local spin ice order in the appearance of different field regimes. In particular, we observe a prominent feature at approximately 1.0 T that is a precursor of the low-temperature metamagnetic transition out of field-induced kagome ice, below which the kinetic constraints imposed by the ice rules manifest themselves in a substantial frequency-dependence of the susceptibility. Despite the relatively high temperatures, our results are consistent with a monopole picture, and they demonstrate that such a picture can give physical insight to the spin ice systems even outside the low-temperature, low-density limit where monopole excitations are well-defined quasiparticles

Binding effects in multivalent Gibbs-Donnan equilibrium

The classical Gibbs-Donnan equilibrium describes excess osmotic pressure associated with confined colloidal charges embedded in an electrolyte solution. In this work, we extend this approach to describe the influence of multivalent ion binding on the equilibrium force acting on a charged rod translocating between two compartments, thereby mimicking ionic effects on force balance during in vitro DNA ejection from bacteriophage. The subtle interplay between Gibbs-Donnan equilibrium and adsorption equilibrium leads to a non-monotonic variation of the ejection force as multivalent salt concentration is increased, in qualitative agreement with experimental observations

Quality of institutions and productivity of State-Invested Enterprises: International evidence from major telecom companies

The quality of institutions is at the core of the differences in the growth of income and productivity of nations. A growing body of evidence shows how this is also true at the firm level. After taking stock of earlier theoretical and empirical literature on the efficiency of state-owned versus private enterprises, while we consider ownership as the core internal governance mechanism of firms, we add quality of government as a determinant of the external institutional environment. To disentangle the effect of internal and external institutions on firms' productivity, we use different sets of ownership and institutional environment indicators. After having identified the top 350 private, state-invested (i.e. partially state-owned)and state-owned enterprises in the telecommunications industry in EU28 and in more than 60 other countries between 2007 and 2015, we empirically investigate models of firms' productivity augmented with ownership and quality of government. Our findings suggest that, after controlling for the regulatory and competitive conditions at the country level, on average, public ownership has a negative impact on firm-level TFP. This effect is however mitigated by high external institutional quality and even reversed in some countries with a particularly favourable institutional environment

Molecular random tilings as glasses

We have recently shown [Blunt et al., Science 322, 1077 (2008)] that p-terphenyl-3,5,3',5'-tetracarboxylic acid adsorbed on graphite self-assembles into a two-dimensional rhombus random tiling. This tiling is close to ideal, displaying long range correlations punctuated by sparse localised tiling defects. In this paper we explore the analogy between dynamic arrest in this type of random tilings and that of structural glasses. We show that the structural relaxation of these systems is via the propagation--reaction of tiling defects, giving rise to dynamic heterogeneity. We study the scaling properties of the dynamics, and discuss connections with kinetically constrained models of glasses.Comment: 5 pages, 5 figure