4,380 research outputs found
Reaction of Group III Biheterocyclic Complexes
Group III alkyl complexes supported by a ferrocene diamide ligand (1,1âČ-fc(NSitBuMe_2)_2) have been found to be reactive toward aromatic N-heterocycles such as 1-methylimidazole and pyridines. These reactions were investigated experimentally and computationally. An initial CâH activation event is followed by a coupling reaction to form biheterocyclic complexes, in which one of the rings is dearomatized. In the case of 1-methylimidazole, the biheterocyclic compound could not be isolated and further led to an imidazole ring-opened product; in the case of pyridines, it transformed into an isomer with extended conjugation of double bonds. Mechanisms for both reactions are proposed on the basis of experimental and computational results. DFT calculations were also used to show that an energetically accessible pathway for the ring-opening of pyridines exists
DNAPlotter: circular and linear interactive genome visualization
Summary: DNAPlotter is an interactive Java application for generating circular and linear representations of genomes. Making use of the Artemis libraries to provide a user-friendly method of loading in sequence files (EMBL, GenBank, GFF) as well as data from relational databases, it filters features of interest to display on separate user-definable tracks. It can be used to produce publication quality images for papers or web pages
Trait self-control and beliefs about the utility of emotions for initiatory and inhibitory self-control
How do people with high trait self-control achieve their success? This research aimed to provide evidence for beliefs about emotion utility as a potential mechanism. Specifically, because beliefs about the utility of emotions predict emotion regulation and successful performance, we investigate the hypothesis that trait self-control influences beliefs about the utility of emotions for self-control. Two preregistered studies examined whether beliefs about the utility of emotions in everyday self-control situations varied depending on the person (trait self-control) and the situation (initiatory or inhibitory self-control). Our key finding was that people considered positive emotions more useful for self-control than negative emotions. This effect was also moderated by situational and individual factors, such that positive emotions were considered especially useful by participants with high trait self-control and in situations requiring initiatory self-control (with the opposite effect for negative emotions). This research suggests a potential role for instrumental emotion regulation in self-control success
Voltage control of nuclear spin in ferromagnetic Schottky diodes
We employ optical pump-probe spectroscopy to investigate the voltage
dependence of spontaneous electron and nuclear spin polarizations in hybrid
MnAs/n-GaAs and Fe/n-GaAs Schottky diodes. Through the hyperfine interaction,
nuclear spin polarization that is imprinted by the ferromagnet acts on
conduction electron spins as an effective magnetic field. We demonstrate tuning
of this nuclear field from <0.05 to 2.4 kG by varying a small bias voltage
across the MnAs device. In addition, a connection is observed between the diode
turn-on and the onset of imprinted nuclear polarization, while traditional
dynamic nuclear polarization exhibits relatively little voltage dependence.Comment: Submitted to Physical Review B Rapid Communications. 15 pages, 3
figure
A novel algorithm for dynamic student profile adaptation based on learning styles
The file attached to this record is the author's final peer reviewed version. The Publisher's final version can be found by following the DOI link.E-learning recommendation systems are used to enhance student performance and knowledge by providing tailor- made services based on the studentsâ preferences and learning styles, which are typically stored in student profiles. For such systems to remain effective, the profiles need to be able to adapt and reflect the studentsâ changing behaviour. In this paper, we introduce new algorithms that are designed to track student learning behaviour patterns, capture their learning styles, and maintain dynamic student profiles within a recommendation system (RS). This paper also proposes a new method to extract features that characterise student behaviour to identify studentsâ learning styles with respect to the Felder-Silverman learning style model (FSLSM). In order to test the efficiency of the proposed algorithm, we present a series of experiments that use a dataset of real students to demonstrate how our proposed algorithm can effectively model a dynamic student profile and adapt to different student learning behaviour. The results revealed that the students could effectively increase their learning efficiency and quality for the courses when the learning styles are identified, and proper recommendations are made by using our method
Controlling spin relaxation with a cavity
Spontaneous emission of radiation is one of the fundamental mechanisms by
which an excited quantum system returns to equilibrium. For spins, however,
spontaneous emission is generally negligible compared to other non-radiative
relaxation processes because of the weak coupling between the magnetic dipole
and the electromagnetic field. In 1946, Purcell realized that the spontaneous
emission rate can be strongly enhanced by placing the quantum system in a
resonant cavity -an effect which has since been used extensively to control the
lifetime of atoms and semiconducting heterostructures coupled to microwave or
optical cavities, underpinning single-photon sources. Here we report the first
application of these ideas to spins in solids. By coupling donor spins in
silicon to a superconducting microwave cavity of high quality factor and small
mode volume, we reach for the first time the regime where spontaneous emission
constitutes the dominant spin relaxation mechanism. The relaxation rate is
increased by three orders of magnitude when the spins are tuned to the cavity
resonance, showing that energy relaxation can be engineered and controlled
on-demand. Our results provide a novel and general way to initialise spin
systems into their ground state, with applications in magnetic resonance and
quantum information processing. They also demonstrate that, contrary to popular
belief, the coupling between the magnetic dipole of a spin and the
electromagnetic field can be enhanced up to the point where quantum
fluctuations have a dramatic effect on the spin dynamics; as such our work
represents an important step towards the coherent magnetic coupling of
individual spins to microwave photons.Comment: 8 pages, 6 figures, 1 tabl
Developing autonomous learning in first year university students using perspectives from positive psychology
Autonomous learning is a commonly occurring learning outcome from university study, and it is argued that students require confidence in their own abilities to achieve this. Using approaches from positive psychology, this study aimed to develop confidence in firstâyear university students to facilitate autonomous learning. Psychological character strengths were assessed in 214 students on day one at university. Two weeks later their top three strengths were given to them in study skills modules as part of a psychoâeducational intervention designed to increase their selfâefficacy and selfâesteem. The impact of the intervention was assessed against a control group of 40 students who had not received the intervention. The results suggested that students were more confident after the intervention, and that levels of autonomous learning increased significantly compared to the controls. Character strengths were found to be associated with selfâefficacy, selfâesteem and autonomous learning in ways that were theoretically meaningful
Working Title Films and Universal : The Integration of a British Production Company into a Hollywood Studio
Working Title Films is arguably the most successful and well-known production company in Britain today. For over 30 years, it has produced a diverse range of critically and commercially successful British films including romantic comedies such as Four Weddings and a Funeral (1994) and Bridget Jonesâs Diary (2001), family films like Bean (1997) and Nanny McPhee (2005) and dramas including Atonement (2007) and The Theory of Everything (2014). For the majority of its history, however, Working Title has been defined in business terms by its status as a subsidiary of one of two multinational media conglomerates, PolyGram (1992â8) and Universal (1998âpresent). The transition between the two began when PolyGram, and its film studio, PolyGram Filmed Entertainment (PFE), was sold to Seagram, the parent company of Universal. This article examines Working Titleâs integration into Universal and the evolving media ecology which shaped the processes of development, green-lighting, production, marketing and distribution at play within and between both companies between 1998 and 2006. In these respects, Working Titleâs transition between parent companies is a narrative of both continuity and change. Significantly, three key stages of gatekeeping remained common to both the PFE and Universal eras: development, green-lighting and distribution. The institutional perimeters within which these points of decision-making occurred, however, changed considerably. The article concludes by considering the impact of such structures and processes on the films which Working Title produced, particularly their various representations of Britain and âBritishnessâ
New Perspectives for Watering Substrate-Based Root Modules in Microgravity in the Advanced Plant Habitat (APH)
No abstract availabl
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