Lesson Study and Service Learning in Teacher Preparation

The aim of this paper is to share an teacher preparation experience that combines Lesson Study (LS) with a Service Learning methodology. This experience is interdisciplinary and includes three subjects from first-grade Childhood Education, carried out at University of Malaga since academic year 2014-2015. Within this framework, our students carry out Service Learning projects for schools in our area that are designed and developed following the LS methodology. Service Learning projects go through the following phases (Puig, J., Martín, & Batlle, 2008): 1) Preparation by the teachers involved in the project; 2) Implementation, i.e. developing the project with the students; 3) Evaluation. The implementation phase also has three sub-phases: preparation, implementation, and round-up. It is here that the LS is developed through the following phases (Soto & Pérez, 2015): 1. Define the problem; 2. Co-operatively design an experimental lesson and its observation process; 3. First experimental lesson; 4. Analyse and review the lesson; 5. Second experimental lesson; 6. Analysis and drafting of conclusions; 7. Presentation in extended context. We were able to gather evidence on how students teachers resolved different cognitive conflicts during the process. We saw how the LS process, with its phases and cooperative work, allows them to combine creativity and unique talents in a common project that acquires meaning and relevance thanks to Service Learning. This provides a framework that facilitates the construction of solid structures related to the meaning of the educational process, and which can be used to recalibrate what it means to be a Childhood School teacher: a creative, relevant, complex experience that requires recreating the knowledge and experience that students bring with them to the University about what it means to be a Childhood School teacher.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

Hydrothermal assisted synthesis of iron oxide-based magnetic silica spheres and their performance in magnetophoretic water purification

Porous Magnetic Silica (PMS) spheres of about 400 nm diameter were synthesised by one-pot process using the classical Stӧber method combined with hydrothermal treatment. Maghemite nanoparticles (γ-Fe2O3) were used as fillers and cetyltrimethylammonium bromide (CTAB) was used as templating agent. The application of the hydrothermal process (120 °C during 48 h) before the calcination leads to the formation of homogeneous and narrow size distribution PMS spheres. X-ray diffraction patterns (XRD), Infrared measurements (FTIR) and Transmission Electron microscopy (TEM) methods were used to determine the composition and morphology of the obtained PMS spheres. The results show a homogeneous distribution of the γ-Fe2O3 nanoparticles in the silica matrix with a “hollow-like” morphology. Magnetophoresis measurements at 60 T m−1 show a total separation time of the PMS spheres suspension of about 16 min. By using this synthesis method, the limitation of the formation of silica spheres without incorporation of magnetic nanoparticles is overcome. These achievements make this procedure interesting for industrial up scaling. The obtained PMS spheres were evaluated as adsorbents for Ni2+ in aqueous solution. Their adsorption capacity was compared with the adsorption capacity of magnetic silica spheres obtained without hydrothermal treatment before calcination process. PMS spheres show an increase of the adsorption capacity of about 15% of the initial dissolution of Ni2+ without the need to functionalize the silica surface.Fundação para a Ciência e a Tecnologia (FCT

Tuning the antimicrobial activity of low molecular weight hydrogels using dopamine autoxidation

We present a method to trigger the formation of dipeptide-based hydrogels by the simple addition of dopamine. Dopamine undergoes oxidation in air, reducing the pH to induce gelation. The production of polydopamine and release of reactive oxygen species such as hydrogen peroxide confers antimicrobial activity. Gel stiffness can be controlled by modulating the initial starting pH of the gelator solution. We can use this method to tune the antimicrobial activity of the gels, with gels that are less stiff demonstrating increased bactericidal efficacy against Gram-positive bacteria

The effect of nanotube surface oxidation in the electrical response of MWCNT/PVDF nanocomposites

Carbon nanotubes / poly(vinylidene fluoride) composites were prepared using CNT with different oxidation and thermal treatments. The oxidation procedure leads to CNT with the most acidic characteristics that lower the degree of crystallinity of the polymer and contribute to a large increase of the dielectric constant. The surface treatments, in general, increase percolation threshold and decrease conductivity, but, on the other hand, are able to promote the nucleation of the electroactive phase of the polymer, which is suitable for the use of PVDF in sensors, actuators and other smart materials applications. Finally, the surface treatments do not seem to affect CNT interaction among them, reaching similar degrees of dispersion in all cases, as shown by the SEM results. The maximum value of the dielectric constant is ~630. It is demonstrated that the composite conductivity can be attributed to a hopping mechanism that is strongly affected by the surface treatment of the CNT.The authors thank the Fundacao para a Ciencia e a Tecnologia (FCT), Portugal, for financial support through the projects PTDC/CTM/69316/2006 and NANO/NMed-SD/0156/2007), and CIENCIA 2007 program for S.A.C.; V. S., J.S. and J.N.P. also thank FCT for the SFRH/BPD/63148/2009, SFRH/BD/60623/2009 and SFRH/BD/66930/2009 grants

Controlling photocatalytic activity by self-assembly – Tuning perylene bisimide photocatalysts for the hydrogen evolution reaction

Amino acid functionalized perylene bisimides (PBIs) form self-assembled structures in solution, the nature of which depends on the local environment. Using a high-throughput photocatalysis setup, five PBIs are studied for the hydrogen evolution reaction (HER) under a range of conditions (pH and hole scavenger concentration) across 350 experiments to explore the relationship between supramolecular structure and photocatalytic activity. Using small angle X-ray scattering (SAXS), NMR spectroscopy and ultraviolet-visible (UV-vis) absorption spectroscopy, it is shown that photocatalytic activity is determined by the nature of the self-assembled aggregate that is formed, demonstrating the potential of self-assembly to tune activity. There is a clear correlation between the presence of charged flexible cylindrical aggregates and the occurrence of photocatalytic H2 production, with UV–vis spectroscopy indicating that the most active structure type has a distinctive form of π-aggregation which is proposed to enable efficient charge separation across multiple PBI units

An analysis of the local optima storage capacity of Hopfield network based fitness function models

A Hopfield Neural Network (HNN) with a new weight update rule can be treated as a second order Estimation of Distribution Algorithm (EDA) or Fitness Function Model (FFM) for solving optimisation problems. The HNN models promising solutions and has a capacity for storing a certain number of local optima as low energy attractors. Solutions are generated by sampling the patterns stored in the attractors. The number of attractors a network can store (its capacity) has an impact on solution diversity and, consequently solution quality. This paper introduces two new HNN learning rules and presents the Hopfield EDA (HEDA), which learns weight values from samples of the fitness function. It investigates the attractor storage capacity of the HEDA and shows it to be equal to that known in the literature for a standard HNN. The relationship between HEDA capacity and linkage order is also investigated

PAINT‐ing fluorenylmethoxycarbonyl (Fmoc)‐diphenylalanine hydrogels

Self‐assembly of Fmoc‐protected diphenylalanine (FmocFF) in water is widely known to produce hydrogels. Typically, confocal microscopy is used to visualize such hydrogels under wet conditions, i.e. without freezing or drying. However, key aspects of hydrogels like fibre diameter, network morphology and mesh size are sub‐diffraction limited features and cannot be visualized effectively using this approach. In this work, we show that it is possible to image FmocFF hydrogels by Points Accumulation for Imaging in Nanoscale Topography (PAINT) in native conditions and without direct gel labelling. We demonstrate that the fibre network can be visualized with improved resolution (~50 nm) both in 2D and 3D. Quantitative information is extracted such as mesh size and fibre diameter. This method can complement the existing characterization tools for hydrogels and provide useful information supporting the design of new materials

Mechanical characterization of multilayered hydrogels: a rheological study for 3D-printed systems

We describe rheological protocols to study layered and three-dimensional (3D)-printed gels. Our methods allow us to measure the properties at different depths and determine the contribution of each layer to the resulting combined properties of the gels. We show that there are differences when using different measuring systems for rheological measurement, which directly affects the resulting properties being measured. These methods allow us to measure the gel properties after printing, rather than having to rely on the assumption that there is no change in properties from a preprinted gel. We show that the rheological properties of fluorenylmethoxycarbonyl-diphenylalanine (FmocFF) gels are heavily influenced by the printing process

ESTUDIO PROSPECTIVO DE LA LECTURA DE LA TEMPERATURA TIMPÁNICA EN UNA UCI POLIVALENTE.

Es un estudio sobre la lectura de la temperatura timpánica comparándola con otros métodos de temperatura. El objetivo es conocer y determinar temperaturas medias que nos sirvan de referencia así como establecer diferencias con otras variables. Es un estudio prospectivo y observacional realizado en una UCI polivalente pequeña. Se midió la temperatura timpánica en ambos oídos, en axila, en arteria pulmonar y en el box a todos los pacientes posibles. Como resultados se obtuvieron 535 casos, edad media 68 años, 312 varones (58,3%), Temperatura en oído izquierdo (O.I.)37,087ºC, O.D.37, 001ºC, axilar 36,69ºC, arteria pulmonar 37,672ºC. Se obtuvo diferencia estadísticamente significativa entre las distintas lecturas con

Implementation of a multidisciplinary psychoeducational intervention for Parkinson's disease patients and carers in the community: study protocol

Background: Parkinson’s disease progressively limits patients at different levels and as a result family members play a key role in their care. However, studies show lack of an integrative approach in Primary Care to respond to the difficulties and psychosocial changes experienced by them. The aim of this study is to evaluate the effects of a multidisciplinary psychoeducational intervention focusing on improving coping skills, the psychosocial adjustment to Parkinson’s disease and the quality of life in patients and family carers in a Primary Care setting. Methods: This quasi-experimental study with control group and mixed methods was designed to evaluate a multidisciplinary psychoeducational intervention. Based on the study power calculations, 100 people with Parkinson’s disease and 100 family carers will be recruited and assigned to two groups. The intervention group will receive the ReNACE psychoeducational intervention. The control group will be given a general educational programme. The study will be carried out in six community-based health centres. The results obtained from the two groups will be collected for evaluation at three time points: at baseline, immediately after the intervention and at 6 months post-intervention. The results will be measured with these instruments: the Quality of Life Scale PDQ39 for patients and the Scale of Quality of Life of Care-givers SQLC for family carers, and for all participants the Psychosocial Adjustment to Illness scale and the Brief COPE Inventory. Focus groups will be organised with some patients and family carers who will have received the ReNACE psychoeducational intervention and also with the healthcare professionals involved in its development. Discussion: An important gap exists in the knowledge and application of interventions with a psychosocial approach for people with PD and family carers as a whole. This study will promote this comprehensive approach in Primary Care, which will clearly contribute in the existing knowledge and could reduce the burden of PD for patients and family carers, and also in other long-term conditions