4,146 research outputs found
Influence of Adhesion on the Chemical Potential of Supported Nanoparticles as Modeled with Spherical Caps
Existence of multi-site intrinsic localized modes in one-dimensional Debye crystals
The existence of highly localized multi-site oscillatory structures (discrete
multibreathers) in a nonlinear Klein-Gordon chain which is characterized by an
inverse dispersion law is proven and their linear stability is investigated.
The results are applied in the description of vertical (transverse, off-plane)
dust grain motion in dusty plasma crystals, by taking into account the lattice
discreteness and the sheath electric and/or magnetic field nonlinearity.
Explicit values from experimental plasma discharge experiments are considered.
The possibility for the occurrence of multibreathers associated with vertical
charged dust grain motion in strongly-coupled dusty plasmas (dust crystals) is
thus established. From a fundamental point of view, this study aims at
providing a first rigorous investigation of the existence of intrinsic
localized modes in Debye crystals and/or dusty plasma crystals and, in fact,
suggesting those lattices as model systems for the study of fundamental crystal
properties.Comment: 12 pages, 8 figures, revtex forma
Modeling potential hydrochemical responses to climate change and increasing CO2 at the Hubbard Brook Experimental Forest using a dynamic biogeochemical model (PnET-BGC)
Dynamic hydrochemical models are useful tools for understanding and predicting the interactive effects of climate change, atmospheric CO2, and atmospheric deposition on the hydrology and water quality of forested watersheds. We used the biogeochemical model, PnET-BGC, to evaluate the effects of potential future changes in temperature, precipitation, solar radiation, and atmospheric CO2 on pools, concentrations, and fluxes of major elements at the Hubbard Brook Experimental Forest in New Hampshire, United States. Future climate projections used to run PnET-BGC were generated specifically for the Hubbard Brook Experimental Forest with a statistical technique that downscales climate output (e.g., air temperature, precipitation, solar radiation) from atmosphere-ocean general circulation models (AOGCMs) to a finer temporal and spatial resolution. These climate projections indicate that over the twenty-first century, average air temperature will increase at the site by 1.7 degrees C to 6.5 degrees C with simultaneous increases in annual average precipitation ranging from 4 to 32 cm above the long-term mean (1970–2000). PnET-BGC simulations under future climate change show a shift in hydrology characterized by later snowpack development, earlier spring discharge (snowmelt), greater evapotranspiration, and a slight increase in annual water yield (associated with CO2 effects on vegetation). Model results indicate that under elevated temperature, net soil nitrogen mineralization and nitrification markedly increase, resulting in acidification of soil and stream water, thereby altering the quality of water draining from forested watersheds. Invoking a CO2 fertilization effect on vegetation under climate change substantially mitigates watershed nitrogen loss, highlighting the need for a more thorough understanding of CO2 effects on forest vegetation
CFD Simulations of Boundary Layer Transition Flight Experiment Catalytic Coating Data
A CFD analysis is performed to model the catalytic jump in surface heating rates measured as part of the Space Shuttle Boundary Layer Transition (BLT) flight experiment
Space Shuttle Boundary Layer Transition Flight Experiment Ground Testing Overview
In support of the Boundary Layer Transition (BLT) Flight Experiment (FE) Project in which a manufactured protuberance tile was installed on the port wing of Space Shuttle Orbiter Discovery for STS-119, STS- 128, STS-131 and STS-133 as well as Space Shuttle Orbiter Endeavour for STS-134, a significant ground test campaign was completed. The primary goals of the test campaign were to provide ground test data to support the planning and safety certification efforts required to fly the flight experiment as well as validation for the collected flight data. These test included Arcjet testing of the tile protuberance, aerothermal testing to determine the boundary layer transition behavior and resultant surface heating and planar laser induced fluorescence (PLIF) testing in order to gain a better understanding of the flow field characteristics associated with the flight experiment. This paper provides an overview of the BLT FE Project ground testing. High-level overviews of the facilities, models, test techniques and data are presented, along with a summary of the insights gained from each test
Experimental Space Shuttle Orbiter Studies to Acquire Data for Code and Flight Heating Model Validation
In an experimental study to obtain detailed heating data over the Space Shuttle Orbiter, CUBRC has completed an extensive matrix of experiments using three distinct models and two unique hypervelocity wind tunnel facilities. This detailed data will be employed to assess heating augmentation due to boundary layer transition on the Orbiter wing leading edge and wind side acreage with comparisons to computational methods and flight data obtained during the Orbiter Entry Boundary Layer Flight Experiment and HYTHIRM during STS-119 reentry. These comparisons will facilitate critical updates to be made to the engineering tools employed to make assessments about natural and tripped boundary layer transition during Orbiter reentry. To achieve the goals of this study data was obtained over a range of Mach numbers from 10 to 18, with flight scaled Reynolds numbers and model attitudes representing key points on the Orbiter reentry trajectory. The first of these studies were performed as an integral part of Return to Flight activities following the accident that occurred during the reentry of the Space Shuttle Columbia (STS-107) in February of 2003. This accident was caused by debris, which originated from the foam covering the external tank bipod fitting ramps, striking and damaging critical wing leading edge heating tiles that reside in the Orbiter bow shock/wing interaction region. During investigation of the accident aeroheating team members discovered that only a limited amount of experimental wing leading edge data existed in this critical peak heating area and a need arose to acquire a detailed dataset of heating in this region. This new dataset was acquired in three phases consisting of a risk mitigation phase employing a 1.8% scale Orbiter model with special temperature sensitive paint covering the wing leading edge, a 0.9% scale Orbiter model with high resolution thin-film instrumentation in the span direction, and the primary 1.8% scale Orbiter model with detailed thin-film resolution in both the span and chord direction in the area of peak heating. Additional objectives of this first study included: obtaining natural or tripped turbulent wing leading edge heating levels, assessing the effectiveness of protuberances and cavities placed at specified locations on the orbiter over a range of Mach numbers and Reynolds numbers to evaluate and compare to existing engineering and computational tools, obtaining cavity floor heating to aid in the verification of cavity heating correlations, acquiring control surface deflection heating data on both the main body flap and elevons, and obtain high speed schlieren videos of the interaction of the orbiter nose bow shock with the wing leading edge. To support these objectives, the stainless steel 1.8% scale orbiter model in addition to the sensors on the wing leading edge was instrumented down the windward centerline, over the wing acreage on the port side, and painted with temperature sensitive paint on the starboard side wing acreage. In all, the stainless steel 1.8% scale Orbiter model was instrumented with over three-hundred highly sensitive thin-film heating sensors, two-hundred of which were located in the wing leading edge shock interaction region. Further experimental studies will also be performed following the successful acquisition of flight data during the Orbiter Entry Boundary Layer Flight Experiment and HYTHIRM on STS-119 at specific data points simulating flight conditions and geometries. Additional instrumentation and a protuberance matching the layout present during the STS-119 boundary layer transition flight experiment were added with testing performed at Mach number and Reynolds number conditions simulating conditions experienced in flight. In addition to the experimental studies, CUBRC also performed a large amount of CFD analysis to confirm and validate not only the tunnel freestream conditions, but also 3D flows over the orbiter acreage, wing leading edge, and controlurfaces to assess data quality, shock interaction locations, and control surface separation regions. This analysis is a standard part of any experimental program at CUBRC, and this information was of key importance for post-test data quality analysis and understanding particular phenomena seen in the data. All work during this effort was sponsored and paid for by the NASA Space Shuttle Program Office at the Johnson Space Center in Houston, Texas
Gravity and Signature Change
The use of proper ``time'' to describe classical ``spacetimes'' which contain
both Euclidean and Lorentzian regions permits the introduction of smooth
(generalized) orthonormal frames. This remarkable fact permits one to describe
both a variational treatment of Einstein's equations and distribution theory
using straightforward generalizations of the standard treatments for constant
signature.Comment: Plain TeX, 6 pages; to appear in GR
Model-independent extraction of matrix elements from top-quark measurements at hadron colliders
Current methods to extract the quark-mixing matrix element from
single-top production measurements assume that : top quarks decay into quarks with 100% branching fraction,
s-channel single-top production is always accompanied by a quark and
initial-state contributions from and quarks in the -channel
production of single top quarks are neglected. Triggered by a recent
measurement of the ratio
performed by the D0 collaboration, we consider a extraction method
that takes into account non zero d- and s-quark contributions both in
production and decay. We propose a strategy that allows to extract consistently
and in a model-independent way the quark mixing matrix elements ,
, and from the measurement of and from single-top
measured event yields. As an illustration, we apply our method to the Tevatron
data using a CDF analysis of the measured single-top event yield with two jets
in the final state one of which is identified as a -quark jet. We constrain
the matrix elements within a four-generation scenario by combining
the results with those obtained from direct measurements in flavor physics and
determine the preferred range for the top-quark decay width within different
scenarios.Comment: 36 pages, 17 figure
Kinetic Model for Sintering of Supported Metal Particles with Improved Size-Dependent Energetics and Applications to Au on TiO2(110)
Reactivity and Sintering Kinetics of Au/TiO2(110) Model Catalysts: Particle Size Effects
We review here our studies of the reactivity and sintering kinetics of model catalysts consisting of gold nanoparticles dispersed on TiO2(110). First, the nucleation and growth of vapor-deposited gold on this surface was experimentally examined using x-ray photoelectron spectroscopy and low energy ion scattering. Gold initially grows as two-dimensional islands up to a critical coverage, hcr, after which 3D gold nanoparticles grow. The results at different temperatures are fitted well with a kinetic model, which includes various energetic parameters for Au adatom migration. Oxygen was dosed onto the resulting gold nanoparticles using a hot filament technique. The desorption energy of Oa was examined using temperature programmed desorption (TPD). The Oa is bonded ~40% more strongly to smaller (thinner) Au islands. Gaseous CO reacts rapidly with this Oa to make CO2, probably via adsorbed CO. The reactivity of Oa with CO increases with increasing particle size, as expected based on Brønsted relations. Propene adsorption leads to TPD peaks for three different molecularly adsorbed states on Au/TiO2(110), corresponding to propene adsorbed on gold islands, to Ti sites on the substrate, and to the perimeter of gold islands, with adsorption energies of 40, 52 and 73 kJ/mol, respectively. Thermal sintering of the gold nanoparticles was explored using temperature-programmed low-energy ion scattering. These sintering rates for a range of Au loadings at temperatures from 200 to 700 K were well fitted by a theoretical model which takes into consideration the dramatic effect of particle size on metal chemical potential using a modified bond additivity model. When extrapolated to simulate isothermal sintering at 700 K for 1 year, the resulting particle size distribution becomes very narrow. These results question claims that the shape of particle size distributions reveal their sintering mechanisms. They also suggest why the growth of colloidal nanoparticles in liquid solutions can result in very narrow particle size distributions
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