Super-Nernstian Shifts of Interfacial Proton-Coupled Electron Transfers : Origin and Effect of Noncovalent Interactions

The support of the University of Aberdeen is gratefully acknowledged. C.W. acknowledges a summer studentship from the Carnegie Trust for the Universities of Scotland. E.P.M.L. acknowledges SeCYT (Universidad Nacional de Cordoba), ́ CONICET- PIP 11220110100992, Program BID (PICT 2012-2324), and PME 2006-01581 for financial support.Peer reviewedPostprin

Sistema de información geográfica para la generación de mapas temáticos (SIGMAT). Producción de cartografía temática

El Sistema de Información Geográfica para la Generación de Mapas Temáticos (SIGMAT) es una nueva herramienta que incorpora las más avanzadas tecnologías y métodos a la producción de cartografía temática. Mediante la introducción de numerosos asistentes facilita todas las tareas de gestión, elaboración y publicación automatizada de los mapas controlando así el ciclo de vida completo de los mismos. Su diseño permite actualizar automáticamente los mapas cuando cambian los datos vinculados.Geographic Information System for Thematic Map Generation (SIGMAT from spanish) is a new tool that incorporates the most advanced technologies and methods to production in thematic mapping. With the introduction of numerous assistants makes easy all the tasks of management, production and publication of the maps thus controlling the whole life cycle of the same. Its design allows to automatically update the maps when we change the linked data

Global air conditioning performance indicator (ACPI) for buildings, in tropical climate

The selection of the most suitable HVAC technology for buildings, is a complex challenge. Many factors such as, the features of the building, climatic conditions, energy consumption, Indoor Air Quality (IAQ), thermal comfort, regulations, aspects, economic and environmental aspects, all of which are shown on a local and national scope. There is no standard methodology that guarantees a single criterion for the selection of HVAC systems. Therefore, in its solution, as in almost all decision-making problems in the field of engineering, two different aspects are considered, theoretical and practical (Moreno, 2002) [1], thus forming a typical multi-criteria decision problem. This study proposes an integral performance indicator for the selection of air conditioning systems (ACPI), based on the multicriteria method of the Analytic Hierarchy Process (AHP), in order to choose the best HVAC system variant, based on its classification by integrating energy, environmental, and economic criteria. For the definition of the criteria, studies on HVAC system selection were reviewed and classified, applying multi-criteria on methods. The criteria were weighted based on surveys issued by a team made up of Professors/Researchers, architects, engineers, installers and managers linked to the HVAC sector. The ACPI model obtained, shows that the highest weighting corresponds to building energy consumption index 26.6%, IAQ 20.6%, thermal comfort 18.6%, CO2 emissions 12.1%, and finally, investment costs, operation and maintenance costs 11.6% and 10.3% respectively. The proposed ACPI, together with its analysis methodology, will allow researchers, architects, engineers, and government administration, to consider a wide range of alternative HVAC systems applied in buildings. With this, it will be possible to select them based on a decision-making model with a reliable source of information

Energy evaluation and energy savings analysis with the 2 selection of AC systems in an educational building

This paper presents an energy performance assessment on an educational building in Barranquilla, Colombia. The electricity consumption performance was assessed using the software DesignBuilder for two different Air Conditioning (AC) systems. The current electricity intensity is 215.3 kWh/m2 -year and centralized AC systems with individual fan coils and a water chiller share 66% of the total consumption and lighting at 16%. The simulation of the AC technology change to Variable Refrigerant Flow (VRF) resulted in an improvement of 38% in AC energy intensity with 88 kWh/m2 -year and significant savings in electricity consumption and life-cycle cost of AC systems in buildings.Este artículo presenta una evaluación del desempeño energético en un edificio educativo en Barranquilla, Colombia. El rendimiento del consumo de electricidad se evaluó mediante el software DesignBuilder para dos sistemas de aire acondicionado (AC) diferentes. La intensidad actual de la electricidad es 215,3 kWh / m2-año y sistemas de aire acondicionado centralizados con fan coils individuales y un enfriador de agua compartido 66% del consumo total e iluminación al 16%. La simulación de la tecnología AC cambia a El flujo de refrigerante variable (VRF) resultó en una mejora del 38% en la intensidad de energía de CA con 88 kWh / m2 al año y ahorros significativos en el consumo de electricidad y el costo del ciclo de vida de los sistemas de CA en edificios

Ultralow power voltage reference circuit for implantable devices in standard CMOS technology

This is the peer reviewed version of the following article: Óscar Pereira-Rial, Paula López, Juan M. Carrillo, Victor M. Brea and Diego Cabello (2019) Ultralow power voltage reference circuit for implantable devices in standard CMOS technology. International journal of circuit theory and applications, 47 (7), 991-1005, which has been published in final form at https://doi.org/10.1002/cta.2643. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived VersionsAn ultralow power CMOS voltage reference for body implantable devices is presented in this paper. The circuit core consists of only regular threshold voltage PMOS transistors, thus leading to a very reduced output voltage dispersion, defined as σ/μ, and extremely low power consumption. A mathematical model of the generated reference voltage was obtained by solving circuit equations, and its numerical solution has been validated by extensive electrical simulations using a commercial circuit simulator. The proposed solution incorporates a passive RC low‐pass filter, to enhance power supply rejection (PSR) over a wide frequency range, and a speed‐up section, to accelerate the switching‐on of the circuit. The prototype was implemented in 0.18 μm standard CMOS technology and is able to operate with supply voltages ranging from 0.7 to 1.8 V providing a measured output voltage value of 584.2 mV at the target temperature of 36° C. The measured σ/μ dispersion of the reference voltage generated is 0.65% without the need of trimming. At the minimum supply of 0.7 V, the experimental power consumption is 64.5 pW, while the measured PSR is kept below –60 dB from DC up to the MHz frequency rangeThis work has been partially funded by the Spanish government projects TEC2015‐66878‐C3‐3‐R (MINECO/FEDER) and RTI2018‐097088‐B‐C32 (FEDER), by the Xunta de Galicia under project ED431C2017/69, by the Consellería de Cultura, Educación e Ordenación Universitaria (accreditation 2016‐2019, ED431G/08 and reference competitive group 2017‐2020, ED431C 2017/69), by the Junta de Extremadura R&D Plan, and the European Fund for Regional Development (EFRD) under Grant IB18079S

Cleaner production for achieving the sustainable development goals

Cleaner production is a lively concept in which new procedures and technologies constantly emerge introducing methods and practices to prevent damages to the environment. A broad range of cleaner production initiatives contribute to sustainable development not only through the efficient management of resources and energy, but also through the development of new and smart technologies, new ways of assisting policies development, and organizing supply chains, sectors and individual companies. The authors of this Virtual Special Issue sought to introduce first-hand knowledge and discussions identifying and highlighting the ways cleaner production can contribute to reach the United Nations sustainable development targets. The intent of the Virtual Special Issue is to provide an overview of the recent trends that cleaner production practitioners/researchers are following in the chase of the sustainable development goals, and in this context, this editorial was designed to summarize and underscore the link between cleaner production concepts and practices and the sustainable development goals. An adequate response to this challenge required scientific knowledge and reassessment of the papers ensuring that the science is responsive to the evolving needs of sustainable development. This Virtual Special Issue of the Journal of Cleaner Production is mainly dedicated to the 7th International Workshop on Advances in Cleaner Production, held at Universidad de La Costa, Barranquilla, Colombia on 21–22 June 2018. Based upon the examination of the papers of this Virtual Special Issue, the authors were able to establish that there is an pressing need for research on the assessment on which/when cleaner production interventions are more effective; inter and multidisciplinary cooperation among social and technical scientists to distinguish and address the cleaner production/sustainable development goals interactions and connect cleaner production solutions and large-scale sustainability approaches

Evaluación de fallas en un transportador de cangilones. Caso de estudio

A failure in the bottom sheet of a bucket conveyor (KZBQ.AUMUND) during service was investigated. Sheets are coupled to the chain throught a screw connection; they operate in variable load scenarios causing fatigue. A chemical and microstructural analysis was made showing that sheet was built in steel with 0.15 % of Carbone without alloying elements that contribute to the refined grain and resistance increase. Strength calculation, used to determinate safety factor, consider load system and type material. Results concluded that geometry and thickness value do not provide an adequate fatigue resistance coefficient.Es investigada la falla en las láminas del fondo de un transportador de cangilones KZB-Q.AUMUND durante su servicio. Las láminas están acopladas a una cadena a través de uniones atornilladas y operan bajo un régimen de cargas variables causándoles fatiga. Se realiza un análisis químico y microestructural el cual evidencia que las láminas fueron elaboradas de un acero con 0,15 % de carbono sin elementos de aleación que contribuyan al afinamiento del grano y al incremento de la resistencia. Se calculan las tensiones para determinar el coeficiente de seguridad a la fatiga considerando el sistema de cargas y el material de las láminas. Los resultados concluyen que la geometría y los valores de espesor no le proporcionan a las láminas un adecuado coeficiente de resistencia a la fatiga

Microwave-driven synthesis of bisphosphonate nanoparticles allows in vivo visualisation of atherosclerotic plaque

A fast and reproducible microwave-driven process has allowed us to synthesise neridronate-functionalised nanoparticles. Contrary to tradition, the phosphate groups decorate the outside layer of the particles providing Ca2+ binding properties in vitro and selective accumulation in vivo in the atheroma plaque. In vivo and ex vivo detection by T2-weighted MRI is demonstrated and validated by histology. The accumulation in the plaque takes place in less than one hour following the intravenous injection, which is particularly suitable for clinical applications

Automated Generation of Clinical Reports Using Sensing Technologies with Deep Learning Techniques

This study presents a pioneering approach that leverages advanced sensing technologies and data processing techniques to enhance the process of clinical documentation generation during medical consultations. By employing sophisticated sensors to capture and interpret various cues such as speech patterns, intonations, or pauses, the system aims to accurately perceive and understand patient–doctor interactions in real time. This sensing capability allows for the automation of transcription and summarization tasks, facilitating the creation of concise and informative clinical documents. Through the integration of automatic speech recognition sensors, spoken dialogue is seamlessly converted into text, enabling efficient data capture. Additionally, deep models such as Transformer models are utilized to extract and analyze crucial information from the dialogue, ensuring that the generated summaries encapsulate the essence of the consultations accurately. Despite encountering challenges during development, experimentation with these sensing technologies has yielded promising results. The system achieved a maximum ROUGE-1 metric score of 0.57, demonstrating its effectiveness in summarizing complex medical discussions. This sensor-based approach aims to alleviate the administrative burden on healthcare professionals by automating documentation tasks and safeguarding important patient information. Ultimately, by enhancing the efficiency and reliability of clinical documentation, this innovative method contributes to improving overall healthcare outcomes.We would like to thank “A way of making Europe” European Regional Development Fund (ERDF) and MCIN/AEI/10.13039/501100011033 for supporting this work under the “CHAN-TWIN” project (grant TED2021-130890B-C21. HORIZON-MSCA-2021-SE-0 action number: 101086387, REMARKABLE, Rural Environmental Monitoring via ultra wide-ARea networKs And distriButed federated Learning; CIAICO/2022/132 Consolidated group project “AI4Health” funded by the Valencian government and International Center for Aging Research ICAR funded project “IASISTEM.” This work has also been supported by a Valencian government grant for PhD studies, CIACIF/2022/175 and a research initiation grant from the University of Alicante, AII23-12