1,845 research outputs found

    The generalized parton distributions of the nucleon in the NJL model based on the Faddeev approach

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    We study the generalized parton distributions, including the helicity-flip ones, using Nambu-Jona-Lasinio model based on a relativistic Faddeev approach with `static approximation'. Sum rules relating the generalized parton distributions to nucleon electromagnetic form factors are satisfied. Moreover, quark-antiquark contributions in the region ξ<x<ξ-\xi<x<\xi are non-vanishing. Our results are qualitatively similar to those calculated with Radyushkin's double distribution ansatz using forward parton distribution functions calculated in the NJL model as inputs.Comment: 35 pages, 15 figure

    Multi-Threshold Level Set Model for Image Segmentation

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    A multi-threshold level set model for image segmentations is presented in the paper. The multi-threshold level set formulation uses a speed function for stopping the locations of the active contours. The speed function with multiple thresholds is designed for detecting boundaries of multiple regions of interest (ROI) in images. These thresholds can be automatically obtained by Fuzzy C-means method. The experimental results show that the proposed method is able to capture boundaries of multiple regions of interest

    Rhenium complex as emitting material in highly efficient phosphorescent organic light-emitting diodes

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    Interest in luminescent materials able to efficiently emit in the solid state is continuously growing, because in most applications the dyes are used as solid films. This is the case of the Organic Light Emitting Diodes (OLEDs), where electroluminescent metal complexes have been widely investigated as dopants, able to increase their performances [1]. We present here a dinuclear Re(I) complexes (1, see Scheme 1) whose emission is higher in solid state and in PMMA matrix than in solution and is used as dopant in OLEDs. This complex belong to the family of neutral Re(I) complexes with general formula [Re2(CO)6(\u3bc-1,2-diazine)(\u3bc-X)2], where X is halogen. Some of them have recently gained interest for their intense yellow/green emission, occurring from triplet metal-to-ligand charge transfer (3MLCT) states [2], showing a modulation effect of the diazine substituents on wavelengths, lifetimes and quantum yields of the emission. \u3a6 up to 0.53 has been measured for the di-chloro complexes containing diazines bearing alkyl groups in both the \u3b2 positions [3]. At variance with the chloro derivatives, the bromo analogue 1 is almost not-emitting in solution (\u3a6em 0.002 in deareated toluene). We have now found that in the solid state 1 shows intense yellow-orange emission (\u3a6em 0.50 in neat powder), blue shifted with respect to the solution (560 nm vs. 620 nm). The emission is intense also in PMMA matrix (\u3a6em 0.19 in PMMA at 10% w/w, 556 nm). This very high aggregated emission here is discussed in terms of the restriction of the intramolecular roto-vibrational motions of the \u201cRe2(CO)6(\u3bc-Br)2\u201d scaffold imposed by the rigid environment, as evidenced by the strong decrease of the knr. Moreover a parallel increase of kr is noticed, which clearly shows the influence of the halides in determining not only the energy of the excited state, but also the nature of the lowest (emitting) state. These properties allowed its successful use as a phosphorescent dopant in OLEDs and here we report the performances of OLED devices prepared both by solution- and vacuumprocessing. The values of the external quantum efficiency are 1.7% (4.3 cd/A and 1.7 lm/W) and 10% (29.1 cd/A and 22.1 lm/W) respectively and are the highest ever reported for rhenium-based devices, comparable to state-of-the-art devices employing Ir(III)- and Pt(II)- based metal complexes. The combination of synthetic strategy and encouraging results in potential OLEDs applications should make these dinuclear Re(I) complexes highly attractive to a broad spectrum of research fields. 1. \u201cHighly efficient OLEDs with Phosphorescent Materials\u201d H. Yersin Ed. Wiley-VCH, (2008). 2. D. Donghi, G. D\u2019Alfonso, M. Mauro, M. Panigati, P. Mercandelli, A. Sironi, P. Mussini, L. D\u2019Alfonso, Inorg. Chem. 28 (2008) 4243-4255. 3. M. Mauro, E. Quartapelle Procopio, Y. Sun, C. H. Chien, D. Donghi, M. Panigati, P. Mercandelli, P. Mussini, G. D\u2019Alfonso, L. De Cola, Adv. Funct. Mater. 19 (2009) 2607-2614

    Surfactant-mediated growth of semiconductor materials

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    During epitaxial growth of semiconducting materials using either molecular beam epitaxy or organometallic vapour deposition, the addition of a surfactant can enhance two-dimensional layer-by-layer growth. This modified growth process is now called the surfactant-mediated growth (SMG) method. It has had an important impact on the development of technologically important materials in device applications, such as heterostructures used for laser applications. Recent developments that use surfactants to improve doping profiles in semiconducting systems and antisurfactants (ASMG) to grow quantum dots further ensure that SMG/ASMG will play a major role in the future development of optoelectronic materials and nanoparticles. In this paper, we review important earlier experimental work involving the SMG method as well as some recent developments. Theoretical work involving first-principles methods and kinetic Monte Carlo simulations are discussed but confined only to the surfactant effect

    Aldose Reductase Genotypes and Cardiorenal Complications: An 8-year prospective analysis of 1,074 type 2 diabetic patients

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    OBJECTIVE—We report the independent risk association of type 2 diabetic nephropathy with the z−2 allele of the 5′-(CA)n microsatellite and C-106T promoter polymorphisms of the aldose reductase gene (ALR2) using a case-control design. In this expanded cohort, we examined their predictive roles on new onset of cardiorenal complications using a prospective design

    Optical Properties and Enhanced Photothermal Conversion Efficiency of SiO2/A-Dlc Selective Absorber Films for A Solar Energy Collector Fabricated by Unbalance Sputter

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    AbstractSolar energy could become the most attractive alternative energy source. In this study we test an attractive new candidate material for solar energy collectors. It can be found that the higher the gas pressure is, the higher the sp2/sp3 area ratio, the greater the sputtering rate and the greater the optical absorption. The photothermal conversion efficiency of a SiO2 coating on the amorphous diamond-like carbon (a-DLC) selective absorber films deposited on the Cr/mirror like Al substrate is 93.2% as the film thickness of a SiO2 coating is 105nm. The coatings also increase the protective properties for a longer service life. This makes the SiO2 coated a-DLC film a promising new candidate material for solar selective absorber films. The SiO2/a-DLC selective absorber films also were deposited on the Al extrusion substrates

    The Localization of ss-Wave and Quantum Effective Potential of a Quasi-Free Particle with Position-Dependent Mass

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    The properties of the s-wave for a quasi-free particle with position-dependent mass(PDM) have been discussed in details. Differed from the system with constant mass in which the localization of the s-wave for the free quantum particle around the origin only occurs in two dimensions, the quasi-free particle with PDM can experience attractive forces in DD dimensions except D=1 when its mass function satisfies some conditions. The effective mass of a particle varying with its position can induce effective interaction which may be attractive in some cases. The analytical expressions of the eigenfunctions and the corresponding probability densities for the s-waves of the two- and three-dimensional systems with a special PDM are given, and the existences of localization around the origin for these systems are shown.Comment: 12pages, 8 figure

    Electronic and magnetic properties of zinc blende half-metal superlattices

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    Zinc blende half-metallic compounds such as CrAs, with large magnetic moments and high Curie temperatures, are promising materials for spintronic applications. We explore layered materials, consisting of alternating layers of zinc blende half-metals, by first principles calculations, and find that superlattices of (CrAs)1(MnAs)1 and (CrAs)2(MnAs)2 are half-metallic with magnetic moments of 7.0mB and 14.0mB per unit cell, respectively. We discuss the nature of the bonding and half-metallicity in these materials and, based on the understanding acquired, develop a simple expression for the magnetic moment in such materials. We explore the range of lattice constants over which half-metallicity is manifested, and suggest corresponding substrates for growth in thin film form

    Six low-strain zinc-blende half metals: An ab initio investigation

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    A class of spintronic materials, the zinc-blende (ZB) half metals, has recently been synthesized in thin-film form. We apply all-electron and pseudopotential ab initio methods to investigate the electronic and structural properties of ZB Mn and Cr pnictides and carbides, and find six compounds to be half metallic at or near their respective equilibrium lattice constants, making them excellent candidates for growth at low strain. Based on these findings, we further propose substrates on which the growth may be accomplished with minimum strain. Our findings are supported by the recent successful synthesis of ZB CrAs on GaAs and ZB CrSb on GaSb, where our predicted equilibrium lattice constants are within 0.5% of the lattice constants of the substrates on which the growth was accomplished. We confirm previous theoretical results for ZB MnAs, but find ZB MnSb to be half metallic at its equilibrium lattice constant, whereas previous work has found it to be only nearly so. We report here two low-strain half metallic ZB compounds, CrP and MnC, and suggest appropriate substrates for each. Unlike the other five compounds, we predict ZB MnC to become/remain half metallic with compression rather than expansion, and to exhibit metallicity in the minority-rather than majority-spin channel. These fundamentally different properties of MnC can be connected to substantially greater p-d hybridization and d-d overlap, and correspondingly larger bonding-antibonding splitting and smaller exchange splitting. We examine the relative stability of each of the six ZB compounds against NiAs and MnP structures, and find stabilities for the compounds not yet grown comparable to those already grown
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