Sustainable landfill leachate treatment using refuse and pine bark as a carbon source for biodenitrification

Raw and 10-week composted commercial garden refuse (CGR) materials and pine bark (PB) mulch were evaluated for their potential use as alternative and sustainable sources of carbon for landfill leachate bio-denitrification. Dynamic batch tests using synthetic nitrate solutions of 100, 500 and 2000 mg NO3 L−1 were used to investigate the substrate performance at increasing nitrate concentrations under optimal conditions. Further to this, sequential batch tests using genuine nitrified landfill leachate with a concentration of 2000 mg NO3 L−1 were carried out to evaluate substrates behaviour in the presence of a complex mixture of chemicals present in leachate. Results showed that complete denitrification occurred in all conditions, indicating that raw and composted CGR and PB can be used as sustainable and efficient media for landfill leachate bio-denitrification. Of the three substrates, raw garden refuse yields the fastest denitrification rate followed by 10-week composted CGR and PB. However, the efficiency of the raw CGR was lower when using genuine leachate, indicating the inhibitory effect of components of the leachate on the denitrification process. Ten-week composted CGR performed optimally at low nitrate concentrations, while poor nitrate removal ability was found at higher nitrate concentrations (2000 mg L−1). In contrast, the PB performance was 3.5 times faster than that of the composted garden refuse at higher nitrate concentrations. Further to this, multi-criteria analysis of the process variables provided an easily implementable framework for the use of waste materials as an alternative and sustainable source of carbon for denitrification

Long-term emissions from mechanically biologically treated waste: Influence on leachate quality – Part II

Mechanical biological pretreatment of waste prior to disposal is proven to effectively reduce the long-term polluting potentials of landfilled waste. The combined effect of waste pretreatment and flushing, as is possible in landfills operated in tropical or sub-tropical countries, has the potential to further reduce the landfills’ environmental impact. In this study, long-term emissions from pretreated waste were monitored in anaerobic leaching columns operated at increasing liquid-to-solid ratios. The efficiency of the pretreatment, conducted in full-scale passively aerated windrows, was assessed by comparing different treatment periods (8 and 16 weeks). In order to understand the influence of sorting (separated collection) on the pretreatment, the treated waste was sieved in a 50mm diameter sieve and the coarse and fine fractions separately analysed in the leaching columns. The results showed that treating the waste markedly reduces the COD and NH3-N loadings while the coarse fractions show a greater long-term pollutant risk.Keywords: mechanical biological waste treatment, flushing, leaching columns, bioreactor landfill, leachat

Evaluating leachate recirculation with cellulase addition to enhance waste biostabilisation and landfill gas production

The effect of leachate recirculation with cellulase augmentation on municipal solid waste (MSW) biostabilisation and landfill gas production was investigated using batch bioreactors to determine the optimal conditions of moisture content, temperature and nutrients. Experimentation was thereafter scaled-up in 7 L bioreactors. Three conditions were tested including (1) leachate recirculation only, (2) leachate recirculation with enzyme augmentation and (3) no leachate recirculation (control). Cumulative biogas production of the batch tests indicated that there was little difference between the leachate and control test conditions, producing on average 0.043 m3 biogas kg−1 waste. However the addition of cellulase at 15 × 106 U tonne−1 waste doubled the biogas production (0.074 m3 biogas kg−1 waste). Similar trend was observed with the bioreactors. Cellulase addition also resulted in the highest COD reduction in both the waste and the leachate samples (47% and 42% COD reduction, respectively). In both cases, the quantity of biogas produced was closer to the lower value of theoretical and data-based biogas prediction indicators (0.05–0.4 m3 biogas kg−1 waste). This was likely due to a high concentration of heavy metals present in the leachate, in particular Cr and Mn, which are known to be toxic to methanogens. The cost-benefit analysis (CBA) based on the settings of the study (cellulase concentration of 15 × 106 U tonne−1 waste) showed that leachate bioaugmentation using cellulase is economically viable, with a net benefit of approximately €12.1 million on a 5 Mt mixed waste landfill

Compositional and physicochemical changes in waste materials and biogas production across 7 landfill sites in UK

The aim of this study was to evaluate the spatial distribution of the paper and fines across seven landfill sites (LFS) and assess the relationship between waste physicochemical properties and biogas production. Physicochemical analysis of the waste samples demonstrated that there were no clear trends in the spatial distribution of total solids (TS), moisture content (MC) and waste organic strength (VS) across all LFS. There was however noticeable difference between samples from the same landfill site. The effect of landfill age on waste physicochemical properties showed no clear relationship, thus, providing evidence that waste remains dormant and non-degraded for long periods of time. Landfill age was however directly correlated with the biochemical methane potential (BMP) of waste; with the highest BMP obtained from the most recent LFS. BMP was also correlated with depth as the average methane production decreased linearly with increasing depth. There was also a high degree of correlation between the Enzymatic Hydrolysis Test (EHT) and BMP test results, which motivates its potential use as an alternative to the BMP test method. Further to this, there were also positive correlations between MC and VS, VS and biogas volume and biogas volume and CH4 content. Outcomes of this work can be used to inform waste degradation and methane enhancement strategies for improving recovery of methane from landfills

On the Angular Resolution of the AGILE gamma-ray imaging detector

We present a study of the Angular Resolution of the AGILE gamma-ray imaging detector (GRID) that is operational in space since April 2007. The AGILE instrument is made of an array of 12 planes each equipped with a Tungsten converter and Silicon micros trip detectors and is sensitive in the energy range 50 MeV - 10 GeV. Among the space instruments devoted to gamma-ray astrophysics, AGILE uniquely exploits an analog readout system with dedicated electronics coupled with Silicon detectors. We show the results of Monte Carlo simulations carried out to reproduce the gamma-ray detection by the GRID, and we compare them to in-flight data. We use the Crab (pulsar + Nebula) system for discussion of real data performance, since its E^{-2} energy spectrum is representative of the majority of gamma-ray sources. For Crab-like spectrum sources, the GRID angular resolution (FWHM of ~4deg at 100 MeV; ~0.8deg at 1 GeV; ~0.9deg integrating the full energy band from 100 MeV to tens of GeV) is stable across a large field of view, being characterized by a flat response up to 30deg off-axis. A comparison of the angular resolution obtained by the two operational gamma-ray instruments, AGILE-GRID and Fermi-LAT, is interesting in view of future gamma-ray missions, that are currently under study. The two instruments exploit different detector configurations affecting the angular resolution: the former being optimized in the readout and track reconstruction especially in the low-energy band, the latter in terms of converter thickness and power consumption. We show that, despite these differences, the angular resolution of both instruments is very similar between 100 MeV and a few GeV.Comment: 19 pages, 8 figures, accepted for publication in Ap

The Agile Alert System For Gamma-Ray Transients

In recent years, a new generation of space missions offered great opportunities of discovery in high-energy astrophysics. In this article we focus on the scientific operations of the Gamma-Ray Imaging Detector (GRID) onboard the AGILE space mission. The AGILE-GRID, sensitive in the energy range of 30 MeV-30 GeV, has detected many gamma-ray transients of galactic and extragalactic origins. This work presents the AGILE innovative approach to fast gamma-ray transient detection, which is a challenging task and a crucial part of the AGILE scientific program. The goals are to describe: (1) the AGILE Gamma-Ray Alert System, (2) a new algorithm for blind search identification of transients within a short processing time, (3) the AGILE procedure for gamma-ray transient alert management, and (4) the likelihood of ratio tests that are necessary to evaluate the post-trial statistical significance of the results. Special algorithms and an optimized sequence of tasks are necessary to reach our goal. Data are automatically analyzed at every orbital downlink by an alert pipeline operating on different timescales. As proper flux thresholds are exceeded, alerts are automatically generated and sent as SMS messages to cellular telephones, e-mails, and push notifications of an application for smartphones and tablets. These alerts are crosschecked with the results of two pipelines, and a manual analysis is performed. Being a small scientific-class mission, AGILE is characterized by optimization of both scientific analysis and ground-segment resources. The system is capable of generating alerts within two to three hours of a data downlink, an unprecedented reaction time in gamma-ray astrophysics.Comment: 34 pages, 9 figures, 5 table

IXPE Mission System Concept and Development Status

The Goal of the Imaging X-Ray Polarimetry Explorer (IXPE) Mi SMEX), is to expand understanding of high-energy astrophysical processes and sources, in support of NASAs first science objective in Astrophysics: Discover how the universe works. IXPE, an international collaboration, will conduct X-ray imaging polarimetry for multiple categories of cosmic X-ray sources such as neutron stars, stellar-mass black holes, supernova remnants and active galactic nuclei. The Observatory uses a single science operational mode capturing the X-ray data from the targets. The IXPE Observatory consists of spacecraft and payload modules built up in parallel to form the Observatory during system integration and test. The payload includes three X-ray telescopes each consisting of a polarization-sensitive, gas pixel X-ray detector, paired with its corresponding grazing incidence mirror module assembly (MMA). A deployable boom provides the correct separation (focal length) between the detector units (DU) and MMAs. These payload elements are supported by the IXPE spacecraft which is derived from the BCP-small spacecraft architecture. This paper summarizes the IXPE mission science objectives, updates the Observatory implementation concept including the payload and spacecraft ts and summarizes the mission status since last years conference

Sardinia Radio Telescope observations of Local Group dwarf galaxies -- I. The cases of NGC6822, IC1613, and WLM

Almost all dwarf galaxies in the Local Group that are not satellites of the Milky Way or M31, belong to either one of two highly-symmetric planes. It is still a matter of debate, whether these planar structures are dynamically stable or whether they only represent a transient alignment. Proper motions, if they could be measured, could help to discriminate between these scenarios. Such motions could be determined with multi-epoch Very Long Baseline Interferometry (VLBI) of sources that show emission from water and methanol at frequencies of 22 and 6.7 GHz, respectively. We report searches for such masers. We have mapped three Local Group galaxies, NGC6822, IC1613 and WLM in the bands covering the water vapor and methanol lines. These systems are members of the two above mentioned planes of galaxies. We have produced deep radio continuum (RC) maps and spectral line cubes. The former have been used to identify star forming regions and to derive global galactic star formation rates (SFRs). These SFRs turn out to be lower than those determined at other wavelengths in two of our sources. This indicates that dwarf galaxies may follow predictions on the RC-SFR relation only in individual regions of enhanced radio continuum emission, but not when considering the entire optical body of the sources. No methanol or water maser emission has been confidently detected, down to line luminosity limits of ~0.004 and 0.01 solar luminosities, respectively. This finding is consistent with the small sizes, low SFRs and metallicities of these galaxies.Comment: 15 pages, 7 figures, accepted for publication by MNRAS. A high-resolution version of the paper can be found at the link http://erg.oa-cagliari.inaf.it/preprints/SRT_LGdwarfs_I.pd