Imaging the symmetry breaking of molecular orbitals in carbon nanotubes

Carbon nanotubes have attracted considerable interest for their unique electronic properties. They are fascinating candidates for fundamental studies of one dimensional materials as well as for future molecular electronics applications. The molecular orbitals of nanotubes are of particular importance as they govern the transport properties and the chemical reactivity of the system. Here we show for the first time a complete experimental investigation of molecular orbitals of single wall carbon nanotubes using atomically resolved scanning tunneling spectroscopy. Local conductance measurements show spectacular carbon-carbon bond asymmetry at the Van Hove singularities for both semiconducting and metallic tubes, demonstrating the symmetry breaking of molecular orbitals in nanotubes. Whatever the tube, only two types of complementary orbitals are alternatively observed. An analytical tight-binding model describing the interference patterns of ? orbitals confirmed by ab initio calculations, perfectly reproduces the experimental results

Assessment of fine scale population genetic diversity and regeneration in Congo basin logged forests

In the Congo Basin most of the light-demanding timber tree species display a deficit of natural regeneration which is a major handicap for sustainable production and certification. Whilst the majority of scientists investigate abiotic and biotic factors explaining that pattern, we hypothesize that tree population density or individual spatial isolation may also affect the tree fitness through inbreeding. In this study, we integrate ecological and genetic approaches to characterize the regeneration potential of a set of priority timber species by (i) estimating pollen dispersal distances at various tree population densities, and (ii) evaluating the impact of increasing spatial isolation on mating characteristics and tree fitness. The ultimate goal is the proposal of minimum population density that prevents inbreeding consequences. Method This ongoing study focuses on 10 timber species (Pericopsis elata, Milicia excelsa, Baillonella toxisperma, Entandrophragma cylindricum, E. utile, E. angolense, E. candollei, Afzelia bipindensis, Erythrophleum suaveloens, Terminalia superba). The data collection was carried out in the logging concession granted to Pallisco in Cameroon. We established two 400-ha plots, where all individuals (DBH > 10 cm) of the target species were inventoried and mapped. A sample of leave or cambium was collected for each of these individuals, as well as for seedlings to characterize patterns of gene flow using genetic tools (nuclear microsatellites). Dispersal agents were identified by direct observations and camera traps. Germination success was characterized in nursery for seeds collected on trees under an increasing isolation gradient. Results Main dispersal agents (wind, bat, rodent) and predators (rodent) were identified for all the species. The gene flow and germination data is still being analyzed and the main results will be presented in the poster. Conclusion Our data will allow characterizing the reproductive biology of a set of important timber species from the Congo basin. These information will strengthen sustainable forest management and the application of certification by adjusting harvesting norms through the use of scientifically-relevant data. In particular, we will tentatively define a maximum distance to be maintained between two adults to allow a qualitative reproduction

The construction of non-spherical models of quasi-relaxed stellar systems

Spherical models of collisionless but quasi-relaxed stellar systems have long been studied as a natural framework for the description of globular clusters. Here we consider the construction of self-consistent models under the same physical conditions, but including explicitly the ingredients that lead to departures from spherical symmetry. In particular, we focus on the effects of the tidal field associated with the hosting galaxy. We then take a stellar system on a circular orbit inside a galaxy represented as a "frozen" external field. The equilibrium distribution function is obtained from the one describing the spherical case by replacing the energy integral with the relevant Jacobi integral in the presence of the external tidal field. Then the construction of the model requires the investigation of a singular perturbation problem for an elliptic partial differential equation with a free boundary, for which we provide a method of solution to any desired order, with explicit solutions to two orders. We outline the relevant parameter space, thus opening the way to a systematic study of the properties of a two-parameter family of physically justified non-spherical models of quasi-relaxed stellar systems. The general method developed here can also be used to construct models for which the non-spherical shape is due to internal rotation. Eventually, the models will be a useful tool to investigate whether the shapes of globular clusters are primarily determined by internal rotation, by external tides, or by pressure anisotropy.Comment: AASTeX v5.2, 37 pages with 2 figures, accepted for publication in The Astrophysical Journa

Efficient Merger of Binary Supermassive Black Holes in Non-Axisymmetric Galaxies

Binary supermassive black holes form naturally in galaxy mergers, but their long-term evolution is uncertain. In spherical galaxies, N-body simulations show that binary evolution stalls at separations much too large for significant emission of gravitational waves (the "final parsec problem"). Here, we follow the long-term evolution of a massive binary in more realistic, triaxial and rotating galaxy models. We find that the binary does not stall. The binary hardening rates that we observe are sufficient to allow complete coalescence of binary SBHs in 10 Gyr or less, even in the absence of collisional loss-cone refilling or gas-dynamical torques, thus providing a potential solution to the final parsec problem.Comment: 5 pages, 3 figure

Effect of angular momentum on equilibrium properties of a self-gravitating system

The microcanonical properties of a two dimensional system of N classical particles interacting via a smoothed Newtonian potential as a function of the total energy E and the total angular momentum L are discussed. In order to estimate suitable observables a numerical method based on an importance sampling algorithm is presented. The entropy surface shows a negative specific heat region at fixed L for all L. Observables probing the average mass distribution are used to understand the link between thermostatistical properties and the spatial distribution of particles. In order to define a phase in non-extensive system we introduce a more general observable than the one proposed by Gross and Votyakov [Eur. Phys. J. B:15, 115 (2000)]: the sign of the largest eigenvalue of the entropy surface curvature. At large E the gravitational system is in a homogeneous gas phase. At low E there are several collapse phases; at L=0 there is a single cluster phase and for L>0 there are several phases with 2 clusters. All these pure phases are separated by first order phase transition regions. The signal of critical behaviour emerges at different points of the parameter space (E,L). We also discuss the ensemble introduced in a recent pre-print by Klinko & Miller; this ensemble is the canonical analogue of the one at constant energy and constant angular momentum. We show that a huge loss of informations appears if we treat the system as a function of intensive parameters: besides the known non-equivalence at first order phase transitions, there exit in the microcanonical ensemble some values of the temperature and the angular velocity for which the corresponding canonical ensemble does not exist, i.e. the partition sum diverges.Comment: 17 pages, 11 figures, submitted to Phys. Rev.

Grain Boundaries in Graphene on SiC(0001ˉ\bar{1}) Substrate

Grain boundaries in epitaxial graphene on the SiC(000$\bar{1}$) substrate are studied using scanning tunneling microscopy and spectroscopy. All investigated small-angle grain boundaries show pronounced out-of-plane buckling induced by the strain fields of constituent dislocations. The ensemble of observations allows to determine the critical misorientation angle of buckling transition $\theta_c = 19 \pm~2^\circ$. Periodic structures are found among the flat large-angle grain boundaries. In particular, the observed $\theta = 33\pm2^\circ$ highly ordered grain boundary is assigned to the previously proposed lowest formation energy structural motif composed of a continuous chain of edge-sharing alternating pentagons and heptagons. This periodic grain boundary defect is predicted to exhibit strong valley filtering of charge carriers thus promising the practical realization of all-electric valleytronic devices

Tuning the Magnetic Anisotropy at a Molecule-Metal Interface

International audienceWe demonstrate that a C 60 overlayer enhances the perpendicular magnetic anisotropy of a Co thin film, inducing an inverse spin reorientation transition from in plane to out of plane. The driving force is the C 60 =Co interfacial magnetic anisotropy that we have measured quantitatively in situ as a function of the C 60 coverage. Comparison with state-of-the-art ab initio calculations show that this interfacial anisotropy mainly arises from the local hybridization between C 60 p z and Co d z 2 orbitals. By generalizing these arguments, we also demonstrate that the hybridization of C 60 with a Fe(110) surface decreases the perpendicular magnetic anisotropy. These results open the way to tailor the interfacial magnetic anisotropy in organic-material–ferromagnet systems

Parallelization, Special Hardware and Post-Newtonian Dynamics in Direct N - Body Simulations

The formation and evolution of supermassive black hole (SMBH) binaries during and after galaxy mergers is an important ingredient for our understanding of galaxy formation and evolution in a cosmological context, e.g. for predictions of cosmic star formation histories or of SMBH demographics (to predict events that emit gravitational waves). If galaxies merge in the course of their evolution, there should be either many binary or even multiple black holes, or we have to find out what happens to black hole multiples in galactic nuclei, e.g. whether they come sufficiently close to merge resulting from emission of gravitational waves, or whether they eject each other in gravitational slingshot interactions

Cours de physique : fondements et applications, Tome 1 : Électronique. Fondements et applications

Public : Étudiants en Licences de physique ou EEA ; Candidats au CAPES et à l'agrégation de physique.Cet ouvrage rassemble, les fondements de l'électronique et ses principales applications. Cet ensemble est présenté pédagogiquement en relation avec les autres domaines de la physique, principalement l'électromagnétisme. Les théorèmes de base sont démontrés (Thévenin, Boucherot, etc.). De nombreux exemples et plus de 250 exercices et problèmes résolus permettent à l'étudiant de valider la compréhension du cours

Physique. Une introduction

Cet ouvrage est une introduction à l'enseignement de la physique, destinée aux étudiants qui abordent des études scientifiques après le baccalauréat. II rassemble, en dix leçons, les bases de la physique déjà vues, et les développe, à l'aide de dix outils mathématiques élémentaires, de dix illustrations informatiques et de cinq ouvertures vers la physique moderne. Le livre s'adresse principalement à tous les étudiants scientifiques entrant dans un établissement d'enseignement supérieur (universités, CPGE, INSA, IUT, etc.). Les auteurs l'ont voulu attractif et moderne ; pour cela, ils se sont appuyés, d'une part sur leur formation de professeurs agrégés de physique, d'autre part sur leurs activités de recherche dans le centre universitaire de Toulouse. En outre, ils l'ont voulu efficace ; pour cette raison, l'ouvrage comporte beaucoup d'exemples concrets, souligne l'intérêt des analyses qualitatives préalables, insiste sur les ordres de grandeur et prolonge chaque leçon par dix travaux dirigés, constitués chacun de dix questions de cours et de dix exercices résolus. Enfin, en raison de son contenu, cette introduction pourrait être utile plus largement à tous ceux, étudiants ou non, physiciens ou non, professionnels de l'enseignement des sciences ou non, qui sont intéressés par la science (physique et sciences spécialisées) et son enseignement