174 research outputs found

    Organic Carbon Burial following the Middle Eocene Climatic Optimum (MECO) in the central - western Tethys

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    We present trace metal geochemistry and stable isotope records for the middle Eocene Alano di Piave section, NE Italy, deposited during magnetochron C18n in the marginal Tethys Ocean. We identify a \sim 500 kyr long carbon isotope perturbation event we infer to be the middle Eocene Climatic Optimum (MECO) confirming the northern hemisphere expression and global occurrence of MECO. Interpreted peak climatic conditions are followed by the rapid deposition of two organic rich intervals (\le3\% TOC) and contemporaneous positive δ13\delta^{13}C excursions. These two intervals are associated with increases in the concentration of sulphur and redox-sensitive trace metals, and low concentrations of Mn, as well as coupled with the occurrence of pyrite. Together these changes imply low, possibly dysoxic, bottom water O2_{2} conditions promoting increased organic carbon burial. We hypothesize that this rapid burial of organic carbon lowered global {\it p}CO2_{2} following the peak warming and returned the climate system to the general Eocene cooling trend

    Mode and tempo of the Paleocene-Eocene thermal maximum in an expanded section from the Venetian pre-Alps.

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    The central part of the Piave River valley in the Venetian pre-Alps of NE Italy exposes an expanded and continuous marine sediment succession that encompasses the Paleocene series and the Paleocene to Eocene transition. The Paleocene through lowermost Eocenemsuccession is >100 m thick and was depositednat middle to lower bathyal depths in a hemipelagic, near-continental setting in the central western Tethys. In the Forada section, the Paleocene succession of limestone-marl couplets is sharply interrupted by an ~3.30- m-thick unit of clays and marls (clay marl unit). The very base of this unit represents the biostratigraphic Paleocene-Eocene boundary, and the entire unit coincides with the main carbon isotope excursion of the Paleocene-Eocene thermal maximum event. Concentrations of hematite and biogenic carbonate, δ13C measurements, and abundance of radiolarians, all oscillate in a cyclical fashion and are interpreted to represent precession cycles. The main excursion interval spans fi ve complete cycles, that is, 105 ± 10 k.y. The overlying carbon isotope recovery interval, which is composed of six distinct limestone-marl couplets, is interpreted to represent six precessional cycles with a duration of 126 ± 12 k.y. The entire carbon isotope excursion interval in Forada has a total duration of ~231 ± 22 k.y., which is 5%–10% longer than previous estimates derived from open ocean sites (210–220 k.y.). Geochemical proxies for redox conditions indicate oxygenated conditions before, during, and after the carbon isotope excursion event. The Forada section exhibits a nonstepped sharp decrease in δ13C (−2.35‰) at the base of the clay marl unit. The hemipelagic, near-continental depositional setting of Forada and the sharply elevated sedimentation rates throughout the clay marl unit argue for continuous rather than interrupted deposition and show that the initial nonstepped carbon isotope shift was not caused by a hiatus. A single sample at the base of the unit lacks biogenic carbonate. Preservation of carbonate thereafter improves progressively up-section in the clay marl unit, which is consistent with a prodigiously abrupt and rapid acidifi cation of the oceans followed by a slower, successive deepening of the carbonate compensation depth. Increased sedimentation rates through the clay marl unit (approximately the main interval of the carbon isotope excursion) are consistent with an intensifi ed hydrological cycle driven by supergreenhouse conditions and enhanced weathering and transport of terrigenous material to this near-continental, hemipelagic environment in the central western Tethys. The sharp transition in lithology from the clay marl unit to the overlying limestonemarl couplets in the recovery interval and the coincident shift toward heavier δ13C values suggest that the silicate pump and continental weathering, the cause of the enhanced terrigenous fl ux to Forada, stopped abruptly. This implies that the source of the light CO2 ceased to be added to the ocean-atmosphere system at the top of the clay marl unit

    Case Report: Could Hennebert's Sign Be Evoked Despite Global Vestibular Impairment on Video Head Impulse Test? Considerations Upon Pathomechanisms Underlying Pressure-Induced Nystagmus due to Labyrinthine Fistula

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    We describe a case series of labyrinthine fistula, characterized by Hennebert's sign (HS) elicited by tragal compression despite global hypofunction of semicircular canals (SCs) on a video-head impulse test (vHIT), and review the relevant literature. All three patients presented with different amounts of cochleo-vestibular loss, consistent with labyrinthitis likely induced by labyrinthine fistula due to different temporal bone pathologies (squamous cell carcinoma involving the external auditory canal in one case and middle ear cholesteatoma in two cases). Despite global hypofunction on vHIT proving impaired function for each SC for high accelerations, all patients developed pressure-induced nystagmus, presumably through spared and/or recovered activity for low-velocity canal afferents. In particular, two patients with isolated horizontal SC fistula developed HS with ipsilesional horizontal nystagmus due to resulting excitatory ampullopetal endolymphatic flows within horizontal canals. Conversely, the last patient with bony erosion involving all SCs developed mainly torsional nystagmus directed contralaterally due to additional inhibitory ampullopetal flows within vertical canals. Moreover, despite impaired measurements on vHIT, we found simultaneous direction-changing positional nystagmus likely due to a buoyancy mechanism within the affected horizontal canal in a case and benign paroxysmal positional vertigo involving the dehiscent posterior canal in another case. Based on our findings, we might suggest a functional dissociation between high (impaired) and low (spared/recovered) accelerations for SCs. Therefore, it could be hypothesized that HS in labyrinthine fistula might be due to the activation of regular ampullary fibers encoding low-velocity inputs, as pressure-induced nystagmus is perfectly aligned with the planes of dehiscent SCs in accordance with Ewald's laws, despite global vestibular impairment on vHIT. Moreover, we showed how pressure-induced nystagmus could present in a rare case of labyrinthine fistulas involving all canals simultaneously. Nevertheless, definite conclusions on the genesis of pressure-induced nystagmus in our patients are prevented due to the lack of objective measurements of both low-acceleration canal responses and otolith function

    A Low Temperature Unitized Regenerative Fuel Cell Realizing 60% Round Trip Efficiency and 10,000 Cycles of Durability for Energy Storage Applications

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    Unitized regenerative fuel cells (URFC) convert electrical energy to and from chemical bonds in hydrogen. URFCs have the potential to provide economical means for efficient long-term, seasonal, energy storage and on-demand conversion back to electrical energy. We first optimize the catalyst layer for discrete electrolyzer and fuel cell and then configure the URFC. Two possible configurations of URFCs are compared, which emphasize the advantages of the unconventional constant-electrode (CE) URFC over the traditional constant-gas (CG) configuration. We also study the stability via accelerated stress tests (ASTs) and demonstrate steady state operation in a daily cycle for day to night energy shifting. The goal is to identify a competitive configuration for URFCs, and demonstrate it in terms of upper limit of round trip efficiencies (RTEs). From the investigations, the optimum composition of the URFC anode catalyst layer is 90 at% Ir-black balanced by Pt-black for both CE and CG configurations. At 80 °C and 1 A/cm2, the optimized CE URFC achieves 58 and 61% RTE with air and O2 as the reductant gases, respectively. We then evaluated the differences in durability using an AST over 10k charge-discharge cycles; the results reveal that the wider potential window at the anode in CE (0.05-1.55 V) has minimal effect on catalyst layer stability compared to CG (0.55-1.55 V). Furthermore, there was no degradation up to the range of 2k-5k cycles; beyond that the fuel cell (discharge) performance degraded while the electrolyzer (charge) performance was still stable. The observations here indicate substantial potential to employ URFCs as efficient and cost-effective bidirectional energy-conversion devices within energy storage and utilization systems after appropriate technological and operational optimizations

    Применение метода контрольных возмущений для определения характерных узлов присоединения комплексной нагрузки при расчетах динамической устойчивости

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    Рассматривается влияние способа замещения комплексной нагрузки на характер электромеханических переходных процессов в электрических системах (ЭС) от действия больших возмущений. Показано, что установить общие рекомендации относительно способа замещения нагрузки в сложных ЭС затруднительно. Предлагается для опреде­ления характерных узлов нагрузки, оказывающих существенное влияние на характер динамического перехода, применять известный метод контрольных возмущений. Приводятся результаты сравнительных расчетов с использованием предлагаемой методики

    Improvement in the Accuracy of Back Trajectories Using WRF to Identify Pollen Sources in Southern Iberian Peninsula

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    Airborne pollen transport at micro-, meso-gamma and meso-beta scales must be studied by atmospheric models, having special relevance in complex terrain. In these cases, the accuracy of these models is mainly determined by the spatial resolution of the underlying meteorological dataset. This work examines how meteorological datasets determine the results obtained from atmospheric transport models used to describe pollen transport in the atmosphere. We investigate the effect of the spatial resolution when computing backward trajectories with the HYSPLIT model. We have used meteorological datasets from the WRF model with 27, 9 and 3 km resolutions and from the GDAS files with 1 ° resolution. This work allows characterizing atmospheric transport of Olea pollen in a region with complex flows. The results show that the complex terrain affects the trajectories and this effect varies with the different meteorological datasets. Overall, the change from GDAS to WRF-ARW inputs improves the analyses with the HYSPLIT model, thereby increasing the understanding the pollen episode. The results indicate that a spatial resolution of at least 9 km is needed to simulate atmospheric flows that are considerable affected by the relief of the landscape. The results suggest that the appropriate meteorological files should be considered when atmospheric models are used to characterize the atmospheric transport of pollen on micro-, meso-gamma and meso-beta scales. Furthermore, at these scales, the results are believed to be generally applicable for related areas such as the description of atmospheric transport of radionuclides or in the definition of nuclear-radioactivity emergency preparedness

    Hierarchical Electrode Design of Highly Efficient and Stable Unitized Regenerative Fuel Cells (URFCs) for Long-term Energy Storage

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    The unitized regenerative fuel cell (URFC) is a promising electrochemical device for intermittent renewable energy storage in chemical bonds. However, widespread application has been hindered due to low round-trip efficiencies

    The Italian arm of the PREPARE study: an international project to evaluate and license a maternal vaccine against group B streptococcus.

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    BACKGROUND: Group B streptococcus (GBS) is a leading cause of sepsis, pneumonia and meningitis in infants, with long term neurodevelopmental sequelae. GBS may be associated with poor pregnancy outcomes, including spontaneous abortion, stillbirth and preterm birth. Intrapartum antibiotic prophylaxis (IAP) is currently the only way to prevent early-onset disease (presenting at 0 to 6 days of life), although it has no impact on the disease presenting over 6 days of life and its implementation is challenging in resource poor countries. A maternal vaccine against GBS could reduce all GBS manifestations as well as improve pregnancy outcomes, even in low-income countries. MAIN BODY: The term "PREPARE" designates an international project aimed at developing a maternal vaccination platform to test vaccines against neonatal GBS infections by maternal immunization. It is a non-profit, multi-center, interventional and experimental study (promoted by the St George University of London. [UK]) with the aim of developing a maternal vaccination platform, determining pregnancy outcomes, and defining the extent of GBS infections in children and mothers in Africa. PREPARE also aims to estimate the protective serocorrelates against the main GBS serotypes that cause diseases in Europe and Africa and to conduct two trials on candidate GBS vaccines. PREPARE consists of 6 work packages. In four European countries (Italy, UK, Netherlands, France) the recruitment of cases and controls will start in 2020 and will end in 2022. The Italian PREPARE network includes 41 centers. The Italian network aims to collect: GBS isolates from infants with invasive disease, maternal and neonatal sera (cases); cord sera and GBS strains from colonized mothers whose infants do not develop GBS infection (controls). SHORT CONCLUSION: PREPARE will contribute information on protective serocorrelates against the main GBS serotypes that cause diseases in Europe and Africa. The vaccine that will be tested by the PREPARE study could be an effective strategy to prevent GBS disease
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