549 research outputs found
Ferromagnetism and Lattice Distortions in the Perovskite YTiO
The thermodynamic properties of the ferromagnetic perovskite YTiO are
investigated by thermal expansion, magnetostriction, specific heat, and
magnetization measurements. The low-temperature spin-wave contribution to the
specific heat, as well as an Arrott plot of the magnetization in the vicinity
of the Curie temperature K, are consistent with a
three-dimensional Heisenberg model of ferromagnetism. However, a magnetic
contribution to the thermal expansion persists well above , which
contrasts with typical three-dimensional Heisenberg ferromagnets, as shown by a
comparison with the corresponding model system EuS. The pressure dependences of
and of the spontaneous moment are extracted using thermodynamic
relationships. They indicate that ferromagnetism is strengthened by uniaxial
pressures and is weakened by uniaxial
pressures and hydrostatic pressure.
Our results show that the distortion along the - and -axes is further
increased by the magnetic transition, confirming that ferromagnetism is favored
by a large GdFeO-type distortion. The c-axis results however do not fit
into this simple picture, which may be explained by an additional
magnetoelastic effect, possibly related to a Jahn-Teller distortion.Comment: 12 pages, 13 figure
Dominance of the planktonic diatom Thalassiosira minima in recent summers in the Bahia Blanca Estuary, Argentina
The diatom Thalassiosira minima was first recorded in the Baha Blanca Estuary in 1992. In 19921993 it exhibited a broad seasonal occurrence. A recent survey (20062007) showed a seasonal appearance restricted mainly to summer together with a greater relative abundance within the phytoplankton. A close connection was found with warmer, more saline and highly turbid conditions experienced in recent summers in the estuary. Whether these changes will impact the estuary trophic dynamics remains an open question
Effect of annealing on the specific heat of optimally doped Ba(FeCo)As
We report the temperature dependence of the low-temperature specific heat
down to 400 mK of the electron-doped Ba(FeCo)As
superconductors. We have measured two samples extracted from the same batch:
first sample has been measured just after preparation with no additional heat
treatment. The sample shows =20 K, residual specific heat
=3.6 mJ/mol K and a Schottky-like contribution at low
temperatures. A second sample has been annealed at 800 for two weeks
and shows = 25 K and =1.4 mJ/mol~K. By subtracting
the lattice specific heat, from pure BaFeAs, the temperature
dependence of the electronic specific heat has been obtained and studied. For
both samples the temperature dependence of clearly indicate the
presence of low-energy excitations in the system. Their specific heat data
cannot be described by single clean s- or d-wave models and the data requires
an anisotropic gap scenario which may or may not have nodesComment: SCES 2010, 5 pages, 2 figure
Superconductivity mediated by a soft phonon mode: specific heat, resistivity, thermal expansion and magnetization of YB6
The superconductor YB6 has the second highest critical temperature Tc among
the boride family MBn. We report measurements of the specific heat,
resistivity, magnetic susceptibility and thermal expansion from 2 to 300 K,
using a single crystal with Tc = 7.2 K. The superconducting gap is
characteristic of medium-strong coupling. The specific heat, resistivity and
expansivity curves are deconvolved to yield approximations of the phonon
density of states, the spectral electron-phonon scattering function and the
phonon density of states weighted by the frequency-dependent Grueneisen
parameter respectively. Lattice vibrations extend to high frequencies >100 meV,
but a dominant Einstein-like mode at ~8 meV, associated with the vibrations of
yttrium ions in oversized boron cages, appears to provide most of the
superconducting coupling and gives rise to an unusual temperature behavior of
several observable quantities. A surface critical field Hc3 is also observed.Comment: 29 pages, 5 tables, 17 figures. Accepted for publication in Phys.
Rev.
MicrografÃa cuantitativa y perfiles de HPLC y FTIR de Melissa officinalis y Nepeta cataria (Lamiaceae) de Argentina
Melissa officinalis L., so called "Melissa" or "Toronjil", is a perennial aromatic herb, whose leaves are used in traditional medicine as a carminative, digestive and sedative, both in simple as in mixtures. Meanwhile, Nepeta cataria L., commonly called "Cat mint" or "Toronjil", with some similar properties, often replacing M. officinalis in the market, although their chemical composition is not completely matched, and contains an iridoid potentially toxic (nepetalactone). It is therefore necessary to establish diacritic parameters to differentiate these species, both at crude drug level, mixtures and extracts. Samples from various sources in Argentina were studied and documental specimens are preserved in the Herbarium UNSL. Anatomical sections were analyzed, and quantitative micrographic parameters were obtained, together with HPLC and FTIR spectra from methanolic and aqueous lyophilized extracts. Significant differences were detected in the prevailing smell foliage, morphology of leaves and inflorescences, trichomata type, palisade ratio, veinlet termination number, rosmarinic acid concentration (with distinctive HPLC profiles), and the CO/CH relationships obtained by FTIR from the extracts, that together allow adequate differentiation of both drugs, even when they were ground or powdered.Melissa officinalis L., llamada vulgarmente "melisa" o "toronjil", es una hierba perenne, aromática, cuyas hojas son empleadas en medicina popular como carminativo, digestivo y sedante, tanto en droga simple como en asociación. Por su parte Nepeta cataria L., llamada vulgarmente "menta de los gatos" y también "toronjil", con algunas propiedades similares, sustituye con frecuencia a M. officinalis
en el mercado, aunque su composición quÃmica no es del todo coincidente y contiene un iridoide potencialmente tóxico (nepetalactona). Por ello es necesario establecer parámetros diacrÃticos para diferenciar ambas especies, a nivel de droga cruda, mezclas y extractos. Fueron estudiados especÃmenes de diversas procedencias en
Argentina, y los ejemplares documentales son conservados en el Herbario UNSL.
Se analizaron cortes anatómicos, se registraron los parámetros micrográficos cuantitativos y se obtuvieron espectros de HPLC y FTIR a partir de extractos metanólicos y acuosos liofilizados. Fueron detectadas diferencias significativas
entre ambas especies en cuanto al aroma prevaleciente del follaje, la exomorfologÃa de hojas e inflorescencias, los tipos tricomáticos, la relación de empalizada, el número de terminales de nerviación, la concentración de ácido rosmarÃnico (con perfiles HPLC distintivos), y las relaciones CO/CH obtenidas por FTIR a partir de los extractos, caracteres que en conjunto permiten una diferenciación adecuada de ambas drogas, aún cuando se presenten molidas o reducidas a polvo.Fil: Petenatti, Marta E..
Universidad Nacional de San LuisFil: Gette, MarÃa A..
Universidad Nacional de San LuisFil: CamÃ, Gerardo E..
Universidad Nacional de San LuisFil: Popovich, Mariana C..
Universidad Nacional de San LuisFil: Marchevsky, Eduardo J..
Universidad Nacional de San LuisFil: Del Vitto, Luis A..
Universidad Nacional de San LuisFil: Petenatti, Elisa M..
Universidad Nacional de San Lui
Large single crystal growth of BaFe1.87Co0.13As2 using a nucleation pole
Co-doped iron arsenic single crystal of BaFe1.87Co0.13As2 with dimension up
to 20 x 10 x 2 mm3 were grown by a nucleation pole: an alumina stick served as
nucleation center during growth. The high quality of crystalline was
illustrated by the measurements of neutron rocking curve and X-ray diffraction
pattern. A very sharp superconducting transition temperature Tc~25 K was
revealed by both resistivity and susceptibility measurements. A nearly 100%
shielding fraction and bulk nature of the superconductivity for the single
crystal were confirmed using magnetic susceptibility data.Comment: 4 pages, 5 figure
Dimensionality Control of Electronic Phase Transitions in Nickel-Oxide Superlattices
The competition between collective quantum phases in materials with strongly
correlated electrons depends sensitively on the dimensionality of the electron
system, which is difficult to control by standard solid-state chemistry. We
have fabricated superlattices of the paramagnetic metal LaNiO3 and the wide-gap
insulator LaAlO3 with atomically precise layer sequences. Using optical
ellipsometry and low-energy muon spin rotation, superlattices with LaNiO3 as
thin as two unit cells are shown to undergo a sequence of collective
metalinsulator and antiferromagnetic transitions as a function of decreasing
temperature, whereas samples with thicker LaNiO3 layers remain metallic and
paramagnetic at all temperatures. Metal-oxide superlattices thus allow control
of the dimensionality and collective phase behavior of correlated-electron
systems
Rare earth magnetism in CeFeAsO: A single crystal study
Single crystals of CeFeAsO, large enough to study the anisotropy of the
magnetic properties, were grown by an optimized Sn-flux technique. The high
quality of our single crystals is apparent from the highest residual
resistivity ratio, RRR = 12, reported among undoped RFeAsO compounds (R=rare
earth) as well as sharp anomalies in resistivity, specific heat, C(T), and
thermal expansion at the different phase transitions. The magnetic
susceptibility chi(T) presents a large easy-plane anisotropy consistent with
the lowest crystal electric field doublet having a dominant Gamma_6 character.
Curie-Weiss like susceptibilities for magnetic field parallel and perpendicular
to the crystallographic c-axis do not reveal an influence of a staggered field
on the Ce site induced by magnetic ordering of the Fe. Furthermore, the
standard signatures for antiferromagnetic order of Ce at T_N = 3.7 K observed
in chi(T) and C(T) are incompatible with a Zeeman splitting Delta = 10 K of the
CEF ground state doublet at low temperature due to the Fe-magnetic order as
previously proposed. Our results can be reconciled with the earlier observation
by assuming a comparatively stronger effect of the Ce-Ce exchange leading to a
reduction of this Zeeman splitting below 15 K.Comment: 15 pages, 6 figures, added section on magn. susceptibilit
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