Conjugated Polymers for Organic Electronics: Structural and Electronic Characteristics

The use of organic materials to design electronic devices has actually presented a broad interest for because they constitute an ecological and suitable resource for our current "electronic world". These materials provide several advantages (low cost, light weight, good flexibility and solubility to be easily printed) that cannot be afforded with silicium. They can also potentially interact with biological systems, something impossible with inorganic devices. Between these materials we can include small molecules, polymers, fullerenes, nanotubes, graphene, other carbon-based molecular structures and hybrid materials. Actually these materials are being used to build electronic structures into electronic devices, like organic light-emitting diodes (OLEDs), organic solar cells (OSCs), and organic field-effect transistors (OFETs), constituting and already commercial reality. Some of them are used on a widespread basis1, and are the focus of some recent researches in molecules2,3 and polymers4-6 suitable for these purposes. In this study we analyze the electronic and molecular characteristics of some different π-conjugated structures in order to evaluate their potential as semiconducting materials for organic electronics. For this purpose we focus on the study of conjugated polymers with different backbones configurations: (i) donor-acceptor configuration, (ii) 1D lineal or 2D branched conjugated backbones, and (iii) encapsulated polymers. To achieve this goal, we use a combined experimental and theoretical approach that includes electronic spectroscopies (i.e., absorption, emission and microsecond transient absorption), vibrational Raman spectroscopy and DFT calculations. These structural modifications are found to provoke a strong impact on the HOMO and LUMO levels and the molecular morphology, and, consequently, on their suitability as semiconductors in organic electronic applications.References 1. S. R. Forrest, M. E. Thompson. Chem. Rev., 2007, 107, 923 2. R. C. González-Cano, G. Saini, J. Jacob, J. T. López Navarrete, J. Casado and M. C. Ruiz Delgado. Chem. Eur. J. 2013, 19, 17165 3. J. L. Zafra, R. C. González-Cano, M. C. Ruiz Delgado, Z. Sun, Y. Li, J. T. López Navarrete, J. Wu and J. Casado. J. Chem. Phys. , 2014, 140, 054706 4. M. Goll, A. Ruff, E. Muks, F. Goerigk, B. Omiecienski, I. Ruff, R. C. González-Cano, J. T. López Navarrete, M. C. Ruiz Delgado, S. Ludwigs. Beilstein J. Org. Chem., 2015, 11, 335. 5. D. Herrero-Carvajal, A. de la Peña, R. C. González-Cano, C. Seoane, J. T. López Navarrete, J. L. Segura, J. Casado, M. C. Ruiz Delgado, J. Phys. Chem. C, 2014, 118, 9899. 6. M. Scheuble, Y. M. Gross, D. Trefz, M. Brinkmann, J. T. López Navarrete, M. C. Ruiz Delgado, and S. Ludwigs, Macromolecules, 2015, 48, 7049.Universidad de Málaga. Campus de Excelencia Internacional Andalucía Tech

A census of ρ\rho Oph candidate members from Gaia DR2

The Ophiuchus cloud complex is one of the best laboratories to study the earlier stages of the stellar and protoplanetary disc evolution. The wealth of accurate astrometric measurements contained in the Gaia Data Release 2 can be used to update the census of Ophiuchus member candidates. We seek to find potential new members of Ophiuchus and identify those surrounded by a circumstellar disc. We constructed a control sample composed of 188 bona fide Ophiuchus members. Using this sample as a reference we applied three different density-based machine learning clustering algorithms (DBSCAN, OPTICS, and HDBSCAN) to a sample drawn from the Gaia catalogue centred on the Ophiuchus cloud. The clustering analysis was applied in the five astrometric dimensions defined by the three-dimensional Cartesian space and the proper motions in right ascension and declination. The three clustering algorithms systematically identify a similar set of candidate members in a main cluster with astrometric properties consistent with those of the control sample. The increased flexibility of the OPTICS and HDBSCAN algorithms enable these methods to identify a secondary cluster. We constructed a common sample containing 391 member candidates including 166 new objects, which have not yet been discussed in the literature. By combining the Gaia data with 2MASS and WISE photometry, we built the spectral energy distributions from 0.5 to 22\microm for a subset of 48 objects and found a total of 41 discs, including 11 Class II and 1 Class III new discs. Density-based clustering algorithms are a promising tool to identify candidate members of star forming regions in large astrometric databases. If confirmed, the candidate members discussed in this work would represent an increment of roughly 40% of the current census of Ophiuchus.Comment: A&A, Accepted. Abridged abstrac

The Urban Unbanked In Mexico And The United States

This paper examines the ways in which lower-income households obtain basic financial services in urban communities in Mexico and the United States. And it discusses the efforts that private sector and government organizations are making to lower the cost or improve the quality of those services. The paper summarizes available information on these issues and assesses the rationale and challenges facing the strategies that both countries are using to improve the financial services available to lower-income households, giving particular attention to unbanked households, meaning households that do not have deposit accounts with any regulated deposit-taking institution, and also to lower-income households in large urban areas. In comparing the experiences of the two countries, the paper reviews the extent to which lower-income households are unbanked, their use of non-bank financial services, and strategies for improving financial services to the unbanked. The underlying differences between the countries\u27 typical household incomes-national income per capita in Mexico in 2002 was US$8,540, compared with$35,060 in the United States (World Bank 2003)-may also influence the difference in percentage of unbanked-9.1 percent of families in the United States compared with 76.4 percent found in a recent study in Mexico City

Relación entre la ganadería extensiva y aves carroñeras en la Sierra de Segura en el marco del proyecto life “acciones para la reintroducción del quebrantahuesos en Andalucía. Perspectivas de futuro

MEDIO RURAL Y SOSTENIBILIDAD IV CONGRESO ANDALUZ DE DESARROLLO SOSTENIBLE VIII CONGRESO ANDALUZ DE CIENCIAS AMBIENTALE

On the critical point structure of eigenfunctions belonging to the first nonzero eigenvalue of a genus two closed hyperbolic surface

We develop a method based on spectral graph theory to approximate the eigenvalues and eigenfunctions of the Laplace-Beltrami operator of a compact riemannian manifold -- The method is applied to a closed hyperbolic surface of genus two -- The results obtained agree with the ones obtained by other authors by different methods, and they serve as experimental evidence supporting the conjectured fact that the generic eigenfunctions belonging to the first nonzero eigenvalue of a closed hyperbolic surface of arbitrary genus are Morse functions having the least possible total number of critical points among all Morse functions admitted by such manifold

Poisson Structures on Trivial Extension Algebras

We present a class of Poisson structures on trivial extension algebras which generalize some known structures induced by Poisson modules. We show that there exists a one-to-one correspondence between such a class of Poisson structures and some data involving (not necessarily flat) contravariant derivatives, and then we give a formulation of this result in terms of Lie algebroids. Some properties of the first Poisson cohomology are also presented. Examples coming from Poisson modules and Poisson submanifolds are given.Comment: 31 page

Distribución del Sn y W en relación con las facies del Batolito de Jálama. Aplicación a la valoración del potencial metalogenético

Este plutón puede incluirse dentro de los granitoides tipo Araya (Corretgé et al. 1985). Se trata de un cuerpo granítico alóctono, de geometría ovoidal y extensión de 220 km2, emplazado en el dominio Epizonal de la Zona Centro Ibérica. Se han diferenciado las siguientes facies (Fig. 1): granitos con sillimanita de grano fino-medio (Gst granito porfídico de dos micas de grano mediogrueso (GP), leucogranito con turmalina (LT) y leucogranitos tardíos (Lt) (Ramirez, 1996). Este plutón presenta mineralizaciones de Sn y intra y extrabatolítica, y raramente de Pb-Zn