Crystal Structures, Local Atomic Environments, and Ion Diffusion Mechanisms of Scandium-Substituted Sodium Superionic Conductor (NASICON) Solid Electrolytes

The importance of exploring new solid electrolytes for all-solid-state batteries has led to significant interest in NASICON-type materials. Here, the Sc3+-substituted NASICON compositions Na3ScxZr2-x(SiO4)2-x(PO4)1+x (termed N3) and Na2ScyZr2-y(SiO4)1-y(PO4)2+y (termed N2) (x, y = 0 – 1) are studied as model Na+-ion conducting electrolytes for solid-state batteries. The influence of Sc3+ substitution on the crystal structures and local atomic environments has been characterized by powder X-ray diffraction (XRD) and neutron powder diffraction (NPD), as well as solid-state 23Na, 31P, and 29Si nuclear magnetic resonance (NMR) spectroscopy. A phase transition between 295 and 473 K from monoclinic C2/c to rhombohedral R c is observed for the N3 compositions, while N2 compositions crystallize in a rhombohedral R c unit cell in this temperature range. Alternating current (AC) impedance spectroscopy, molecular dynamics (MD) and high temperature 23Na NMR are in good agreement, showing that with a higher Sc3+ concentration, the ionic conductivity (about 10-4 S/cm at 473 K) decreases and the activation energy for ion diffusion increases. 23Na NMR experiments indicate that the nature of the Na+-ion motion is two-dimensional on the local atomic scale of NMR though the long-range diffusion pathways are three-dimensional. In addition, a combination of MD, bond valence, maximum entropy/Rietveld and van Hove correlation methods has been used, to reveal that the Na+-ion diffusion in these NASICON materials is three-dimensional and that there is a continuous exchange of sodium between Na(1) and Na(2) sites

Standardizing Type Ia Supernova Absolute Magnitudes Using Gaussian Process Data Regression

We present a novel class of models for Type Ia supernova time-evolving spectral energy distributions (SED) and absolute magnitudes: they are each modeled as stochastic functions described by Gaussian processes. The values of the SED and absolute magnitudes are defined through well-defined regression prescriptions, so that data directly inform the models. As a proof of concept, we implement a model for synthetic photometry built from the spectrophotometric time series from the Nearby Supernova Factory. Absolute magnitudes at peak $B$ brightness are calibrated to 0.13 mag in the $g$-band and to as low as 0.09 mag in the $z=0.25$ blueshifted $i$-band, where the dispersion includes contributions from measurement uncertainties and peculiar velocities. The methodology can be applied to spectrophotometric time series of supernovae that span a range of redshifts to simultaneously standardize supernovae together with fitting cosmological parameters.Comment: 47 pages, 15 figures, accepted for publication by Astrophysical Journa

Atmospheric extinction properties above Mauna Kea from the Nearby Supernova Factory spectro-photometric data set

We present a new atmospheric extinction curve for Mauna Kea spanning 3200--9700 \AA. It is the most comprehensive to date, being based on some 4285 standard star spectra obtained on 478 nights spread over a period of 7 years obtained by the Nearby SuperNova Factory using the SuperNova Integral Field Spectrograph. This mean curve and its dispersion can be used as an aid in calibrating spectroscopic or imaging data from Mauna Kea, and in estimating the calibration uncertainty associated with the use of a mean extinction curve. Our method for decomposing the extinction curve into physical components, and the ability to determine the chromatic portion of the extinction even on cloudy nights, is described and verified over the wide range of conditions sampled by our large dataset. We demonstrate good agreement with atmospheric science data obtain at nearby Mauna Loa Observatory, and with previously published measurements of the extinction above Mauna Kea.Comment: 22 pages, 24 figures, 6 table

Measuring cosmic bulk flows with Type Ia Supernovae from the Nearby Supernova Factory

Context. Our Local Group of galaxies appears to be moving relative to the cosmic microwave background with the source of the peculiar motion still uncertain. While in the past this has been studied mostly using galaxies as distance indicators, the weight of type Ia supernovae (SNe Ia) has increased recently with the continuously improving statistics of available low-redshift supernovae. Aims. We measured the bulk flow in the nearby universe ($0.015 < z < 0.1$) using 117 SNe Ia observed by the Nearby Supernova Factory, as well as the Union2 compilation of SN Ia data already in the literature. Methods. The bulk flow velocity was determined from SN data binned in redshift shells by including a coherent motion (dipole) in a cosmological fit. Additionally, a method of spatially smoothing the Hubble residuals was used to verify the results of the dipole fit. To constrain the location and mass of a potential mass concentration (e.g., the Shapley supercluster) responsible for the peculiar motion, we fit a Hubble law modified by adding an additional mass concentration. Results. The analysis shows a bulk flow that is consistent with the direction of the CMB dipole up to $z \sim 0.06$, thereby doubling the volume over which conventional distance measures are sensitive to a bulk flow. We see no significant turnover behind the center of the Shapley supercluster. A simple attractor model in the proximity of the Shapley supercluster is only marginally consistent with our data, suggesting the need for another, more distant source. In the redshift shell $0.06 < z < 0.1$, we constrain the bulk flow velocity to $< 240~\textrm{km s}^{-1}$ (68% confidence level) for the direction of the CMB dipole, in contradiction to recent claims of the existence of a large-amplitude dark flow.Comment: 12 pages, 5 figures, added corrigendum (http://adsabs.harvard.edu/abs/2015A%26A...578C...1F

Host Galaxy Properties and Hubble Residuals of Type Ia Supernovae from the Nearby Supernova Factory

We examine the relationship between Type Ia Supernova (SN Ia) Hubble residuals and the properties of their host galaxies using a sample of 115 SNe Ia from the Nearby Supernova Factory (SNfactory). We use host galaxy stellar masses and specific star-formation rates fitted from photometry for all hosts, as well as gas-phase metallicities for a subset of 69 star-forming (non-AGN) hosts, to show that the SN Ia Hubble residuals correlate with each of these host properties. With these data we find new evidence for a correlation between SN Ia intrinsic color and host metallicity. When we combine our data with those of other published SN Ia surveys, we find the difference between mean SN Ia brightnesses in low and high mass hosts is 0.077 +- 0.014 mag. When viewed in narrow (0.2 dex) bins of host stellar mass, the data reveal apparent plateaus of Hubble residuals at high and low host masses with a rapid transition over a short mass range (9.8 <= log(M_*/M_Sun) <= 10.4). Although metallicity has been a favored interpretation for the origin of the Hubble residual trend with host mass, we illustrate how dust in star-forming galaxies and mean SN Ia progenitor age both evolve along the galaxy mass sequence, thereby presenting equally viable explanations for some or all of the observed SN Ia host bias.Comment: 20 pages, 11 figures, accepted for publication in Ap

Type Ia Supernova Hubble Residuals and Host-Galaxy Properties

Kim et al. (2013) [K13] introduced a new methodology for determining peak-brightness absolute magnitudes of type Ia supernovae from multi-band light curves. We examine the relation between their parameterization of light curves and Hubble residuals, based on photometry synthesized from the Nearby Supernova Factory spectrophotometric time series, with global host-galaxy properties. The K13 Hubble residual step with host mass is $0.013\pm 0.031$ mag for a supernova subsample with data coverage corresponding to the K13 training; at $\ll 1\sigma$, the step is not significant and lower than previous measurements. Relaxing the data coverage requirement the Hubble residual step with host mass is $0.045\pm 0.026$ mag for the larger sample; a calculation using the modes of the distributions, less sensitive to outliers, yields a step of 0.019 mag. The analysis of this article uses K13 inferred luminosities, as distinguished from previous works that use magnitude corrections as a function of SALT2 color and stretch parameters: Steps at $>2\sigma$ significance are found in SALT2 Hubble residuals in samples split by the values of their K13 $x(1)$ and $x(2)$ light-curve parameters. $x(1)$ affects the light-curve width and color around peak (similar to the $\Delta m_{15}$ and stretch parameters), and $x(2)$ affects colors, the near-UV light-curve width, and the light-curve decline 20 to 30 days after peak brightness. The novel light-curve analysis, increased parameter set, and magnitude corrections of K13 may be capturing features of SN~Ia diversity arising from progenitor stellar evolution.Comment: 17 pages, 6 figures. Accepted by Astrophysical Journa

Evidence of Environmental Dependencies of Type Ia Supernovae from the Nearby Supernova Factory indicated by Local H{\alpha}

(Abridged) We study the host galaxy regions in close proximity to Type Ia supernovae (SNe Ia) to analyze relations between the properties of SN Ia events and environments most similar to where their progenitors formed. We focus on local H\alpha\ emission as an indicator of young environments. The Nearby Supernova Factory has obtained flux-calibrated spectral timeseries for SNe Ia using integral field spectroscopy, allowing the simultaneous measurement of the SN and its immediate vicinity. For 89 SNe Ia we measure H\alpha\ emission tracing ongoing star formation within a 1 kpc radius around each SN. This constitutes the first direct study of the local environment for a large sample of SNe Ia also having accurate luminosity, color and stretch measurements. We find that SNe Ia with local H\alpha\ emission are redder by 0.036+/-0.017 mag, and that the previously-noted correlation between stretch and host mass is entirely driven by the SNe Ia coming from passive regions. Most importantly, the mean standardized brightness for SNe Ia with local H\alpha\ emission is 0.094+/-0.031 mag fainter than for those without. This offset arises from a bimodal structure in the Hubble residuals, that also explains the previously-known host-mass bias. We combine this bimodality with the cosmic star-formation rate to predict changes with redshift in the mean SN Ia brightness and the host-mass bias. This change is confirmed using high-redshift SNe Ia from the literature. These environmental dependences point to remaining systematic errors in SNe Ia standardization. The observed brightness offset is predicted to cause a significant bias in measurements of the dark energy equation of state. Recognition of these effects offers new opportunities to improve SNe Ia as cosmological probes - e.g. SNe Ia having local H\alpha\ emission are more homogeneous, having a brightness dispersion of 0.105+/-0.012 mag.Comment: accepted for publication in Section 3. Cosmology of A&A (The official date of acceptance is 30/08/2013

Host Galaxies of Type Ia Supernovae from the Nearby Supernova Factory

We present photometric and spectroscopic observations of galaxies hosting Type Ia supernovae (SNe Ia) observed by the Nearby Supernova Factory (SNfactory). Combining GALEX UV data with optical and near infrared photometry, we employ stellar population synthesis techniques to measure SN Ia host galaxy stellar masses, star-formation rates (SFRs), and reddening due to dust. We reinforce the key role of GALEX UV data in deriving accurate estimates of galaxy SFRs and dust extinction. Optical spectra of SN Ia host galaxies are fitted simultaneously for their stellar continua and emission lines fluxes, from which we derive high precision redshifts, gas-phase metallicities, and Halpha-based SFRs. With these data we show that SN Ia host galaxies present tight agreement with the fiducial galaxy mass-metallicity relation from SDSS for stellar masses log(M_*/M_Sun)>8.5 where the relation is well-defined. The star-formation activity of SN Ia host galaxies is consistent with a sample of comparable SDSS field galaxies, though this comparison is limited by systematic uncertainties in SFR measurements. Our analysis indicates that SN Ia host galaxies are, on average, typical representatives of normal field galaxies.Comment: 25 pages, 13 figures, accepted for publication in Ap

Analyse préliminaire de la valeur verte pour les logements

Analyse préliminaire de la valeur verte pour les logement

Improving Cosmological Distance Measurements Using Twin Type Ia Supernovae

We introduce a method for identifying "twin" Type Ia supernovae, and using them to improve distance measurements. This novel approach to Type Ia supernova standardization is made possible by spectrophotometric time series observations from the Nearby Supernova Factory (SNfactory). We begin with a well-measured set of supernovae, find pairs whose spectra match well across the entire optical window, and then test whether this leads to a smaller dispersion in their absolute brightnesses. This analysis is completed in a blinded fashion, ensuring that decisions made in implementing the method do not inadvertently bias the result. We find that pairs of supernovae with more closely matched spectra indeed have reduced brightness dispersion. We are able to standardize this initial set of SNfactory supernovae to 0.083 +/- 0.012 magnitudes, implying a dispersion of 0.072 +/- 0.010 magnitudes in the absence of peculiar velocities. We estimate that with larger numbers of comparison SNe, e.g, using the final SNfactory spectrophotometric dataset as a reference, this method will be capable of standardizing high-redshift supernovae to within 0.06-0.07 magnitudes. These results imply that at least 3/4 of the variance in Hubble residuals in current supernova cosmology analyses is due to previously unaccounted-for astrophysical differences among the supernovaeComment: 37 pages, 9 figures, 5 tables. Accepted for publication in ApJ. Fixed typo in arXiv abstrac