3,013 research outputs found
Crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_{4} : role of the orbital degree of freedom
The crystal and magnetic structure of La_{1-x}Sr_{1+x}MnO_4 (0<x<0.7) has
been studied by diffraction techniques and high resolution capacitance
dilatometry. There is no evidence for a structural phase transition like those
found in isostructural cuprates or nickelates, but there are significant
structural changes induced by the variation of temperature and doping which we
attribute to a rearrangement of the orbital occupation.Comment: 8 pages, 6 figures, submitted to PR
Fermat hypersurfaces and Subcanonical curves
We extend the classical Enriques-Petri Theorem to -subcanonical
projectively normal curves, proving that such a curve is -gonal if and
only if it is contained in a surface of minimal degree. Moreover, we show that
any Fermat hypersurface of degree is apolar to an -subcanonical
-gonal projectively normal curve, and vice versa.Comment: 18 pages; AMS-LaTe
Sparsity of integer solutions in the average case
We examine how sparse feasible solutions of integer programs are, on average. Average case here means that we fix the constraint matrix and vary the right-hand side vectors. For a problem in standard form with m equations, there exist LP feasible solutions with at most m many nonzero entries. We show that under relatively mild assumptions, integer programs in standard form have feasible solutions with O(m) many nonzero entries, on average. Our proof uses ideas from the theory of groups, lattices, and Ehrhart polynomials. From our main theorem we obtain the best known upper bounds on the integer Carathéodory number provided that the determinants in the data are small
Evidence for Jahn-Teller distortions at the antiferromagnetic transition in LaTiO
LaTiO is known as Mott-insulator which orders antiferromagnetically at
K. We report on results of thermal expansion and temperature
dependent x-ray diffraction together with measurements of the heat capacity,
electrical transport measurements, and optical spectroscopy in untwinned single
crystals. At significant structural changes appear, which are
volume conserving. Concomitant anomalies are also observed in the
dc-resistivity, in bulk modulus, and optical reflectivity spectra. We interpret
these experimental observations as evidence of orbital order.Comment: 4 pages, 4 figures; published in Phys. Rev. Lett. 91, 066403 (2003
Measurements of O3</sub>, NO<sub>2</sub> and BrO at the Kaashidhoo Climate Observatory (KCO) during the INDOEX (INDian Ocean EXperiment) Campaign using ground based DOAS (Differential Optical Absorption Spectroscopy) and satellite based GOME (Global Ozone Monitoring Experiment) data
International audienceThe INDian Ocean EXperiment (INDOEX) was an international, multi-platform field campaign to measure long-range transport of air masses from South and South-East-(SE) Asia towards the Indian Ocean. During the dry monsoon season between January and March 1999, local measurements were carried out from ground based platforms and were compared with satellite based data. The objective of this study was to characterise stratospheric and tropospheric trace gas amounts in the equatorial region, and to investigate the impact of air pollution at this remote site. For the characterisation of the chemical composition of the outflow from the S-SE-Asian region, we performed ground based dual-axis-DOAS (Differential Optical Absorption Spectroscopy) measurements at the KCO (Kaashidhoo Climate Observatory) in the Maldives (5.0° N, 73.5° E). The ground based dual-axis-DOAS measurements were conducted using two different observation modes (off-axis and zenith-sky). This technique allows the separation of the tropospheric and stratospheric columns for different trace gases like O3 and NO2. These dual-axis DOAS data were compared with O3-sonde measurements performed at KCO and satellite based GOME (Global Ozone Measuring Experiment) data during the intensive measuring phase of the INDOEX campaign in February and March 1999. From GOME observations, tropospheric and stratospheric columns for O3 and NO2 were retrieved. In addition, the analysis of the O3-sonde measurements allowed the determination of the tropospheric O3 amount. The comparison shows that the results of all three measurement systems agree within their error limits. During the INDOEX campaign, background conditions were observed most of the time, but in a single case an increase of tropospheric NO2 during a short pollution event was observed and the impact on the vertical columns was calculated. In the GOME measurements, evidence was found for large tropospheric contributions to the BrO budget, probably located in the free troposphere and present throughout the year. The latter has been investigated by the comparison of satellite pixels influenced by high and low cloud conditions based on GOME data which allows the determination of the detection limit of tropospheric BrO columns
The Hilbert basis method for D-flat directions and the superpotential
We discuss, using the Hilbert basis method, how to efficiently construct a
complete basis for D-flat directions in supersymmetric Abelian and non-Abelian
gauge theories. We extend the method to discrete (R and non-R) symmetries. This
facilitates the construction of a basis of all superpotential terms in a theory
with given symmetries.Comment: 11 pages; a related mathematica code can be found at
http://einrichtungen.ph.tum.de/T30e/codes/NonAbelianHilbert
Quantum Theory Of Atoms In Molecules/charge-charge Flux-dipole Flux Models For Fundamental Vibrational Intensity Changes On H-bond Formation Of Water And Hydrogen Fluoride.
The Quantum Theory of Atoms In Molecules/Charge-Charge Flux-Dipole Flux (QTAIM/CCFDF) model has been used to investigate the electronic structure variations associated with intensity changes on dimerization for the vibrations of the water and hydrogen fluoride dimers as well as in the water-hydrogen fluoride complex. QCISD/cc-pVTZ wave functions applied in the QTAIM/CCFDF model accurately provide the fundamental band intensities of water and its dimer predicting symmetric and antisymmetric stretching intensity increases for the donor unit of 159 and 47 km mol(-1) on H-bond formation compared with the experimental values of 141 and 53 km mol(-1). The symmetric stretching of the proton donor water in the dimer has intensity contributions parallel and perpendicular to its C2v axis. The largest calculated increase of 107 km mol(-1) is perpendicular to this axis and owes to equilibrium atomic charge displacements on vibration. Charge flux decreases occurring parallel and perpendicular to this axis result in 42 and 40 km mol(-1) total intensity increases for the symmetric and antisymmetric stretches, respectively. These decreases in charge flux result in intensity enhancements because of the interaction contributions to the intensities between charge flux and the other quantities. Even though dipole flux contributions are much smaller than the charge and charge flux ones in both monomer and dimer water they are important for calculating the total intensity values for their stretching vibrations since the charge-charge flux interaction term cancels the charge and charge flux contributions. The QTAIM/CCFDF hydrogen-bonded stretching intensity strengthening of 321 km mol(-1) on HF dimerization and 592 km mol(-1) on HF:H2O complexation can essentially be explained by charge, charge flux and their interaction cross term. Atomic contributions to the intensities are also calculated. The bridge hydrogen atomic contributions alone explain 145, 237, and 574 km mol(-1) of the H-bond stretching intensity enhancements for the water and HF dimers and their heterodimer compared with total increments of 149, 321, and 592 km mol(-1), respectively.14008430
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