Analysis of the fume produced during laser-material interactions

The purpose of this research was to improve knowledge of the by-products of laser processing; namely the composition of particles, gases and vapours that are evolved during laser-material interactions. For IR sources, photothermal processes occur and thermal degradation products result, whereas UV lasers may additionally induce photochemical effects. The material investigated was an ITO ink (indium tin oxide nanoparticles in a photo-curable binder and organic solvent) spin-coated onto glass substrates. Thermogravimetric analysis showed that even for temperatures below the upper working limit of the glass substrate, gas-phase products are produced. Laser heating of the binder, 3-methacryloxypropyl-trimethoxysilane (MPTS), in a closed chamber showed that infrared irradiation generates butyl methacrylate. In order to collect a sample representative of the fume entrained in a local exhaust ventilation (LEV) system, an isokinetic arrangement was de- veloped. This balances the volumetric flow rates of the main extraction flow and a sampling tube so that both experience the same flow velocity. Gases were collected with this system into a Tedlar bag and then adsorbed onto a solid phase microextraction (SPME) fibre followed by GC-MS analysis. However, contami- nation from polymers in the sampling system was detected and so a glass/metal construction was utilized in the final version. The gas phase data were inconclusive as no peaks above the detection limits of the equipment could be attributed to laser interactions. The cause of this has been tentatively attributed to excessive dilution of the analytes. Through SEM and EDXA measurements, particulates captured following 130mJ/cm2 XeCl laser irradiation were successfully identified as 40nm ITO particle clusters. It is concluded that the use of a three-stage LEV system is advisable with pre-filter, HEPA filter, and activated charcoal. A flow rate of at least 150m3/hr is recommended, and personal monitoring is advised

Regional variation in the Amitsoq gneisses related to crustal levels during late Archean granulite facies metamorphism: Southern west Greenland

The dominant lithology at Kangimut sangmissoq is described as nebulitic tonalitic gneiss containing highly distended plagioclase phyric amphibolites. The gneiss amphibolite complex was intruded by Nuk gneiss between 3.05 and 2.90 Ga and later (2.6 to 2.7 Ga) by post granulite facies granitoid sheets. The amphibolites are though to be Ameralik dikes and the older gray gneiss are then Amitsoq by definition. The problem arises when the isotopic data are considered, none of which indicate rocks older that about 3.0 Ga

Kinetic study of the pyrolysis of miscanthus and its acid hydrolysis residue by thermogravimetric analysis

The kinetic parameters of the pyrolysis of miscanthus and its acid hydrolysis residue (AHR) were determined using thermogravimetric analysis (TGA). The AHR was produced at the University of Limerick by treating miscanthus with 5 wt.% sulphuric acid at 175 °C as representative of a lignocellulosic acid hydrolysis product. For the TGA experiments, 3 to 6 g of sample, milled and sieved to a particle size below 250 μm, were placed in the TGA ceramic crucible. The experiments were carried out under non-isothermal conditions heating the samples from 50 to 900 °C at heating rates of 2.5, 5, 10, 17 and 25 °C/min. The activation energy (EA) of the decomposition process was determined from the TGA data by differential analysis (Friedman) and three isoconversional methods of integral analysis (Kissinger–Akahira–Sunose, Ozawa–Flynn–Wall, Vyazovkin). The activation energy ranged from 129 to 156 kJ/mol for miscanthus and from 200 to 376 kJ/mol for AHR increasing with increasing conversion. The reaction model was selected using the non-linear least squares method and the pre-exponential factor was calculated from the Arrhenius approximation. The results showed that the best fitting reaction model was the third order reaction for both feedstocks. The pre-exponential factor was in the range of 5.6 × 1010 to 3.9 × 10+ 13 min− 1 for miscanthus and 2.1 × 1016 to 7.7 × 1025 min− 1 for AHR

Strontium and neodymium isotopic variations in early Archean gneisses affected by middle to late Archean high-grade metamorphic processes: West Greenland and Labrador

Relicts of continental crust formed more than 3400 Ma ago are preserved fortuitously in most cratons. The cratons provide the most direct information about crust and mantle evolutionary processes during the first billion years of Earth history. In view of their polymetamorphic character, these terrains are commonly affected by subsequent tectonothermal events. Hence, their isotope systematics may be severely disturbed as a result of bulk chemical change or local isotopic homogenization. This leads to equivocal age and source information for different components within these terrains. The Sr and Nd isotopic data are presented for early Archean gneisses from the North Atlantic Craton in west Greenland and northern Labrador which were affected by younger metamorphic events

Physical pretreatment of biogenic-rich trommel fines for fast pyrolysis

Energy from Waste (EfW) technologies such as fluidized bed fast pyrolysis, are beneficial for both energy generation and waste management. Such technologies, however face significant challenges due to the heterogeneous nature, particularly the high ash contents of some municipal solid waste types e.g. trommel fines. A study of the physical/mechanical and thermal characteristics of these complex wastes is important for two main reasons; (a) to inform the design and operation of pyrolysis systems to handle the characteristics of such waste; (b) to control/modify the characteristics of the waste to fit with existing EFW technologies via appropriate feedstock preparation methods. In this study, the preparation and detailed characterisation of a sample of biogenic-rich trommel fines has been carried out with a view to making the feedstock suitable for fast pyrolysis based on an existing fluidized bed reactor. Results indicate that control of feed particle size was very important to prevent problems of dust entrainment in the fluidizing gas as well as to prevent feeder hardware problems caused by large stones and aggregates. After physical separation and size reduction, nearly 70. wt% of the trommel fines was obtained within the size range suitable for energy recovery using the existing fast pyrolysis system. This pyrolyzable fraction could account for about 83% of the energy content of the 'as received' trommel fines sample. Therefore there was no significant differences in the thermochemical properties of the raw and pre-treated feedstocks, indicating that suitably prepared trommel fines samples can be used for energy recovery, with significant reduction in mass and volume of the original waste. Consequently, this can lead to more than 90% reduction in the present costs of disposal of trommel fines in landfills. In addition, the recovered plastics and textile materials could be used as refuse derived fuel

Phases of granular segregation in a binary mixture

We present results from an extensive experimental investigation into granular segregation of a shallow binary mixture in which particles are driven by frictional interactions with the surface of a vibrating horizontal tray. Three distinct phases of the mixture are established viz; binary gas (unsegregated), segregation liquid and segregation crystal. Their ranges of existence are mapped out as a function of the system's primary control parameters using a number of measures based on Voronoi tessellation. We study the associated transitions and show that segregation can be suppressed is the total filling fraction of the granular layer, $C$, is decreased below a critical value, $C_{c}$, or if the dimensionless acceleration of the driving, $\gamma$, is increased above a value $\gamma_{c}$.Comment: 12 pages, 12 figures, submitted to Phys. Rev.

Valorisation of lignin – Achievements of the LignoValue project

Lignocellulosic biorefinery for production of biofuels, materials and chemicals requires valorization of all fractions including lignin. As a consequence of its poly-aromatic structure, lignin potentially serves as a source for aromatic chemicals. The developed biorefinery concept of the LignoValue project comprises two major steps: (1) Organosolv fractionation of wheat straw and willow into (hemi)cellulose and high purity lignin. (2) Further conversion of the isolated lignin via catalytic pyrolysis, supercritical depolymerization and partial hydrodeoxygenation (HDO) into different components like low molecular phenolic compounds, wood adhesives and fuel additives. The cellulose fraction resulting after organosolv fractionation is effectively hydrolysed by enzymes for biofuel production. Quality assessment of the liberated lignins shows interesting characteristics for follow-up chemistry such as high purity, relatively low molar mass and polydispersity. Catalytic pyrolysis in a fluidised bed at 400-500°C was found to convert organosolv lignin in 35-55% phenolic oil, 10% identified monomeric phenolic compounds, 10-20% water, 5-20% gas and 35-55% char. Supercritical depolymerisation of lignin in carbon dioxide based solvents resulted in a similar spectrum of products, however, at a lower temperature (ca 300°C) but at higher pressures. In both thermochemical processes the use of promotors or catalysts lead to an improved yield of the target monomeric aromatic products. Also the residual char fraction shows interesting properties for use in bio-char applications. Catalytic semi-continuous HDO of lignin in hydrogen atmosphere can be manipulated to yield both light oils or heavy oils as potential additives to fuels. Suitable catalysts were found to convert depolymerised lignin to phenolic oils in high yields. In this process no char formation is observed. The lignin oils were successfully tested on lab scale as partial substitution of phenol in resins for gluing wood panels. The LignoValue concept is critically reviewed in a techno-economic analysis demonstrating the potential for further commercial development and adoptation of this innovative biorefinery process in Europe

Actuator and electronics packaging for extrinsic humanoid hand

The lower arm assembly for a humanoid robot includes an arm support having a first side and a second side, a plurality of wrist actuators mounted to the first side of the arm support, a plurality of finger actuators mounted to the second side of the arm support and a plurality of electronics also located on the first side of the arm support

Robot Arm with Tendon Connector Plate and Linear Actuator

A robotic system includes a tendon-driven end effector, a linear actuator, a flexible tendon, and a plate assembly. The linear actuator assembly has a servo motor and a drive mechanism, the latter of which translates linearly with respect to a drive axis of the servo motor in response to output torque from the servo motor. The tendon connects to the end effector and drive mechanism. The plate assembly is disposed between the linear actuator assembly and the tendon-driven end effector and includes first and second plates. The first plate has a first side that defines a boss with a center opening. The second plate defines an accurate through-slot having tendon guide channels. The first plate defines a through passage for the tendon between the center opening and a second side of the first plate. A looped end of the flexible tendon is received within the tendon guide channels

Potential of Virginia Mallow as an Energy Feedstock

This study aims to compare the potential of Virginia mallow to other high yielding perennial grasses and hardwoods by characterising and comparing fast pyrolysis product yields. Feedstocks selected for this study include miscanthus (Miscanthus x giganteus), Virginia mallow (Sida hermaphrodita), willow short rotation coppice (SRC) (Salix viminalis) and oak (Quercus robur). The experimental work was split into two sections: analytical (Py–GC–MS) and laboratory-scale processing using a 300 g h−1 continuous bubbling fluidised bed reactor. Pyrolysis–gas chromatography–mass spectrometry (Py–GC–MS) has been used to quantify pyrolysis products from these feedstocks by simulating fast pyrolysis heating rates using a CDS 5200 pyrolyser closed coupled to a PerkinElmer Clarus 680 GC–MS. High bio-oil yields were achieved for Virginia mallow, willow SRC and oak (65.36, 62.55 and 66.43 wt% respectively), but miscanthus only produced a yield of 53.46 wt% due to increased feedstock ash content. The water content in the bio-oil is highest from miscanthus (17.64 wt%) and relatively low in the Virginia mallow and hardwoods willow SRC and oak (12.49, 13.88 and 14.53 wt%). Similar high yields of bio-oil and low yields of char and non-condensable gas compared to willow SRC make Virginia mallow an attractive feedstock for fast pyrolysis processing. Graphic Abstract: [Figure not available: see fulltext.]