503 research outputs found
The Metal-Insulator Transition of the Magneli phase V_4O_7: Implications for V_2O_3
The metal-insulator transition (MIT) of the Magneli phase V_4O_7 is studied
by means of electronic structure calculations using the augmented spherical
wave method. The calculations are based on density functional theory and the
local density approximation. Changes of the electronic structure at the MIT are
discussed in relation to the structural transformations occuring
simultaneously. The analysis is based on a unified point of view of the crystal
structures of all Magneli phase compounds V_nO_2n-1 (3 =< n =< 9) as well as of
VO_2 and V_2O_3. This allows to group the electronic bands into states behaving
similar to the dioxide or the sesquioxide. In addition, the relationship
between the structural and electronic properties near the MIT of these oxides
can be studied on an equal footing. For V_4O_7, a strong influence of
metal-metal bonding across octahedral faces is found for states both parallel
and perpendicular to the hexagonal c_hex axis of V_2O_3. Furthermore, the
structural changes at the MIT cause localization of those states, which mediate
in-plane metal-metal bonding via octahedral edges. This band narrowing opens
the way to an increased influence of electronic correlations, which are
regarded as playing a key role for the MIT of V_2O_3.Comment: 7 pages, 3 figures, more information at
http://www.physik.uni-augsburg.de/~eyert
CPD damage recognition by transcribing RNA polymerase II.
Cells use transcription-coupled repair (TCR) to efficiently eliminate DNA lesions such as ultraviolet light–induced cyclobutane pyrimidine dimers (CPDs). Here we present the structure-based mechanism for the first step in eukaryotic TCR, CPD-induced stalling of RNA polymerase (Pol) II. A CPD in the transcribed strand slowly passes a translocation barrier and enters the polymerase active site. The CPD 5′-thymine then directs uridine misincorporation into messenger RNA, which blocks translocation. Artificial replacement of the uridine by adenosine enables CPD bypass; thus, Pol II stalling requires CPD-directed misincorporation. In the stalled complex, the lesion is inaccessible, and the polymerase conformation is unchanged. This is consistent with nonallosteric recruitment of repair factors and excision of a lesion-containing DNA fragment in the presence of Pol II
Structure-reactivity relationships in supported VO<sub>x</sub> catalysts for the selective oxidation of 1-butene to acetic acid: A comprehensive in situ - study
Учет материалов
Объектом исследования является: Монгольская компания ОАО «Телекоммонголия». Это ведущий оператор связи на территории Монголии.
Цель работы : Рассмотрение организации учета и методов контроля движения материалов на примере ОАО «Телекоммонголия».The object of the research is: Mongolian company JSC "Telekommongoliya". It is the leading telecommunications operator in the territory of Mongolia.
Objective: Review of the organization of accounting and control of movement of materials methods as an example of "Telekommongoliya"
VPM1002 as Prophylaxis Against Severe Respiratory Tract Infections Including COVID-19 in the Elderly: a phase III randomised, double-blind, placebo-controlled, multicenter clinical study
Measurement of the Omega_c Lifetime
We present the measurement of the lifetime of the Omega_c we have performed
using three independent data samples from two different decay modes. Using a
Sigma- beam of 340 GeV/c we have obtained clean signals for the Omega_c
decaying into Xi- K- pi+ pi+ and Omega- pi+ pi- pi+, avoiding topological cuts
normally used in charm analysis. The short but measurable lifetime of the
Omega_c is demonstrated by a clear enhancement of the signals at short but
finite decay lengths. Using a continuous maximum likelihood method we
determined the lifetime to be tau(Omega_c) = 55 +13-11(stat) +18-23(syst) fs.
This makes the Omega_c the shortest living weakly decaying particle observed so
far. The short value of the lifetime confirms the predicted pattern of the
charmed baryon lifetimes and demonstrates that the strong interaction plays a
vital role in the lifetimes of charmed hadrons.Comment: 15 pages, including 7 figures; gzipped, uuencoded postscrip
Inhomogeneity of misfit stresses in nickel-base superalloys: Effect on propagation of matrix dislocation loops
The HERMES Back Drift Chambers
The tracking system of the HERMES spectrometer behind the bending magnet
consists of two pairs of large planar 6-plane drift chambers. The design and
performance of these chambers is described. This description comprises details
on the mechanical and electronical design, information about the gas mixture
used and its properties, results on alignment, calibration, resolution, and
efficiencies, and a discussion of the experience gained through the first three
years of operation.Comment: 21 pages, LaTex, 16 figures include
In silico evolution of diauxic growth
The glucose effect is a well known phenomenon whereby cells, when presented with two different nutrients, show a diauxic growth pattern, i.e. an episode of exponential growth followed by a lag phase of reduced growth followed by a second phase of exponential growth. Diauxic growth is usually thought of as a an adaptation to maximise biomass production in an environment offering two or more carbon sources. While diauxic growth has been studied widely both experimentally and theoretically, the hypothesis that diauxic growth is a strategy to increase overall growth has remained an unconfirmed conjecture. Here, we present a minimal mathematical model of a bacterial nutrient uptake system and metabolism. We subject this model to artificial evolution to test under which conditions diauxic growth evolves. As a result, we find that, indeed, sequential uptake of nutrients emerges if there is competition for nutrients and the metabolism/uptake system is capacity limited. However, we also find that diauxic growth is a secondary effect of this system and that the speed-up of nutrient uptake is a much larger effect. Notably, this speed-up of nutrient uptake coincides with an overall reduction of efficiency. Our two main conclusions are: (i) Cells competing for the same nutrients evolve rapid but inefficient growth dynamics. (ii) In the deterministic models we use here no substantial lag-phase evolves. This suggests that the lag-phase is a consequence of stochastic gene expression
Mechanical Relaxation in Glasses and at the Glass Transition
The Gilroy-Phillips model of relaxational jumps in asymmetric double-well
potentials, developed for the Arrhenius-type secondary relaxations of the glass
phase, is extended to a formal description of the breakdown of the shear
modulus at the glass transition, the flow process.Comment: 13 pages, 11 figures, 49 ref
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