The absence of the 10 um silicate feature in the isolated Herbig Ae star HD 100453

We analyse the optical and IR spectra, as well as the spectral energy distribution (UV to mm) of the candidate Herbig Ae star HD100453. This star is particular, as it shows an energy distribution similar to that of other isolated Herbig Ae/Be stars (HAEBEs), but unlike most of them, it does not have a silicate emission feature at 10 um, as is shown in Meeus (2001). We confirm the HAEBE nature of HD100453 through an analysis of its optical spectrum and derived location in the H-R diagram. The IR spectrum of HD100453 is modelled by an optically thin radiative transfer code, from which we derive constraints on the composition, grain-size and temperature distribution of the circumstellar dust. We show that it is both possible to explain the lack of the silicate feature as (1) a grain-size effect - lack of small silicate grains, and (2) a temperature effect - lack of small, hot silicates, as proposed by Dullemond (2001), and discuss both possibilities.Comment: 9 pages, 7 figures; accepted by A&

The characteristics of the IR emission features in the spectra of Herbig Ae stars: Evidence for chemical evolution

Herbig Ae/Be stars are a class of young pre-main sequence stellar objects of intermediate mass and are known to have varying amounts of natal cloud material still present in their direct vicinity. We characterise the IR emission bands, due to fluorescence by PAH molecules, in the spectra of Herbig Ae/Be stars and link observed variations to spatial aspects of the mid-IR emission. We analysed two PAH dominated spectra from a sample of 15 Herbig Ae/Be stars observed with Spitzer and derive profiles of the major PAH bands. The shape and the measured band characteristics show pronounced variations between the two Spitzer spectra. Those variations parallel those found between three ISO spectra of other, well-studied, Herbig Ae/Be stars. The derived profiles are compared to those from a broad sample of sources. The Spitzer and ISO spectra exhibit characteristics commonly interpreted respectively as interstellar matter-like (ISM), non-ISM-like, or a combination of the two. We argue that the PAH emission detected from the sources exhibiting a combination of ISM-like and non-ISM-like characteristics indicates the presence of two dissimilar, spatially separated, PAH families. As the shape of the individual PAH band profiles reflects the composition of the PAH molecules involved, this demonstrates that PAHs in subsequent, evolutionary linked stages of star formation are different from those in the general ISM, implying active chemistry. None of the detected PAH emission can be associated with the (unresolved) disk and is thus associated with the circumstellar cloud. This implies that chemical changes may already occur in the natal cloud and not necessarily in the disk

ISO spectroscopy of circumstellar dust in 14 Herbig Ae/Be systems: towards an understanding of dust processing

We present Infrared Space Observatory (ISO) spectra of fourteen isolated Herbig Ae/Be (HAEBE) stars, to study the characteristics of their circumstellar dust. These spectra show large star-to-star differences, in the emission features of both carbon-rich and oxygen-rich dust grains. The IR spectra were combined with photometric data ranging from the UV through the optical into the sub-mm region. We defined two key groups, based upon the spectral shape of the infrared region. The derived results can be summarized as follows: (1) the continuum of the IR to sub-mm region of all stars can be reconstructed by the sum of a power-law and a cool component, which can be represented by a black body. Possible locations for these components are an optically thick, geometrically thin disc (power-law component) and an optically thin flared region (black body); (2) all stars have a substantial amount of cold dust around them, independent of the amount of mid-IR excess they show; (3) also the near-IR excess is unrelated to the mid-IR excess, indicating different composition/location of the emitting material; (4) remarkably, some sources lack the silicate bands; (5) apart from amorphous silicates, we find evidence for crystalline silicates in several stars, some of which are new detections; (6) PAH bands are present in at least 50% of our sample, and their appearance is slightly different from PAHs in the ISM; (7) PAH bands are, with one exception, not present in sources which only show a power-law continuum in the IR; their presence is unrelated to the presence of the silicate bands; (8) the dust in HAEBE stars shows strong evidence for coagulation; this dust processing is unrelated to any of the central star properties (such as age, spectral type and activity).Comment: 15 pages, accepted by A&

Dust evolution in protoplanetary disks around Herbig Ae/Be stars - The Spitzer view

In this paper we present mid-infrared spectra of a comprehensive set of Herbig Ae/Be stars observed with the Spitzer Space Telescope. The signal-to-noise ratio of these spectra is very high, ranging between about a hundred and several hundreds. During the analysis of these data we tested the validity of standard protoplanetary dust models and studied grain growth and crystal formation. On the basis of the analyzed spectra, the major constituents of protoplanetary dust around Herbig Ae/Be stars are amorphous silicates with olivine and pyroxene stoichiometry, crystalline forsterite and enstatite and silica. No other solid state features, indicating other abundant dust species, are present in the Spitzer spectra. Deviations of the synthetic spectra from the observations are most likely related to grain shape effects and uncertainties in the iron content of the dust grains. Our analysis revealed that larger grains are more abundant in the disk atmosphere of flatter disks than in that of flared disks, indicating that grain growth and sedimentation decrease the disk flaring. We did not find, however, correlations between the value of crystallinity and any of the investigated system parameters. Our analysis shows that enstatite is more concentrated toward the warm inner disk than forsterite, in contrast to predictions of equilibrium condensation models. None of the three crystal formation mechanisms proposed so far can alone explain all our findings. It is very likely that all three play at least some role in the formation of crystalline silicates.Comment: 56 pages, 21 figures, accepted for publication in Ap

Binarity as a key factor in protoplanetary disk evolution: Spitzer disk census of the eta Chamaeleontis cluster

The formation of planets is directly linked to the evolution of the circumstellar (CS) disk from which they are born. The dissipation timescales of CS disks are, therefore, of direct astrophysical importance in evaluating the time available for planet formation. We employ Spitzer Space Telescope spectra to complete the CS disk census for the late-type members of the ~8 Myr-old eta Chamaeleontis star cluster. Of the 15 K- and M-type members, eight show excess emission. We find that the presence of a CS disk is anti-correlated with binarity, with all but one disk associated with single stars. With nine single stars in total, about 80% retain a CS disk. Of the six known or suspected close binaries the only CS disk is associated with the primary of RECX 9. No circumbinary disks have been detected. We also find that stars with disks are slow rotators with surface values of specific angular momentum j = 2-15 j_sun. All high specific angular momentum systems with j = 20-30 j_sun are confined to the primary stars of binaries. This provides novel empirical evidence for rotational disk locking and again demonstrates the much shorter disk lifetimes in close binary systems compared to single star systems. We estimate the characteristic mean disk dissipation timescale to be ~5 Myr and ~9 Myr for the binary and single star systems, respectively.Comment: Accepted by ApJ

Global Opportunities to Increase Agricultural Independence Through Phosphorus Recycling

Food production hinges largely upon access to phosphorus (P) fertilizer. Most fertilizer P used in the global agricultural system comes from mining of nonrenewable phosphate rock deposits located within few countries. However, P contained in livestock manure or urban wastes represents a recyclable source of P. To inform development of P recycling technologies and policies, we examined subnational, national, and global spatial patterns for two intersections of land use affording high P recycling potential: (a) manure‐rich cultivated areas and (b) populous cultivated areas. In turn, we examined overlap between P recycling potential and nation‐level P fertilizer import dependency. Populous cultivated areas were less abundant globally than manure‐rich cultivated areas, reflecting greater segregation between crops and people compared to crops and livestock, especially in the Americas. Based on a global hexagonal grid (290‐km2 grid cell area), disproportionately large shares of subnational “hot spots” for P recycling potential occurred in India, China, Southeast Asia, Europe, and parts of Africa. Outside of China, most of the remaining manure‐rich or populous cultivated areas occurred within nations that had relatively high imports of P fertilizer (net P import:consumption ratios ≥0.4) or substantial increases in fertilizer demand between the 2000s (2002–2006) and 2010s (2010–2014). Manure‐rich cultivated grid cells (those above the 75th percentiles for both manure and cropland extent) represented 12% of the global grid after excluding cropless cells. Annually, the global sum of animal manure P was at least 5 times that contained in human excreta, and among cultivated cells the ratio was frequently higher (median = 8.9). The abundance of potential P recycling hot spots within nations that have depended on fertilizer imports or experienced rising fertilizer demand could prove useful for developing local P sources and maintaining agricultural independence

DIGIT survey of far-infrared lines from protoplanetary disks I

[abridged] We present far-infrared spectroscopic observations of PMS stars taken with Herschel/PACS as part of the DIGIT key project. The sample includes 22 Herbig AeBe and 8 T Tauri sources. Multiple atomic fine structure and molecular lines are detected at the source position: [OI], [CII], CO, OH, H_2O, CH^+. The most common feature is the [OI] 63micron line detected in almost all of the sources followed by OH. In contrast with CO, OH is detected toward both Herbig AeBe groups (flared and non-flared sources). An isothermal LTE slab model fit to the OH lines indicates column densities of 10^13 < N_OH < 10^16 cm^-2, emitting radii 15 < r < 100 AU and excitation temperatures 100 < T_ex < 400 K. The OH emission thus comes from a warm layer in the disk at intermediate stellar distances. Warm H_2O emission is detected through multiple lines toward the T Tauri systems AS 205, DG Tau, S CrA and RNO 90 and three Herbig AeBe systems HD 104237, HD 142527, HD 163296 (through line stacking). Overall, Herbig AeBe sources have higher OH/H_2O abundance ratios across the disk than do T Tauri disks, from near- to far-infrared wavelengths. Far-infrared CH^+ emission is detected toward HD 100546 and HD 97048. The slab model suggests moderate excitation (T_ex ~ 100 K) and compact (r ~ 60 AU) emission in the case of HD 100546. The [CII] emission is spatially extended in all sources where the line is detected. This suggests that not all [CII] emission is associated with the disk and that there is a substantial contribution from diffuse material around the young stars. The flux ratios of the atomic fine structure lines are consistent with a disk origin for the oxygen lines for most of the sources.Comment: Accepted for publication in A&

FU Orionis - The MIDI/VLTI Perspective

We present the first mid-infrared interferometric measurements of FU Orionis. We clearly resolve structures that are best explained with an optically thick accretion disk. A simple accretion disk model fits the observed SED and visibilities reasonably well and does not require the presence of any additional structure such as a dusty envelope. The inclination and also the position angle of the disk can be constrained from the multibaseline interferometric observations. Our disk model is in general agreement with most published near-infrared interferometric measurements. From the shape and strength of the 8-13 micrometer spectrum the dust composition of the accretion disk is derived for the first time. We conclude that most dust particles are amorphous and already much larger than those typically observed in the ISM. Although the high accretion rate of the system provides both, high temperatures out to large radii and an effective transport mechanism to distribute crystalline grains, we do not see any evidence for crystalline silicates neither in the total spectrum nor in the correlated flux spectra from the inner disk regions. Possible reasons for this non-detection are mentioned. All results are discussed in context with other high-spatial resolution observations of FU Ori and other FU Ori objects. We also address the question whether FU Ori is in a younger evolutionary stage than a classical TTauri star.Comment: 41 pages (aastex style), 11 figures, 8 tables, accepted by Ap

9.7 um Silicate Features in AGNs: New Insights into Unification Models

We describe observations of 9.7 um silicate features in 97 AGNs, exhibiting a wide range of AGN types and of X-ray extinction toward the central nuclei. We find that the strength of the silicate feature correlates with the HI column density estimated from fitting the X-ray data, such that low HI columns correspond to silicate emission while high columns correspond to silicate absorption. The behavior is generally consistent with unification models where the large diversity in AGN properties is caused by viewing-angle-dependent obscuration of the nucleus. Radio-loud AGNs and radio-quiet quasars follow roughly the correlation between HI columns and the strength of the silicate feature defined by Seyfert galaxies. The agreement among AGN types suggests a high-level unification with similar characteristics for the structure of the obscuring material. We demonstrate the implications for unification models qualitatively with a conceptual disk model. The model includes an inner accretion disk (< 0.1 pc in radius), a middle disk (0.1-10 pc in radius) with a dense diffuse component and with embedded denser clouds, and an outer clumpy disk (10-300 pc in radius).Comment: Accepted for publication in ApJ, 14 pages, 5 figures. The on-line table is available at http://cztsy.as.arizona.edu/~yong/silicate_tab1.pd

Spectral Energy Distributions of T Tauri and Herbig Ae Disks: Grain Mineralogy, Parameter Dependences, and Comparison with ISO LWS Observations

We improve upon the radiative, hydrostatic equilibrium models of passive circumstellar disks constructed by Chiang & Goldreich (1997). New features include (1) account for a range of particle sizes, (2) employment of laboratory-based optical constants of representative grain materials, and (3) numerical solution of the equations of radiative and hydrostatic equilibrium within the original 2-layer (disk surface + disk interior) approximation. We explore how the spectral energy distribution (SED) of a face-on disk depends on grain size distributions, disk geometries and surface densities, and stellar photospheric temperatures. Observed SEDs of 3 Herbig Ae and 2 T Tauri stars, including spectra from the Long Wavelength Spectrometer (LWS) aboard the Infrared Space Observatory (ISO), are fitted with our models. Silicate emission bands from optically thin, superheated disk surface layers appear in nearly all systems. Water ice emission bands appear in LWS spectra of 2 of the coolest stars. Infrared excesses in several sources are consistent with vertical settling of photospheric grains. While this work furnishes further evidence that passive reprocessing of starlight by flared disks adequately explains the origin of infrared-to-millimeter wavelength excesses of young stars, we emphasize how the SED alone does not provide sufficient information to constrain particle sizes and disk masses uniquely.Comment: Accepted to ApJ, 35 pages inc. 14 figures, AAS preprin