The contrasting origins of glauconite in the shallow marine environment highlight this mineral as a marker of paleoenvironmental conditions

Glauconite is an authigenic mineral reputed to form during long-lasting contact between a nucleus (a pre-existing phyllosilicate) and seawater. This protracted contact makes it possible to subtract the ions necessary for the construction of the neoformed phyllosilicate, here, glauconite (a mineral very close to an illite, rich in K and Fe). As a result, glauconite is often associated with sediments deposited in a transgressive context with a strong slowdown in the rate of sedimentation and a relatively large water layer thickness. This is the case of the Cenomanian chalk of Boulonnais (north of France). Being chemically and physically resistant, glauconite is a mineral that is often reworked, like quartz grains. This is frequently the case of the Jurassic deposits of the Boulonnais, where glauconite, almost ubiquitous, either in traces or in significant proportions of the sediments, presents a grain size sorting attesting to its transport and reworking. However, these Jurassic deposits are shallow (shoreface, upper offshore), which supports the idea that the “glauconite factory” was itself in the shallow areas of the Boulonnais. The only identified Jurassic facies of the Boulonnais where glauconite is both relatively abundant, large in size and unsorted (non reworked) are oyster reefs that formed at the outlet of cold seeps linked to a late-Jurassic synsedimentary tectonic (Kimmeridgian, Tithonian). Our work makes it possible to hypothesize that isolated oyster reefs were environments combining the redox conditions and in contact with seawater favoring the authigenic formation of glauconite. The weakly reducing conditions necessary for the formation of glauconite here are attested by the contents of metallic trace elements sensitive to redox conditions (vanadium, germanium, arsenic, in this case). Our work thus adds a new element to the understanding of the mechanisms of formation of glauconite in shallow environments

A novel approach to volcano surveillance using gas geochemistry

The aim of this paper is to test a simple damage model of a cohesive granular medium to study the relationship between the damage and velocity of elastic waves. Our numerical experiments of edometric compression show that the mi- croscopic deformation quickly becomes very heterogeneous, while our simulations of elastic waves propagation show that a small amount of damage induces a dra- matic decrease in the elastic velocity. This shows that cohesive discrete media are very sensitive to strain field heterogeneity, and that the wave velocities in these media can measure subtle transient deformation processes, such as earthquake initiation phases

North western Alps Holocene paleohydrology recorded by flooding activity in Lake Le Bourget, France and possible relations with Mont-Blanc glaciers fluctuations

International audienceA 14-m long piston core was retrieved from Lake Le Bourget, NWAlps (France), in order to provide a continuous record of flooding events of the Rhone River during the Holocene. The selection of the coring site was based on high resolution seismic profiling, in an area with limited mass wasting deposits and accumulated proximal Rhone River inter-and underflow deposits. The age-depth model of this core is based on (i) 14 AMS radiocarbon dates, (ii)radionuclide dating(137Cs) and (iii) the identification of historical data (flood events, eutrophication of the lake).The sedimentary record dates back to 9400 cal BP, and includes a thin mass wasting event deposited around 4500 cal BP. A multi-proxy approach was used to track the evolution and origin of clastic sedimentation during the Holocene, in order to identify periods of higher hydrologic al activity in the catchment area. Spectrophotometry was used to detect fluctuations in clastic supply and the study of clay minerals (especially the Illite crystallinity index) allowed locating the main source area of fine grained clastic particles settling at the lake after flood events. This dataset highlights up to 12 periods of more intense flooding events over the last 9400 years in Lake Le Bourget and shows that the main source area of clastic particles during this period is the upper part of the Arve River drainage basin. This part of the catchment area drains several large glaciers from the Mont-Blanc Massif, and fluctuations in Rhone River flood supply in Lake Le Bourget is interpreted as resulting essentially from Mont-Blanc Glacier activity during the Holocene.The comparison of clastic sedimentationin Lake Le Bourget with periods of increasing land use and periods of Alpine glacier and mid-European lake level fluctuations, suggest that the core LDB04 clastic record in Lake Le Bourget is a continuous proxy of the Holocene hydrologic al history of the NW Alps

Impacts of Mayan land use on Laguna Tusp an watershed (Pet en, Guatemala) as seen through clay and ostracode analysis

International audienceMost of the cities built by the Mayas in the Pet en area, in the Central Yucat an Peninsula, were abandoned 1200 to 1000 years ago. The phenomenon is sometimes un-appropriately called " the collapse of the Maya civilization ". Its main causes are still debated, ranging from climatic according to the occurrence of severe or modest droughts, to societal in the form of environmental mismanagement of the environment. In both processes, it is inferred that stress triggered the formation in many Pet en lake sediments of erosional clay deposits, known as 'Maya clays'. This work presents a high resolution, multi-proxy study of 'Maya clays' in lacustrine sediments from Laguna Tusp an, near the archaeological site of La Joyanca. Micropaleontological (ostracodes), mineral-ogical (clay minerals) and geochemical (bulk elemental composition and stable isotopes in organic carbon) records reveal three different phases of soil erosion throughout the last 5300 years. The oldest phase from 5281 to 2998 cal yr BP (i.e. 3331 e 1048 BC) is characterized by successive natural and moderate soil erosion deposits which follow climatic variations recorded in the American tropical belt. The time interval between 2998 and 1281 cal yr BP (i.e. 1048 BC and AD 661) contains four distinct erosional layers which, according to clay mineralogy, are indicative of both increased erosion of the regolith and strong soil loss. The most recent, also the most massive, deposit of Maya clay ends around 1281 cal yr BP (AD 661), that is some 200 years before the so-called 'Maya collapse' in the Pet en area. Recent archeological fieldwork studies indicate that a population mobility took place into the city of La Joyanca from its hinterland by the early Late Classic Period (ca. AD 600), that is, at the end or just after this erosion episode, and well before the occurrence of the Terminal Classic-Postclassic (AD 800e1250) drastic climatic changes. Shifts in environmental management by the local society and timing of urbanization may explain environmental changes better than droughts per se

New constraints on elemental and Pb and Nd isotope compositions of South American and Southern African aerosol sources to the South Atlantic Ocean

Improving the geochemical database available for characterising potential natural and anthropogenic aerosol sources from South America and Southern Africa is a critical precondition for studies aimed at understanding trace metal controls on the marine biogeochemical cycles of the South Atlantic Ocean. We here present new elemental and isotopic data for a wide range of sample types from South America and Southern Africa that are potentially important aerosol sources. This includes road dust from Buenos Aires and lichen samples from Johannesburg, soil dust from Patagonia, volcanic ash from the Andean volcanic belt, and aerosol samples from São Paulo. All samples were investigated for major (Al, Ca, Fe, Mg, Na, K, Mn) and trace element (Cd, Co, Cr, Cu, Ni, Pb, REE, Sc, Th, Y, V, Zn) concentrations and Nd and Pb isotopic compositions. We show that diagrams of 208Pb/207Pb vs. εNd, 208Pb/207Pb vs. Pb/Al, 1/[Pb], Zn/Al, Cd/Al, Cu/Al, and εNd vs. Pb/Al, and 1/[Nd] are best suited to separate South American and South African source regions as well as natural and anthropogenic sources. A subset of samples from Patagonia and the Andes was additionally subjected to separation of a fine (<5 μm) fraction and compared to the composition of the bulk sample. We show that differences in the geochemical signature of bulk samples between individual regions and source types are significantly larger than between grain sizes. Jointly, these findings present an important step forward towards a quantitative assessment of aeolian trace metal inputs to the South Atlantic Ocean

Mineralogical and Geochemical Tracers of Terrigenous Transfers

International audienc

Mineralogical and Geochemical Tracers of Terrigenous Transfers

International audienc