Do nebular fractionations, evaporative losses, or both, influence chondrule compositions?

We have made observations and performed heating experiments to determine the relative importance of several processes which may have influenced the compositions of chondrules. As heating destroys nuclei, the number density of olivine and pyroxene crystals gives an indication of the extent of melting. We determined number densities of Semarkona type I chondrules and converted them to nominal grain size, for use as a measure of intensity of heating. Bulk compositions of the chondrules show correlations with nominal grain size. Na, K, Fe, Ni, P and S decrease as grain size (degree of melting) increases, and we interpret this as evidence of evaporative loss. The evidence is less clear for Mn, Cr and Si. SiO_2/MgO ratios show very large variations even in fine-grained type I chondrules containing FeS, and we interpret those variations as due to nebular fractionations affecting precursors. Experiments show that Na and S losses increase with higher temperatures and lower cooling rates. It is hard to preserve any sulfide at all, without flash heating. Na, however, can be retained at close to chondritic levels (as in type II chondrules) with flash heating and high cooling rate, provided also that the oxygen fugacity is high. Type II chondrules can retain much more Na than type I under identical thermal conditions, because of higher fO_2 (either due to non-nebular gas or possibly internal buffering by FeO content) and melt structure (higher SiO_2/MgO). Gas reduction experiments show that type II compositions can be converted to IB by Fe loss, but evaporative loss of SiO_2 (so as to approach IA composition) is not achieved without prolonged isothermal heating. Precursors of type I and II chondrules were probably close to chondritic in composition, but with higher Fa in the type II case. They consisted of olivine, pyroxene, plagioclase, Fe (Ni) S and carbon compounds, probably with insignificant metal. Sulfur loss generated much chondrule metal in ordinary chondrites. C is a possible alternative to gas reduction to explain dusty relict grains and the lower olivine Fa in the more melted type I chondrules. We agree with J. N. GROSSMAN and J. T. WASSON (Geochim. Cosmochim. Acta, 47,759,1983) that variations in Mg/Si are due to nebular fractionations and with S. HUANG et al. (Icarus, 122,316,1996) that variations in Na and Fe in type I chondrules are mainly due to evaporative losses

Paris: The slightly altered, slightly metamorphosed CM that bridges the gap between CMs and Cos

A fresh, 1.3 kilo stone was found in Paris. It is a CM chondrite with metal, Fe-sulfide, FeS-rich PCPs and relict mesostasis and is ~3.0 ± 0.1. Petrographic and oxygen isotope evidence indicates that it has affinities with the CO chondrites

Structures, origin and evolution of various carbon phases in the ureilite Northwest Africa 4742 compared with laboratory-shocked graphite

International audienceMineralogical structures of carbon phases within the ureilite North West Africa 4742, a recent find, are investigated at various scales by high-resolution transmission electron microscopy (HRTEM), Raman microspectrometry and X-ray diffraction. Ureilites are the most carbon-rich of all meteorites, containing up to 6 wt.% carbon. Diamond, graphite and so-called "amorphous carbon" are typically described, but their crystallographic relationships and respective thermal histories remain poorly constrained. We especially focus on the origin of "amorphous carbon" and graphite, as well as their relationship with diamond. Two aliquots of carbon-bearing material were extracted: the insoluble organic matter (IOM) and the diamond fraction. We also compare the observed structures with those of laboratory-shocked graphite. Polycrystalline diamond aggregates with mean coherent domains of about 40 nm are reported for the first time in a ureilite and TEM demonstrates that all carbon phases are crystallographically related at the nanometre scale. Shock features show that diamond is produced from graphite through a martensitic transition. This observation demonstrates that graphite was present when the shock occurred and is consequently a precursor of diamond. The structure of what is commonly described as the "amorphous carbon" has been identified. It is not completely amorphous but only disordered and consists of nanometre-sized polyaromatic units surrounding the diamond. Comparison with laboratory-shocked graphite, partially transformed into diamond, indicates that the disordered carbon could be the product of diamond post-shock annealing. As diamond is the carrier of noble gases, whereas graphite is noble gas free, graphite cannot be the sole diamond precursor. This implies a multiple-stage history. A first generation of diamond could have been synthesized from a noble gas rich precursor or environment by either a shock or a condensation process. Thermally-induced graphitization of chondritic-like organic matter could have produced the graphite, which was then transformed by shock processes into polycrystalline nanodiamond aggregates. The formation of the disordered carbon occurred by diamond post-shock back-transformation during post-shock heating. The noble gases in the first generation diamond could then be incorporated directly into the disordered carbon during the transformation

The Asco meteorite (1805): New petrographic description, chemical data, and classification

Abstract— We present magnetic measurements, chemical analyses, and petrographic observations of the poorly studied Asco historical meteorite fall (1805). These new data indicate that this meteorite has been previously misclassified as an L6 ordinary chondrite. Asco is reclassified as an H6 ordinary chondrite with shock stage S3. An interesting feature of this meteorite is the presence of chromite‐plagioclase assemblages with variable textures

Formation of oxygen isotope reservoirs by mixing chondritic components

Published versio

An accretionary origin for ordinary chondrite groups

Accepted versio

Regulation of mating in the budding yeast Saccharomyces cerevisiae by the zinc cluster proteins Sut1 and Sut2

This article is made available through the Brunel Open Access Publishing Fund. Copyright @ The Authors. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.The zinc cluster proteins Sut1 and Sut2 play a role in sterol uptake and filamentous growth in the budding yeast Saccharomyces cerevisiae. In this study, we show that they are also involved in mating. Cells that lack both SUT1 and SUT2 were defective in mating. The expression of the genes NCE102 and PRR2 was increased in the sut1 sut2 double deletion mutant suggesting that Sut1 and Sut2 both repress the expression of NCE102 and PRR2. Consistent with these data, overexpression of either SUT1 or SUT2 led to lower expression of NCE102 and PRR2. Furthermore, expression levels of NCE102, PRR2 and RHO5, another target gene of Sut1 and Sut2, decreased in response to pheromone. Prr2 has been identified as a mating inhibitor before. Here we show that overexpression of NCE102 and RHO5 also reduced mating. Our results suggest that Sut1 and Sut2 positively regulate mating by repressing the expression of the mating inhibitors NCE102, PRR2 and RHO5 in response to pheromone.Deutsche Forschungsgemeinschaf

Metabolism of polysaccharides in dynamic middle lamellae during cotton fibre development

Main conclusion: Evidence is presented that cotton fibre adhesion and middle lamella formation are preceded by cutin dilution and accompanied by rhamnogalacturonan-I metabolism. Cotton fibres are single cell structures that early in development adhere to one another via the cotton fibre middle lamella (CFML) to form a tissue-like structure. The CFML is disassembled around the time of initial secondary wall deposition, leading to fibre detachment. Observations of CFML in the light microscope have suggested that the development of the middle lamella is accompanied by substantial cell-wall metabolism, but it has remained an open question as to which processes mediate adherence and which lead to detachment. The mechanism of adherence and detachment were investigated here using glyco-microarrays probed with monoclonal antibodies, transcript profiling, and observations of fibre auto-digestion. The results suggest that adherence is brought about by cutin dilution, while the presence of relevant enzyme activities and the dynamics of rhamnogalacturonan-I side-chain accumulation and disappearance suggest that both attachment and detachment are accompanied by rhamnogalacturonan-I metabolism

The zinc cluster protein Sut1 contributes to filamentation in Saccharomyces cerevisiae

Copyright © 2013, American Society for Microbiology. All Rights ReservedSut1 is a transcriptional regulator of the Zn(II)(2)Cys(6) family in the budding yeast Saccharomyces cerevisiae. The only function that has been attributed to Sut1 is sterol uptake under anaerobic conditions. Here, we show that Sut1 is also expressed in the presence of oxygen, and we identify a novel function for Sut1. SUT1 overexpression blocks filamentous growth, a response to nutrient limitation, in both haploid and diploid cells. This inhibition by Sut1 is independent of its function in sterol uptake. Sut1 downregulates the expression of GAT2, HAP4, MGA1, MSN4, NCE102, PRR2, RHO3, and RHO5. Several of these Sut1 targets (GAT2, HAP4, MGA1, RHO3, and RHO5) are essential for filamentation in haploids and/or diploids. Furthermore, the expression of the Sut1 target genes, with the exception of MGA1, is induced during filamentous growth. We also show that SUT1 expression is autoregulated and inhibited by Ste12, a key transcriptional regulator of filamentation. We propose that Sut1 partially represses the expression of GAT2, HAP4, MGA1, MSN4, NCE102, PRR2, RHO3, and RHO5 when nutrients are plentiful. Filamentation-inducing conditions relieve this repression by Sut1, and the increased expression of Sut1 targets triggers filamentous growth.The project was supported by Deutsche Forschungsgemeinschaft grant HO 2098/