302 research outputs found

    Models for genesis of Kamchatka are magmas: new insights from U-series

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    Can multimarket competition theory explain why manufacturers are reluctant to adopt e-commerce ? The case of the French household appliances’ manufacturers

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    International audienceWith turnover of more than €51 billion in France in 2013, e-commerce continues to grow, both in volume and number of players. While economic theories suggest that manufacturers should integrate intermediation functions as soon as they are able to perform them at a lower cost than external operators, few French manufacturers are engaging in e-commerce. In this research, we explore why manufacturers of household appliance do not launch e-commerce sites. Our results suggest that, in accordance with multimarket competition theory, they do so in order to avoid coercion from the traditional French distribution system

    Corrigendum to “Testing pyroxenite versus peridotite sources for marine basalts using U-series isotopes” [Lithos 332–333 (2019) 226–244]

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    The authors regret that a small error in the dynamic melting Matlab script used for this paper produced erroneous results for some of the included modeling outcomes. We have written an updated modeling program in python, which can be accessed in the ENKI and pyUserCalc public data repository (https://gitlab.com/ENKI-portal/pyUsercalc/). Although the corrected results shown in revised versions of Figs. S3, S4, S8, S9, and S10 now appear quite different from the original publication, however, we find that when restricted to plausible scenarios of interest, our conclusions overall have not significantly changed. Some details of our results and discussion require corrections, however

    Testing pyroxenite versus peridotite sources for marine basalts using U-series isotopes

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    Geochemically enriched signatures in global oceanic basalts have long indicated a heterogeneous mantle source, but the role of lithologic heterogeneity in producing mantle partial melts, particularly fertile pyroxenite rocks, remains unclear. Uranium-series disequilibria in basalts are particularly sensitive to the increased garnet mode and melting rates of pyroxenite rocks, making the system a useful indicator of mantle lithologic heterogeneity in the melt region for oceanic basalts. Here we summarize evidence for the presence and importance of pyroxenite rocks in the upper mantle and their role in melt generation of mid-ocean ridge basalts and ocean island basalts, with a synthesis of U-series disequilibrium systematics in oceanic basalts and implications for global lithologic heterogeneity of the upper mantle. We further synthesize the melt modeling approaches for the interpretation of U-series disequilibria in basalts and demonstrate the use of numerical solution models for time-dependent reactive porous flow and dynamic melting during decompression of a two-lithology mantle in thermal equilibrium. Our model outcomes corroborate prior interpretations in favor of reactive porous flow and two-porosity transport for relatively homogeneous, peridotite-dominated mantle regimes, and further support contributions of pyroxenite partial melts to aggregated melts in order to reproduce the heterogeneous global basalt data. To most accurately predict the conditions of melting by comparison with measured data, two-lithology melting calculations should carefully consider the role of thermal equilibrium, mineral/melt partitioning, non-linear variations in mineral modes, and degree of melting during the melting process

    Isotope tracers of core formation

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    The study of siderophile element isotope compositions in planetary mantles offers a new methodology to constrain the temperatures of core formation, provided there is an appropriate calibration of the temperature dependence and possibly pressure-dependence of isotope fractionation between metal and silicate and of the metal-silicate partitioning for these elements. In this review, we examine recent studies that have shown that Si, Fe, Mo, Cr, Cu, Ni, N and C could potentially be used to constrain the temperature of metal-silicate equilibration using single stage or continuous models of core formation, yielding contrasted results. Such an approach requires assumptions about the building blocks of the Earth and it is generally considered that the composition of some chondrites is representative of bulk Earth. This is obviously more complex for volatile elements such as Cu, N or C, as the isotope composition of the building blocks of the Earth could have been affected by thermal processing. On the basis of a chondritic bulk composition, one can estimate a temperature of core formation assuming a model for this process. If the metal-silicate equilibration is incomplete, as is likely the case for giant impacts, then the composition of the mantle of the impactor and the fraction of metal that equilibrates needs to be assessed carefully. It has been shown recently that the degree of equilibration will be a function of the metal silicate partition coefficient and will be hence very different for Si, Cr, or Mo, an aspect that has not been considered in previous studies and may help explain differences in interpretation. In this context, the expected temperatures of equilibration are quite variable and are a function of the impactor's conditions of metal-silicate segregation. Another complication arises when considering continuous models of core formation: the most siderophile elements will be sensitive to the last episodes of core formation, while the budget of less siderophile elements will reflect its integrated accretion history (e.g. Cr or Si). A model including Si, Cr and Mo isotope data that takes into account these aspects has been constructed and shown to be consistent with scenarii that were derived from siderophile element data

    Organic matter sources and early diagenetic degradation in a tropical peaty marsh (Tritrivakely, Madagascar). Implications for environmental reconstruction during the Sub-Atlantic

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    Peat samples from a one metre core and living Cyperaceae, collected in Tritrivakely marsh in Madagascar, were studied to determine the organic matter (OM) composition and extent of OM degradation in this core. The study was carried out combining light microscopy observations, bulk analyses, infra-red spectroscopy, hydrolyses of sugars, oxidation of lignin and pyrolyses. In the surface peat, organic matter derived from Cyperaceae undergoes extensive degradation of its basic cell wall components, morphologically revealed by destructuration of plant tissues and their transformation into reddish amorphous organic matter occurring in large amounts all along the core. Two ratios (cinnamic units/lignin and xylose+arabinose/total sugars) were determined as markers of Cyperaceae. It appeared that the vegetation of the marsh remained probably unchanged during the considered accumulation period, i.e. the last 2300 years B.P. Rhamnose, mannose and non-cellulosic glucose probably have a common origin and are mostly derived from bacteria. In contrast, galactose is likely to be a marker of algal source, especially of the diatoms that occur only in the upper part of the core (0-ca. 50 cm). Acid/aldehyde ratios of syringic and vanillic monomers (index of lignin oxidative depolymerisation) and mannose+rhamnose+non-cellulosic glucose/total sugars ratios (reflecting bacterial degradation of hemicelluloses) are positively correlated, and can thus be considered as markers of microbial degradation of the Cyperaceae tissues. The n-alkane/n-alk-1-ene doublets that dominate the pyrolysates of hydrolysed peat samples reflect the contribution of B. braunii algaenan and higher plant suberans, and of condensed lipids mostly derived from higher plants and microalgae. The upper part of the core is characterised by a greater dilution of Cyperaceae-derived compounds by organic matter from microalgae when compared with deeper samples, as recorded by peat bulk features, hydrolysable sugars, lignin oxidation products and pyrolysis products. Two accumulation periods can thus be distinguished in the core: a peaty phase between 2300 years B.P. and ca. 1500 years B.P. (low watertable and strongly limited microalgal growth); a waterlogged marsh, from ca. 1500 years B.P. to the present time, in which a higher water table was longer lasting with a substantial algal production. The environmental variation thus recorded could correspond to a regional climatic change occurring around 1500 years B.P
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