Crystalline and Spectroscopic Experimental Study of the Dinitromesithylen (DNM) Compared with the Theoretical Results

International audienceThe aim by our group is to understand the behavior of the grouping Me starting from the study of mols. having a great symmetry. In this part of work, it is had the cryst. structure of the dinitromesitylen (DNM) who is solved starting from the diffraction of x-​rays starting from a monocrystal at the ambient temp. Parallel to the exptl. study, we undertook theor. calcns. conformation of the insulated mol. of DNM by using the methods of the DFT (D. Functional Theory)​. Calcns. of optimization of the mol. conformation of the DNM by using the chain of program GAUSSIAN03 and functional MPW1PW91, B3LYP level with the 6-​311G and LANL2DZ bases gave a conformation Cs with results very close to the expt. for the lengths and the angles of bond. The computation results obtained starting from the base set (6-​311G) and functional MPW1PW91 give for the conformation of Dinitromesitylen (DNM) a good agreement of about a 1.9​% for the lengths of bond and 1.2​% for the angles of bond compared with the results of the diffraction of x-​rays. Calcns. of Raman and infra-​red spectroscopy undertaken starting from the results of optimization by using same functional MPW1PW91 and B3LYP and the sets of bases 6-​311G LanL2DZ led to the values of frequencies very close to the exptl. results

Variations of VLF/LF signals observed on the ground and satellite during a seismic activity in Japan region in May–June 2008

Signals of two Japanese transmitters (22.2 kHz and 40 kHz) recorded on the ground VLF/LF station in Petropavlovsk-Kamchatsky and on board the DEMETER French satellite have been analyzed during a seismic activity in Japan in May–June 2008. The period of analysis was from 18 April to 27 June. During this time two rather large earthquakes occurred in the north part of Honshu Island – 7 May (<i>M</i>=6.8) and 13 June (<i>M</i>=6.9). The ground and satellite data were processed by a method based on the difference between the real signal in nighttime and the model one. For ground observations a clear decrease in both signals has been found several days before the first earthquake. For the second earthquake anomalies were detected only in JJI signal. The epicenters of earthquakes were in reliable reception zone of 40 kHz signal on board the DEMETER. Signal enhancement above the seismic active region and significant signal intensity depletion in the magnetically conjugate area has been found for satellite observation before the first earthquake. Anomalies in satellite data coincide in time with those in the ground-based observation

A possible radio anomaly observed on the occasion of the MW=6.0 earthquake occurred in Dodecanese islands at the end of January 2020

Since 2009, several VLF/LF radio receivers have been installed throughout Europe in order to realize a European radio network for studying the radio precursors of earthquakes, called the INFREP network. The current network has nine VLF/LF receiving stations, two in Romania and Greece, one in Italy, Austria, Portugal, Cyprus, and Serbia. The receivers can measure with 1 min sampling rate the intensity of 10 radio signals in the band VLF (10-50 kHz) and LF (150-300 kHz). The scope of existing transmitters is manifold, e.g. they are used for radio broadcast (LF), for radio- navigation or time signals and mainly for military purposes in the VLF range. At the end of January 2020 an intense seismic crisis occurred in Dodecanese Islands; the main event (Mw= 6.0) occurred on January 30. This seismic activity occurred in the "sensitive" area of the INFREP network. The analysis of the data collected by INFREP receivers has revealed clear anomalies in three VLF signals appearing some days before the main earthquake. The anomalies appear in the trends collected by the Cyprus receiver and the epicenter is inside the 5th Fresnel ellipses defined by transmitters- receiver. Here we report the data analysis and we present in detail the anomalies. The possibility that they are precursors of the quoted earthquake seems significant. Biagi, P.F., Colella, R., Schiavulli, L., Ermini, A., Boudjada, M., Eichelberger, H., Schwingenschuh, K., Katzis, K., Contadakis, M.E., Skeberis, C., Moldovan, I.A. and Bezzeghoud, M. (2019) The INFREP Network: Present Situation and Recent Results. Open Journal of Earthquake Research,8, 101-115. https://doi.org/10.4236/ojer.2019.8200

Anomalies in VLF radio signals prior the Abruzzo earthquake (M=6.3) on 6 April 2009

Abstract. The VLF/LF radio signals method for studying preseimic activity is applied to the Abruzzo earthquake (M=6.3, 6 April 2009). The data collected by three receivers located in Moscow (Russia), Graz (Austria) and Bari (Italy) at about 3000 km, 1000 km and 500 km from the epicenter were used. The signals received from the Sardinia (20.27 kHz) and the Sicily (45.9 kHz) transmitters, both located in Italy, were compared with those received from the Iceland (37.5 kHz), the Great Britain (19.58 kHz) and the Germany (23.4 kHz) transmitters. The propagation paths of the two Italian transmitters cross the epicentral area (seismic paths) unlike the paths of the other three signals (control paths). Using two different analyses, that are the study of the night-time signal and the research of shifts in the evening terminator times, clear anomalies were revealed 2–8 days before the occurrence of the Abruzzo earthquake in the seismic paths, while no anomalies have been found in the control paths

Wavelet analysis applied on temporal data sets in order to reveal possible pre-seismic radio anomalies and comparison with the trend of the raw data

Since 2009, several radio receivers have been installed throughout Europe in order to realize the INFREP European radio network for studying the VLF (10-50 kHz) and LF (150-300 kHz) radio precursors of earthquakes. Precursors can be related to “anomalies” in the night-time behavior of VLF signals. A suitable method of analysis is the use of the Wavelet spectra. Using the “Morlet function”, the Wavelet transform of a time signal is a complex series that can be usefully represented by its square amplitude, i.e. considering the so-called Wavelet power spectrum. The power spectrum is a 2D diagram that, once properly normalized with respect to the power of the white noise, gives information on the strength and precise time of occurrence of the various Fourier components, which are present in the original time series. The main difference between the Wavelet power spectra and the Fourier power spectra for the time series is that the former identifies the frequency content along the operational time, which cannot be done with the latter. Anomalies are identified as regions of the Wavelet spectrogram characterized by a sudden increase in the power strength. On January 30, 2020 an earthquake with Mw= 6.0 occurred in Dodecanese Islands. The results of the Wavelet analysis carried out on data collected some INFREP receivers is compared with the trends of the raw data. The time series from January 24, 2020 till January 31, 2000 was analyzed. The Wavelet spectrogram shows a peak corresponding to a period of 1 day on the days before January 30. This anomaly was found for signals transmitted at the frequencies 19,58 kHz, 20, 27 kHz, 23,40 kHz with an energy in the peak increasing from 19,58 kHz to 23,40 kHz. In particular, the Powered by TCPDF (www.tcpdf.org) signal at the frequency 19,58 kHz, shows a peak on January 29, while the frequencies 20,27 kHz and 23,40 kHz are characterized by a peak starting on January 28 and continuing to January 29. The results presented in this work shows the perspective use of the Wavelet spectrum analysis as an operational tool for the detection of anomalies in VLF and LF signal potentially related to EQ precursors

Ray paths of VLF/LF transmitter radio signals in the seismic Adriatic regions

We analyze the radio wave propagations of VLF/LF transmitter signals along subionospheric paths using two different reception systems localized in the Graz seismo-electromagnetic facility (15.43E,47.06N). Those systems allow the simultaneous detection of more than fifteen transmitter signals emitting in the northern (i.e. France, Germany and United Kingdom) and southern (i.e. Italy and Turkey) parts of Europe. In this work, we investigate the transmitter radio wave propagations associated with two earthquakes (EQs) which occurred, at two occasions, in nearly the same Croatian regions (Geo. Long.=16°E; Geo. Lat.=45°N). The first and second EQs happened, respectively, on March 22 and December 29, 2020, with magnitudes Mw equal to 5.4 and 6.4. The use of two complementary reception systems, i.e. INFREP (Biagi et al., Open Journal of Earthquake Research, 8, 2019) and UltraMSK (Schwingenschuh et al., Nat. Hazards Earth Syst. Sci., 11, 2011), and the proximity to the epicenters lead us to characterize the behavior of the transmitter signal amplitudes particularly above the Croatian seismic regions. We analyze the amplitude variation for a given transmitter frequency starting few weeks before the earthquakes occurrences. We discuss the observed anomalies in the transmitter signals which may be considered as precursors due to the ionospheric disturbances of the transmitter ray paths above the earthquakes preparation zones

Strong influence of solar X-ray flares on low-frequency electromagnetic signals in middle latitudes

In this paper we analysed sudden phase anomalies (SPAs) of VLF–LF signals recorded at Graz (Austria), Birr (Ireland) and Moscow (Russia) stations during two strong solar flares in September 2017. The first X-class 9.3 flare occurred on 6 September at 12:02 UT, and the second X-class 8.2 flare was observed on 10 September 2017 at 16:06 UT. Data from seven transmitters in a frequency range between 20 and 45 kHz are used for the analysis. The SPAs were observed in all middle-latitude paths (differently orientated) with path lengths from 350 to 7000 km. Solar X-ray burst data were taken from GOES satellite observations in the wavelength band of 0.05–0.4 nm. It was found that (i) the amplitude of SPAs in different paths varies from 10 to 282∘, and (ii) the correlation between the amplitudes of SPAs, the lengths of paths and the signal frequency is weak. The change in effective height of reflection due to lowering of the reflecting layer during the flares was found to be about 12 km for the first event and about 9 km for the second event. Spectral analysis of the X-ray and LF data, filtered in the range between 5 s and 16 min, showed that the LF signal spectra are very similar to X-ray spectra. Maxima of both X-ray and LF spectra are in 2–16 min interval

The Graz seismo-electromagnetic VLF facility

Abstract. In this paper we describe the Graz seismo-electromagnetic very low frequency (VLF) facility, as part of the European VLF receiver network, together with the scientific objectives and results from two years operation. After a brief technical summary of the present system – with heritage from a predecessor facility – i.e. hardware, software, operational modes and environmental influences, we discuss results from statistical data and scientific events related to terrestrial VLF propagation over Europe

A VLF/LF facility network for preseismic electromagnetic investigations

Earthquakes are one of the most frequently occurring natural disasters. Many indications have been collected on the presence of seismo-ionospheric perturbations preceding such tragic phenomena. Radio techniques are the essential tools leading the detection of seismo-electromagnetic emissions by monitoring at very low-frequency (VLF, 3–30 kHz) and low-frequency (LF, 30–300 kHz) sub-ionospheric paths between transmitters and receivers (Hayakawa, 2015). In this brief communication, we present the implementation of a VLF/LF network to search for earthquake electromagnetic precursors. The proposed system is comprised of a monopole antenna including a preamplifier, a GPS receiver and a recording device. This system will deliver a steady stream of real-time amplitude and phase measurements as well as a daily recording VLF/LF data set. The first implementation of the system was done in Graz, Austria. The second one will be in Guyancourt (France), with a third one in Réunion (France) and a fourth one in Moratuwa (Sri Lanka). In the near future, we are planning to expand our network for enhanced monitoring and increased coverage.</p

Case study of radio emission beam associated to very low frequency signal recorded onboard CSES satellite

We report on the variation of electric power density linked to very low frequency (VLF) signal observed during the minimum of solar cycle 25. The detected VLF signal is emitted by the NWC radio station localized in the southern hemisphere, at 21.5∘ S and 114.2∘ E. We attempt in this work to quantify the beam as detected by the Electric Field Detector (EFD) instrument onboard CSES satellite. Geometrical key parameters have been considered to analysis the variation of the power density taking into consideration the distance between the satellite trajectory and the NWC station and its conjugate region. The beam behavior is found to be subject to significant disturbances in the conjugate region with the presence of signal modulations. Above the NWC transmitter station, the beam can be considered as a hollow cone but with irregularity dependence on the electric power density.</p