1,996 research outputs found
Intermodulation distortion from receiver non-linear phase characteristics Final report
Computation of intermodulation distortion levels produced by telemetry system predetection filte
Creation of a ternary complex between a crown ether, 4-aminobenzoic acid and 3,5-dinitrobenzoic acid
YesThe creation of ternary multi-component crystals through the introduction of 18-crown-6 to direct the hydrogen-bonding motifs of the other molecular components was investigated for 3,5-dinitrobenzoic acid (3,5-dnba) with 4-aminobenzoic acid (4-aba). The creation of a binary complex between 18-crown-6 and 4-aba (C12H24O6·2C7H7NO2)2 and a ternary salt between 3,5-dnba, 18-crown-6 and 4-aba (C12H24O6·C7H8NO2+·C7H3N2O6−·C7H4N2O6) were confirmed by single-crystal structure determination. In both structures, the amino molecules bind to the crown ether through N—H...O hydrogen bonds, leaving available only a single O atom site on the crown with restricted geometry to potentially accept a hydrogen bond from 3,5-dnba. While 3,5-dnba and 4-aba form a binary co-crystal containing neutral molecules, the shape-selective nature of 18-crown-6 preferentially binds protonated amino molecules, thereby leading to the formation of the ternary salt, despite the predicted low concentration of the protonated species in the crystallizing solution. Thus, through the choice of crown ether it may be possible to control both location and nature of the available bonding sites for the designed creation of ternary crystals
Nonlinear surface waves in left-handed materials
We study both linear and nonlinear surface waves localized at the interface
separating a left-handed medium (i.e. the medium with both negative dielectric
permittivity and negative magnetic permeability) and a conventional (or
right-handed) dielectric medium. We demonstrate that the interface can support
both TE- and TM-polarized surface waves - surface polaritons, and we study
their properties. We describe the intensity-dependent properties of nonlinear
surface waves in three different cases, i.e. when both the LH and RH media are
nonlinear and when either of the media is nonlinear. In the case when both
media are nonlinear, we find two types of nonlinear surface waves, one with the
maximum amplitude at the interface, and the other one with two humps. In the
case when one medium is nonlinear, only one type of surface wave exists, which
has the maximum electric field at the interface, unlike waves in right-handed
materials where the surface-wave maximum is usually shifted into a
self-focussing nonlinear medium. We discus the possibility of tuning the wave
group velocity in both the linear and nonlinear cases, and show that
group-velocity dispersion, which leads to pulse broadening, can be balanced by
the nonlinearity of the media, so resulting in soliton propagation.Comment: 9 pages, 10 figure
Gyrotropic impact upon negatively refracting surfaces
Surface wave propagation at the interface between different types of gyrotropic materials and an isotropic negatively refracting medium, in which the relative permittivity and relative permeability are, simultaneously, negative is investigated. A general approach is taken that embraces both gyroelectric and gyromagnetic materials, permitting the possibility of operating in either the low GHz, THz or the optical frequency regimes. The classical transverse Voigt configuration is adopted and a complete analysis of non-reciprocal surface wave dispersion is presented. The impact of the surface polariton modes upon the reflection of both plane waves and beams is discussed in terms of resonances and an example of the influence upon the Goos–Hänchen shift is given
Variability in surface chlorophyll a at a shelf-break front
We report an extensive underway sampling of temperature and chlorophyll a in the region of the shelf/slope front in the New York Bight in early spring. Variability in chlorophyll a and frontal structure is analyzed at three spatial scales…
A model structure for coloured operads in symmetric spectra
We describe a model structure for coloured operads with values in the
category of symmetric spectra (with the positive model structure), in which
fibrations and weak equivalences are defined at the level of the underlying
collections. This allows us to treat R-module spectra (where R is a cofibrant
ring spectrum) as algebras over a cofibrant spectrum-valued operad with R as
its first term. Using this model structure, we give suficient conditions for
homotopical localizations in the category of symmetric spectra to preserve
module structures.Comment: 16 page
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Evidence: Biofilter performance and operation as related to commercial composting
This report provides a critical review of available evidence as to how effectively the various categories and configurations of biofilter reduce bioaerosol and odour emissions from composting facilities
The homotopy theory of simplicial props
The category of (colored) props is an enhancement of the category of colored
operads, and thus of the category of small categories. In this paper, the
second in a series on "higher props," we show that the category of all small
colored simplicial props admits a cofibrantly generated model category
structure. With this model structure, the forgetful functor from props to
operads is a right Quillen functor.Comment: Final version, to appear in Israel J. Mat
Assessing the number of users who are excluded by domestic heating controls
This is the pre-print version of the Article. This Article is also referred to as: "Assessing the 'Design Exclusion' of Heating Controls at a Low-Cost, Low-Carbon Housing Development". - Copyright @ 2011 Taylor & FrancisSpace heating accounts for almost 60% of the energy delivered to housing which in turn accounts for nearly 27% of the total UK's carbon emissions. This study was conducted to investigate the influence of heating control design on the degree of ‘user exclusion’. This was calculated using the Design Exclusion Calculator, developed by the Engineering Design Centre at the University of Cambridge. To elucidate the capability requirements of the system, a detailed hierarchical task analysis was produced, due to the complexity of the overall task. The Exclusion Calculation found that the current design placed excessive demands upon the capabilities of at least 9.5% of the UK population over 16 years old, particularly in terms of ‘vision’, ‘thinking’ and ‘dexterity’ requirements. This increased to 20.7% for users over 60 years old. The method does not account for the level of numeracy and literacy and so the true exclusion may be higher. Usability testing was conducted to help validate the results which indicated that 66% of users at a low-carbon housing development could not programme their controls as desired. Therefore, more detailed analysis of the cognitive demands placed upon the users is required to understand where problems within the programming process occur. Further research focusing on this cognitive interaction will work towards a solution that may allow users to behave easily in a more sustainable manner
Nonlinear waves in hyperbolic metamaterials: focus on solitons and rogues
The investigation of hyperbolic metamaterials, shows that metal layers that are part of graphene structures, and also types I and II layered systems, are readily controlled. Since graphene is a nicely conducting sheet it can be easily managed. The literature only eveals a, limited, systematic, approach to the onset of nonlinearity, especially for the methodology based around the famous nonlinear Schrödinger equation [NLSE]. This presentation reveals nonlinear outcomes involving solitons sustained by the popular, and more straightforward to fabricate, type II hyperbolic metamaterials. The NLSE for type II metatamaterials is developed and nonlinear, non-stationary diffraction and dispersion in such important, and active, planar hyperbolic metamaterials is developed. For rogue waves in metamaterials only a few recent numerical studies exist. The basic model assumes a uniform background to which is added a time-evolving perturbation in order to witness the growth of nonlinear waves out of nowhere. This is discussed here using a new NLSE appropriate to hyperbolic metamaterials that would normally produce temporal solitons. The main conclusion is that new pathways for rogue waves can emerge in the form of Peregrine solitons (and near-Peregrines) within a nonlinear hyperbolic metamaterial, based upon double negative guidelines, and where, potentially, magnetooptic control could be practically exerted
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