613 research outputs found
The E. Coli Pyrogen Test in human liver disease
Peer Reviewe
Training-induced inversion of spontaneous exchange bias field on La1.5Ca0.5CoMnO6
In this work we report the synthesis and structural, electronic and magnetic
properties of La1.5Ca0.5CoMnO6 double-perovskite. This is a re-entrant spin
cluster material which exhibits a non-negligible negative exchange bias effect
when it is cooled in zero magnetic field from an unmagnetized state down to low
temperature. X-ray powder diffraction, X-ray photoelectron spectroscopy and
magnetometry results indicate mixed valence state at Co site, leading to
competing magnetic phases and uncompensated spins at the magnetic interfaces.
We compare the results for this Ca-doped material with those reported for the
resemblant compound La1.5Sr0.5CoMnO6, and discuss the much smaller spontaneous
exchange bias effect observed for the former in terms of its structural and
magnetic particularities. For La1.5Ca0.5CoMnO6, when successive magnetization
loops are carried, the spontaneous exchange bias field inverts its sign from
negative to positive from the first to the second measurement. We discuss this
behavior based on the disorder at the magnetic interfaces, related to the
presence of a glassy phase. This compound also exhibits a large conventional
exchange bias, for which there is no sign inversion of the exchange bias field
for consecutive cycles
Magnetic, thermal and transport properties of Cd doped CeIn
We have investigated the effect of Cd substitution on the archetypal heavy
fermion antiferromagnet CeIn via magnetic susceptibility, specific heat and
resistivity measurements. The suppression of the Neel temperature, T,
with Cd doping is more pronounced than with Sn. Nevertheless, a doping induced
quantum critical point does not appear to be achievable in this system. The
magnetic entropy at and the temperature of the maximum in resistivity are
also systematically suppressed with Cd, while the effective moment and the
Curie-Weiss temperature in the paramagnetic state are not affected. These
results suggest that Cd locally disrupts the AFM order on its neighboring Ce
moments, without affecting the valence of Ce. Moreover, the temperature
dependence of the specific heat below is not consistent with 3D magnons
in pure as well as in Cd-doped CeIn, a point that has been missed in
previous investigations of CeIn and that has bearing on the type of quantum
criticality in this system
Distinct high-T transitions in underdoped BaKFeAs
In contrast to the simultaneous structural and magnetic first order phase
transition previously reported, our detailed investigation on an
underdoped BaKFeAs single crystal unambiguously
revealed that the transitions are not concomitant. The tetragonal (:
I4/mmm) - orthorhombic (: Fmmm) structural transition occurs at
110 K, followed by an adjacent antiferromagnetic (AFM) transition
at 102 K. Hysteresis and coexistence of the and
phases over a finite temperature range observed in our NMR
experiments confirm the first order character of the structural transition and
provide evidence that both and are strongly correlated. Our
data also show that superconductivity (SC) develops in the phase
below = 20 K and coexists with long range AFM. This new observation,
, firmly establishes another similarity between the hole-doped
BaFeAs via K substitution and the electron-doped iron-arsenide
superconductors.Comment: 4 pages, 3 figure
New CPT methods for evaluation of the axial capacity of driven piles
High costs associated with offshore foundation installations have provided strong impetus to the offshore energy sector in the search for more reliable design methods. This paper provides a summary of an Industry sponsored project that led to the development of new CPT-based design methods for the evaluation of the axial capacity of driven piles. Particular attention was given to the need for the new methods to be applicable to large diameter offshore piles given that many existing methods are derived by calibration with capacities measured in static pile load tests on smaller diameter onshore piles. The basic mechanisms supporting the general format of the expressions proposed for shaft friction and end bearing in sands and clays are described. It is shown how the new expressions, which are calibrated against a database of the most reliable load tests reported in the literature, lead to better predictions of capacity compared to other methods and can also satisfactorily predict the capacity of piles driven into deposits comprising interbedded layers of sand, silt and clay. Recommendations for the prediction of pile displacements at working loads using CPT data are also presented.New CPT methods for evaluation of the axial capacity of driven pilespublishedVersio
Dynamics of Counterion Condensation
Using a generalization of the Poisson-Boltzmann equation, dynamics of
counterion condensation is studied. For a single charged plate in the presence
of counterions, it is shown that the approach to equilibrium is diffusive. In
the far from equilibrium case of a moving charged plate, a dynamical counterion
condensation transition occurs at a critical velocity. The complex dynamic
behavior of the counterion cloud is shown to lead to a novel nonlinear
force-velocity relation for the moving plate.Comment: 5 pages, 1 ps figure included using eps
REGISTERS OF SEMIOTIC REPRESENTATIONS AIDING THE LEARNING OF COMBINATORIAL SITUATIONS
In order to analyze advances in the resolution of combinatorial situations, due to the identification, conversion and treatment of semiotic registers, two studies were carried out. In the first study, 5th grade students identified, from problems in natural language, registers in trees of possibilities, lists and numerical expressions. The second study, carried out with 5th, 7th and 9th grade students, was configured as an intervention study in which trees or lists were used as an intermediate representation of the departure register (natural language) to the arrival register (numerical expression). The results of the studies confirmed the hypothesis that the conversion to numerical expression is more complex than the conversion to trees or lists. It was also confirmed that trees are more congruent, than lists, with registers in numerical expression. It is concluded that the use of intermediate representations, such as trees or systematic lists, is a good teaching strategy for advances in the combinatorial reasoning of students in the early and middle years of schooling
Compensation temperatures and exchange bias in La1.5Ca0.5CoIrO6
We report on the study of magnetic properties of the La1.5Ca0.5CoIrO6 double
perovskite. Via ac magnetic susceptibility we have observed evidence of weak
ferromagnetism and reentrant spin glass behavior on an antiferromagnetic
matrix. Regarding the magnetic behavior as a function of temperature, we have
found that the material displays up to three inversions of its magnetization,
depending on the appropriate choice of the applied magnetic field. At low
temperature the material exhibit exchange bias effect when it is cooled in the
presence of a magnetic field. Also, our results indicate that this effect may
be observed even when the system is cooled at zero field. Supported by other
measurements and also by electronic structure calculations, we discuss the
magnetic reversals and spontaneous exchange bias effect in terms of magnetic
phase separation and magnetic frustration of Ir4+ ions located between the
antiferromagnetically coupled Co ions.Comment: 10 pages, 8 figures and supplemental materia
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