2,798 research outputs found
Crossover to the KPZ equation
We characterize the crossover regime to the KPZ equation for a class of
one-dimensional weakly asymmetric exclusion processes. The crossover depends on
the strength asymmetry () and it occurs at
. We show that the density field is a solution of an
Ornstein-Uhlenbeck equation if , while for it is
an energy solution of the KPZ equation. The corresponding crossover for the
current of particles is readily obtained.Comment: Published by Annales Henri Poincare Volume 13, Number 4 (2012),
813-82
Thin layer shearing of a highly plastic clay
International audienceShearing tests with a thin layer of clay between filter slabs render possible large and cyclic deformations with drainage. In the pressure range of 100 kPa they serve to validated visco-hypoplastic constitutive relations. This theory is also confirmed by tests with up to 14 MPa and super-imposed anti-plane cycles. After this kind of seismic disturbance the clay stabilizes if the ratio of permanent stresses is undercritical. Otherwise a spontaneous acceleration occurs after a delay. This could help to understand critical phenomena with clay smears in faults
Entanglement Dynamics after a Quench in Ising Field Theory: A Branch Point Twist Field Approach
We extend the branch point twist field approach for the calculation of entanglement entropies to time-dependent problems in 1+1-dimensional massive quantum field theories. We focus on the simplest example: a mass quench in the Ising field theory from initial mass m0 to final mass m. The main analytical results are obtained from a perturbative expansion of the twist field one-point function in the post-quench quasi-particle basis. The expected linear growth of the RĂ©nyi entropies at large times mt â« 1 emerges from a perturbative calculation at second order. We also show that the RĂ©nyi and von Neumann entropies, in infinite volume, contain subleading oscillatory contributions of frequency 2m and amplitude proportional to (mt)â3/2. The oscillatory terms are correctly predicted by an alternative perturbation series, in the pre-quench quasi-particle basis, which we also discuss. A comparison to lattice numerical calculations carried out on an Ising chain in the scaling limit shows very good agreement with the quantum field theory predictions. We also find evidence of clustering of twist field correlators which implies that the entanglement entropies are proportional to the number of subsystem boundary points
Living with Oxygen
Work on the electronic structures of metalâoxo complexes began in Copenhagen over 50 years ago. This work led to the prediction that tetragonal multiply bonded transition metalâoxos would not be stable beyond the ironârutheniumâosmium oxo wall in the periodic table and that triply bonded metalâoxos could not be protonated, even in the strongest BrĂžnsted acids. In this theory, only double bonded metalâoxos could attract protons, with basicities being a function of the electron donating ability of ancillary ligands. Such correlations of electronic structure with reactivity have gained importance in recent years, most notably owing to the widespread recognition that high-valent ironâoxos are intermediates in biological reactions critical to life on Earth.
In this Account, we focus attention on the oxygenations of inert organic substrates by cytochromes P450, as these reactions involve multiply bonded ironâoxos. We emphasize that P450 ironâoxos are strong oxidants, so strong that they would destroy nearby amino acids if substrates are not oxygenated rapidly; it is our view that these high-valent ironâoxos are such dangerous reactive oxygen species that Nature surely found ways to disable them. Looking more deeply into this matter, mainly by examining many thousands of structures in the Protein Data Bank, we have found that P450s and other enzymes that require oxygen for function have chains of tyrosines and tryptophans that extend from active-site regions to protein surfaces. Tyrosines are near the heme active sites in bacterial P450s, whereas tryptophan is closest in most human enzymes. High-valent ironâoxo survival times taken from hole hopping maps range from a few nanoseconds to milliseconds, depending on the distance of the closest Trp or Tyr residue to the heme. In our proposed mechanism, multistep hole tunneling (hopping) through Tyr/Trp chains guides the damaging oxidizing hole to the protein surface, where it can be quenched by soluble protein or small molecule reductants. As the Earthâs oxygenic atmosphere is believed to have developed about 2.5 billion years ago, the increase in occurrence frequency of tyrosine and tryptophan since the last universal evolutionary ancestor may be in part a consequence of enzyme protective functions that developed to cope with the environmental toxin, O_2
Coupling Control Variates for Markov Chain Monte Carlo
We show that Markov couplings can be used to improve the accuracy of Markov
chain Monte Carlo calculations in some situations where the steady-state
probability distribution is not explicitly known. The technique generalizes the
notion of control variates from classical Monte Carlo integration. We
illustrate it using two models of nonequilibrium transport
Corrigendum to âPollen-based paleoenvironmental and paleoclimatic change at Lake Ohrid (south-eastern Europe) during the past 500 kaâ published in Biogeosciences, 13, 1423â1437, 2016
In this corrigendum we report an updated pollen record from the Lake Ohrid DEEP site spanning the past 500 ka whereby we have reprocessed and re-analyzed 104 samples affected by chemical procedure problems that occurred in one palynological laboratory. Firstly, these samples were affected by the use of wrong containers, causing in- adequate settling of particles at the set centrifuging speed. Secondly, HCl and HF treatments were combined without the prescribed intermediate centrifuging and decanting steps. The inaccuracy in the protocol resulted in the loss of smaller pollen grains and in the overrepresentation of bisaccate ones in most of the re-analyzed samples. We therefore provide an updated set of figures with the new data and have revised the description of the results, discussion and conclusions re- ported in Sadori et al. (2016) where necessary. We stress that the majority of the original results and conclusions remain valid, while the recordsâ reliability and resolution have improved as 12 samples that had been omitted in the original study because of low count sums are now included in the revised dataset (Sadori et al., 2018)
Onsager-Machlup theory and work fluctuation theorem for a harmonically driven Brownian particle
We extend Tooru-Cohen analysis for nonequilirium steady state(NSS) of a
Brownian particle to nonequilibrium oscillatory state (NOS) of Brownian
particle by considering time dependent external drive protocol. We consider an
unbounded charged Brownian particle in the presence of an oscillating electric
field and prove work fluctuation theorem, which is valid for any initial
distribution and at all times. For harmonically bounded and constantly dragged
Brownian particle considered by Tooru and Cohen, work fluctuation theorem is
valid for any initial condition(also NSS), but only in large time limit. We use
Onsager-Machlup Lagrangian with a constraint to obtain frequency dependent work
distribution function, and describe entropy production rate and properties of
dissipation functions for the present system using Onsager-Machlup functional.Comment: 6 pages, 1 figur
Exact Free Energy Functional for a Driven Diffusive Open Stationary Nonequilibrium System
We obtain the exact probability of finding a
macroscopic density profile in the stationary nonequilibrium state of
an open driven diffusive system, when the size of the system .
, which plays the role of a nonequilibrium free energy, has a very
different structure from that found in the purely diffusive case. As there,
is nonlocal, but the shocks and dynamic phase transitions of the
driven system are reflected in non-convexity of , in discontinuities in
its second derivatives, and in non-Gaussian fluctuations in the steady state.Comment: LaTeX2e, RevTeX4, PiCTeX. Four pages, one PiCTeX figure included in
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