10 research outputs found
Extensional basins of the former Soviet Union: structure, basin formation mechanisms and subsidence history
ΠΠΎΠ»Π΅Π·Π½Ρ ΠΡΠΎΠ½Π° Ρ ΠΈΠ·ΠΎΠ»ΠΈΡΠΎΠ²Π°Π½Π½ΡΠΌ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΠ΅ΠΌ ΠΆΠ΅Π»ΡΠ΄ΠΊΠ° ΠΊΠ°ΠΊ ΠΏΡΠΈΠΌΠ΅Ρ ΡΠ΅Π΄ΠΊΠΎΠ³ΠΎ ΡΠ΅Π½ΠΎΡΠΈΠΏΠ° Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΡ: ΠΊΠ»ΠΈΠ½ΠΈΡΠ΅ΡΠΊΠΎΠ΅ Π½Π°Π±Π»ΡΠ΄Π΅Π½ΠΈΠ΅
Crohn's disease (CD), along with ulcerative colitis, is one of the predominant nosological forms of inflammatory bowel diseases. In CD, any part of the gastrointestinal tract can be affected; however, the process is commonly associated with terminal ileum or colon involvement. CD cases with isolated or mixed involvement of upper gastrointestinal tract (esophagus, stomach, and duodenum) are rare and least studied types of the disease. In isolated stomach involvement, the complaints are non-specific and include epigastric pain, gastric dyspepsia, early satiety, decreased appetite, and nausea. Isolated CD of upper gastrointestinal tract can be diagnosed after comprehensive work-up and always requires a high diagnostic level, including clinical, endoscopic and morphological one. We present a clinical case of CD with isolated stomach involvement in a 62-year-old woman. The diagnosis was confirmed by the histopathological findings of an epithelioid cell granuloma in the gastric antrum. Treatment with systemic corticosteroids reduced the disease clinical activity and improved the histological characteristics of the gastric biopsy sampled obtained by endoscopy. In this clinical case, there were specific macroscopic gastric lesions found at endoscopy in CD patients with upper gastrointestinal tract involvement, which is characterized by thickened longitudinal folding and linear grooves. This type of lesion has been described in the literature as βbamboo joint-like appearanceβ.Conclusion: Comprehensive assessment of clinical manifestations, endoscopic and histopathological specific features is crucial for the timely diagnosis and treatment of inflammatory bowel diseases.ΠΠΎΠ»Π΅Π·Π½Ρ ΠΡΠΎΠ½Π° (ΠΠ) Π½Π°ΡΡΠ΄Ρ Ρ ΡΠ·Π²Π΅Π½Π½ΡΠΌ ΠΊΠΎΠ»ΠΈΡΠΎΠΌ ΠΏΡΠ΅Π΄ΡΡΠ°Π²Π»ΡΠ΅Ρ ΡΠΎΠ±ΠΎΠΉ ΠΎΠ΄Π½Ρ ΠΈΠ· ΠΏΡΠ΅ΠΎΠ±Π»Π°Π΄Π°ΡΡΠΈΡ
Π½ΠΎΠ·ΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΡ
ΡΠΎΡΠΌ Π² ΡΡΡΡΠΊΡΡΡΠ΅ Π²ΠΎΡΠΏΠ°Π»ΠΈΡΠ΅Π»ΡΠ½ΡΡ
Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΠΉ ΠΊΠΈΡΠ΅ΡΠ½ΠΈΠΊΠ°. ΠΡΠΈ ΠΠ ΠΌΠΎΠΆΠ΅Ρ Π±ΡΡΡ ΠΏΠΎΡΠ°ΠΆΠ΅Π½Π° Π»ΡΠ±Π°Ρ ΡΠ°ΡΡΡ ΠΆΠ΅Π»ΡΠ΄ΠΎΡΠ½ΠΎ-ΠΊΠΈΡΠ΅ΡΠ½ΠΎΠ³ΠΎ ΡΡΠ°ΠΊΡΠ° (ΠΠΠ’), Π½ΠΎ ΠΎΠ±ΡΡΠ½ΠΎ ΠΏΡΠΎΡΠ΅ΡΡ ΡΠ²ΡΠ·Π°Π½ Ρ Π²ΠΎΠ²Π»Π΅ΡΠ΅Π½ΠΈΠ΅ΠΌ ΡΠ΅ΡΠΌΠΈΠ½Π°Π»ΡΠ½ΠΎΠ³ΠΎ ΠΎΡΠ΄Π΅Π»Π° ΠΏΠΎΠ΄Π²Π·Π΄ΠΎΡΠ½ΠΎΠΉ ΠΈΠ»ΠΈ ΡΠΎΠ»ΡΡΠΎΠΉ ΠΊΠΈΡΠΊΠΈ. Π‘Π»ΡΡΠ°ΠΈ ΠΠ Ρ ΠΈΠ·ΠΎΠ»ΠΈΡΠΎΠ²Π°Π½Π½ΡΠΌ ΠΈΠ»ΠΈ ΡΠΎΡΠ΅ΡΠ°Π½Π½ΡΠΌ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΠ΅ΠΌ Π²Π΅ΡΡ
Π½ΠΈΡ
ΠΎΡΠ΄Π΅Π»ΠΎΠ² ΠΠΠ’ (ΠΏΠΈΡΠ΅Π²ΠΎΠ΄Π°, ΠΆΠ΅Π»ΡΠ΄ΠΊΠ° ΠΈ Π΄Π²Π΅Π½Π°Π΄ΡΠ°ΡΠΈΠΏΠ΅ΡΡΡΠ½ΠΎΠΉ ΠΊΠΈΡΠΊΠΈ) β ΡΠ΅Π΄ΠΊΠΎ Π²ΡΡΡΠ΅ΡΠ°Π΅ΠΌΡΠ΅ ΠΈ Π½Π°ΠΈΠΌΠ΅Π½Π΅Π΅ ΠΈΠ·ΡΡΠ΅Π½Π½ΡΠ΅ Π²Π°ΡΠΈΠ°Π½ΡΡ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΡ. ΠΡΠΈ ΠΈΠ·ΠΎΠ»ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΌ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΠΈ ΠΆΠ΅Π»ΡΠ΄ΠΊΠ° ΠΆΠ°Π»ΠΎΠ±Ρ Π½Π΅ΡΠΏΠ΅ΡΠΈΡΠΈΡΠ½Ρ ΠΈ Π²ΠΊΠ»ΡΡΠ°ΡΡ Π±ΠΎΠ»ΠΈ Π² ΡΠΏΠΈΠ³Π°ΡΡΡΠ°Π»ΡΠ½ΠΎΠΉ ΠΎΠ±Π»Π°ΡΡΠΈ, ΠΆΠ΅Π»ΡΠ΄ΠΎΡΠ½ΡΡ Π΄ΠΈΡΠΏΠ΅ΠΏΡΠΈΡ, ΡΡΠ²ΡΡΠ²ΠΎ ΡΠ°Π½Π½Π΅Π³ΠΎ Π½Π°ΡΡΡΠ΅Π½ΠΈΡ, ΡΠ½ΠΈΠΆΠ΅Π½ΠΈΠ΅ Π°ΠΏΠΏΠ΅ΡΠΈΡΠ°, ΡΠΎΡΠ½ΠΎΡΡ. ΠΠΈΠ°Π³Π½ΠΎΠ· ΠΈΠ·ΠΎΠ»ΠΈΡΠΎΠ²Π°Π½Π½ΠΎΠΉ ΠΠ Π²Π΅ΡΡ
Π½ΠΈΡ
ΠΎΡΠ΄Π΅Π»ΠΎΠ² ΠΠΠ’ ΠΌΠΎΠΆΠ΅Ρ Π±ΡΡΡ ΡΡΡΠ°Π½ΠΎΠ²Π»Π΅Π½ ΠΏΡΠΈ ΠΊΠΎΠΌΠΏΠ»Π΅ΠΊΡΠ½ΠΎΠΌ ΠΎΠ±ΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠΈ, ΡΡΠΎ Π²ΡΠ΅Π³Π΄Π° ΡΡΠ΅Π±ΡΠ΅Ρ Π²ΡΡΠΎΠΊΠΎΠ³ΠΎ ΡΡΠΎΠ²Π½Ρ Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΠΈ (ΠΊΠ»ΠΈΠ½ΠΈΡΠ΅ΡΠΊΠΎΠΉ, ΡΠ½Π΄ΠΎΡΠΊΠΎΠΏΠΈΡΠ΅ΡΠΊΠΎΠΉ, ΠΌΠΎΡΡΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΉ). Π ΡΡΠ°ΡΡΠ΅ Π΄Π°Π½ΠΎ ΠΎΠΏΠΈΡΠ°Π½ΠΈΠ΅ ΠΊΠ»ΠΈΠ½ΠΈΡΠ΅ΡΠΊΠΎΠ³ΠΎ Π½Π°Π±Π»ΡΠ΄Π΅Π½ΠΈΡ ΠΠ Ρ ΠΈΠ·ΠΎΠ»ΠΈΡΠΎΠ²Π°Π½Π½ΡΠΌ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΠ΅ΠΌ ΠΆΠ΅Π»ΡΠ΄ΠΊΠ° Ρ 62-Π»Π΅ΡΠ½Π΅ΠΉ ΠΆΠ΅Π½ΡΠΈΠ½Ρ. ΠΠΈΠ°Π³Π½ΠΎΠ· Π±ΡΠ» ΠΏΠΎΠ΄ΡΠ²Π΅ΡΠΆΠ΄Π΅Π½ Π½Π°Π»ΠΈΡΠΈΠ΅ΠΌ ΡΠΏΠΈΡΠ΅Π»ΠΈΠΎΠΈΠ΄Π½ΠΎΠΊΠ»Π΅ΡΠΎΡΠ½ΠΎΠΉ Π³ΡΠ°Π½ΡΠ»Π΅ΠΌΡ Π² Π°Π½ΡΡΠ°Π»ΡΠ½ΠΎΠΌ ΠΎΡΠ΄Π΅Π»Π΅ ΠΆΠ΅Π»ΡΠ΄ΠΊΠ° ΠΏΡΠΈ ΠΏΠ°ΡΠΎΠ³ΠΈΡΡΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΎΠΌ ΠΈΡΡΠ»Π΅Π΄ΠΎΠ²Π°Π½ΠΈΠΈ. ΠΠ° ΡΠΎΠ½Π΅ Π»Π΅ΡΠ΅Π½ΠΈΡ ΡΠΈΡΡΠ΅ΠΌΠ½ΡΠΌΠΈ Π³Π»ΡΠΊΠΎΠΊΠΎΡΡΠΈΠΊΠΎΡΡΠ΅ΡΠΎΠΈΠ΄Π°ΠΌΠΈ Π΄ΠΎΡΡΠΈΠ³Π½ΡΡΠΎ ΡΠ½ΠΈΠΆΠ΅Π½ΠΈΠ΅ ΠΊΠ»ΠΈΠ½ΠΈΡΠ΅ΡΠΊΠΎΠΉ Π°ΠΊΡΠΈΠ²Π½ΠΎΡΡΠΈ Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΡ ΠΈ ΡΠ»ΡΡΡΠ΅Π½ΠΈΠ΅ Π³ΠΈΡΡΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΡ
Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΡΡΠΈΠΊ Π±ΠΈΠΎΠΏΡΠ°ΡΠΎΠ² ΠΈΠ· ΠΆΠ΅Π»ΡΠ΄ΠΊΠ°, ΠΏΠΎΠ»ΡΡΠ΅Π½Π½ΡΡ
ΠΏΡΠΈ ΡΠ½Π΄ΠΎΡΠΊΠΎΠΏΠΈΠΈ. Π Π½Π°ΡΠ΅ΠΌ Π½Π°Π±Π»ΡΠ΄Π΅Π½ΠΈΠΈ Π±ΡΠ»ΠΎ Π²ΡΡΠ²Π»Π΅Π½ΠΎ ΡΠΏΠ΅ΡΠΈΡΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΌΠ°ΠΊΡΠΎΡΠΊΠΎΠΏΠΈΡΠ΅ΡΠΊΠΎΠ΅ ΠΏΠΎΡΠ°ΠΆΠ΅Π½ΠΈΠ΅ ΠΆΠ΅Π»ΡΠ΄ΠΊΠ°, Π½Π°Π±Π»ΡΠ΄Π°Π΅ΠΌΠΎΠ΅ ΠΏΡΠΈ ΡΠ½Π΄ΠΎΡΠΊΠΎΠΏΠΈΠΈ Ρ Π±ΠΎΠ»ΡΠ½ΡΡ
ΠΠ Π²Π΅ΡΡ
Π½ΠΈΡ
ΠΎΡΠ΄Π΅Π»ΠΎΠ² ΠΠΠ’, Ρ
Π°ΡΠ°ΠΊΡΠ΅ΡΠΈΠ·ΡΡΡΠ΅Π΅ΡΡ ΡΡΠΎΠ»ΡΠ΅Π½Π½ΡΠΌΠΈ ΠΏΡΠΎΠ΄ΠΎΠ»ΡΠ½ΡΠΌΠΈ ΡΠΊΠ»Π°Π΄ΠΊΠ°ΠΌΠΈ ΠΈ Π»ΠΈΠ½Π΅ΠΉΠ½ΡΠΌΠΈ Π±ΠΎΡΠΎΠ·Π΄Π°ΠΌΠΈ, ΠΎΠΏΠΈΡΠ°Π½Π½ΠΎΠ΅ ΡΠ°Π½Π΅Π΅ Π² Π»ΠΈΡΠ΅ΡΠ°ΡΡΡΠ΅ ΠΊΠ°ΠΊ Β«ΡΠΎΡΠ»Π΅Π½Π΅Π½ΠΈΡ ΡΡΠ²ΠΎΠ»Π° Π±Π°ΠΌΠ±ΡΠΊΠΎΠ²ΠΎΠ³ΠΎ Π΄Π΅ΡΠ΅Π²Π°Β» (Π°Π½Π³Π». bamboo-joint-like appearance).ΠΠ°ΠΊΠ»ΡΡΠ΅Π½ΠΈΠ΅. ΠΠΎΠΌΠΏΠ»Π΅ΠΊΡΠ½Π°Ρ ΠΎΡΠ΅Π½ΠΊΠ° ΠΊΠ»ΠΈΠ½ΠΈΡΠ΅ΡΠΊΠΎΠΉ ΠΊΠ°ΡΡΠΈΠ½Ρ, ΡΠ½Π΄ΠΎΡΠΊΠΎΠΏΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΈ Π³ΠΈΡΡΠΎΠΏΠ°ΡΠΎΠ»ΠΎΠ³ΠΈΡΠ΅ΡΠΊΠΈΡ
ΠΎΡΠΎΠ±Π΅Π½Π½ΠΎΡΡΠ΅ΠΉ ΠΈΠΌΠ΅Π΅Ρ ΡΠ΅ΡΠ°ΡΡΠ΅Π΅ Π·Π½Π°ΡΠ΅Π½ΠΈΠ΅ Π΄Π»Ρ ΡΠ²ΠΎΠ΅Π²ΡΠ΅ΠΌΠ΅Π½Π½ΠΎΠΉ Π΄ΠΈΠ°Π³Π½ΠΎΡΡΠΈΠΊΠΈ ΠΈ Π»Π΅ΡΠ΅Π½ΠΈΡ Π²ΠΎΡΠΏΠ°Π»ΠΈΡΠ΅Π»ΡΠ½ΡΡ
Π·Π°Π±ΠΎΠ»Π΅Π²Π°Π½ΠΈΠΉ ΠΊΠΈΡΠ΅ΡΠ½ΠΈΠΊΠ°
Electro-deionization of Cr (VI)-Containing solution. Part I: Chromium transport through granulated inorganic ion-exchanger
Kinetics of Cr (VI)βΊOH- exchange on both hydrogel and xerogel of hydrated zirconium dioxide was investigated. Self-diffusion coefficient of Cr (VI) species has been determined by analysis of kinetic curves. Transport of Cr (VI) anions through the inorganic ion exchangers under the influence of applied voltage was also researched. In the case of hydrogel, the ions are transported mainly through the solid phase. Diffusion coefficient of chromate anions through this material was estimated as 9.00 Γ 10-12 m2 s-1. This is in agreement with self-diffusion coefficient of Cr (VI) obtained from kinetic measurements (1.60 Γ 10-12-9.92 Γ 10-12 m2 s-1). Owing to the rather high mobility of Cr (VI) through hydrogel of hydrated zirconium dioxide, this material was recommended for electro-deionization processes. On the other hand, the use of polymer anion-exchange membrane must be excluded to prevent poisoning of the inorganic ion exchanger with Cr (III) cations to be formed during chemical interaction of Cr (VI) with organic materials
Electro-deionization of Cr (VI)-Containing solution. Part II: Chromium transport through Inorganic ion-exchanger and composite ceramic membrane
Cr (VI) transport through a composite ceramic membrane containing an ion-exchange component, namely xerogel of hydrated zirconium dioxide, was investigated. The diffusion coefficient of Cr (VI) species through the membrane, which has been determined under open circuit conditions, is 1.80 Γ 10-10 m2 s-1. The transport number of Cr (VI) species through the ceramic membrane was found to rise with increasing voltage and reached 0.17 under "over-limiting current" conditions. On the other hand, the transport of chromate ions through hydrogel of hydrated zirconium dioxide becomes more intensive with a decrease in potential drop through the system involving ion-exchanger bed and ceramic membrane due to decrease in the membrane resistance. The diffusion coefficient of Cr (VI) ions in hydrogel of the inorganic ion exchanger was estimated as 4.36 Γ 10-12 m2 s-1. A possibility of Cr (VI) removal from a weakly acidic diluted solution using an electro-deionization method was shown: the degree of solution purification was found to reach 50%. The transport of species is realized through both the solution and the ion exchanger.Ministry of Education and Science of Ukraine: TUBITAK-CAYDAG-104Y399This research was supported by TUBITAK and Ministry of Education and Science of Ukraine (TUBITAK-CAYDAG-104Y399). -
Assessment of Creep Strain Distribution Across Base Metal of 316LN Austenitic Stainless Steel Weld Joint by an EBSD-Based Parameter
Effect of Cold Deformation and Annealing on the Microstructure and Tensile Properties of a HfNbTaTiZr Refractory High Entropy Alloy
The interplay between molecular layering and clustering in adsorption of gases on graphitized thermal carbon black - Spill-over phenomenon and the important role of strong sites
We analyse in detail our experimental data, our simulation results and data from the literature, for the adsorption of argon, nitrogen, carbon dioxide, methanol, ammonia and water on graphitized carbon black (GTCB), and show that there are two mechanisms of adsorption at play, and that their interplay governs how different gases adsorb on the surface by either: (1) molecular layering on the basal plane or (2) clustering around very strong sites on the adsorbent whose affinity is much greater than that of the basal plane or the functional groups. Depending on the concentration of the very strong sites or the functional groups, the temperature and the relative strength of the three interactions, (a) fluid-strong sites (fine crevices and functional group) (F-SS), (b) fluid-basal plane (FB) and (c) fluidβfluid (FF), the uptake of adsorbate tends to be dominated by one mechanism. However, there are conditions (temperature and adsorbate) where two mechanisms can both govern the uptake. For simple gases, like argon, nitrogen and carbon dioxide, adsorption proceeds by molecular layering on the basal plane of graphene, but for water which represents an extreme case of a polar molecule, clustering around the strong sites or the functional groups at the edges of the graphene layers is the major mechanism of adsorption and there is little or no adsorption on the basal planes because the F-SS and FF interactions are far stronger than the FB interaction. For adsorptives with lower polarity, exemplified by methanol or ammonia, the adsorption mechanism switches from clustering to layering in the order: ammonia, methanol; and we suggest that the bridging between these two mechanisms is a molecular spill-over phenomenon, which has not been previously proposed in the literature in the context of physical adsorption