Nuclear energy density functional from chiral pion-nucleon dynamics: Isovector spin-orbit terms

We extend a recent calculation of the nuclear energy density functional in the systematic framework of chiral perturbation theory by computing the isovector spin-orbit terms: $(\vec \nabla \rho_p- \vec \nabla \rho_n)\cdot(\vec J_p-\vec J_n) G_{so}(k_f)+ (\vec J_p-\vec J_n)^2 G_J(k_f)$. The calculation includes the one-pion exchange Fock diagram and the iterated one-pion exchange Hartree and Fock diagrams. From these few leading order contributions in the small momentum expansion one obtains already a good equation of state of isospin-symmetric nuclear matter. We find that the parameterfree results for the (density-dependent) strength functions $G_{so}(k_f)$ and $G_J(k_f)$ agree fairly well with that of phenomenological Skyrme forces for densities $\rho > \rho_0/10$. At very low densities a strong variation of the strength functions $G_{so}(k_f)$ and $G_J(k_f)$ with density sets in. This has to do with chiral singularities $m_\pi^{-1}$ and the presence of two competing small mass scales $k_f$ and $m_\pi$. The novel density dependencies of $G_{so}(k_f)$ and $G_J(k_f)$ as predicted by our parameterfree (leading order) calculation should be examined in nuclear structure calculations.Comment: 9 pages, 3 figure, published in: Physical Review C68, 014323 (2003

Mean-field description of ground-state properties of drip-line nuclei. (I) Shell-correction method

A shell-correction method is applied to nuclei far from the beta stability line and its suitability to describe effects of the particle continuum is discussed. The sensitivity of predicted locations of one- and two-particle drip lines to details of the macroscopic-microscopic model is analyzed.Comment: 22 REVTeX pages, 13 uuencoded postscript figures available upon reques

Nuclear isospin mixing and elastic parity-violating electron scattering

The influence of nuclear isospin mixing on parity-violating elastic electron scattering is studied for the even-even, N=Z nuclei 12C, 24Mg, 28Si, and 32S. Their ground-state wave functions have been obtained using a self-consistent axially-symmetric mean-field approximation with density-dependent effective two-body Skyrme interactions. Some differences from previous shell-model calculations appear for the isovector Coulomb form factors which play a role in determining the parity-violating asymmetry. To gain an understanding of how these differences arise, the results have been expanded in a spherical harmonic oscillator basis. Results are obtained not only within the plane-wave Born approximation, but also using the distorted-wave Born approximation for comparison with potential future experimental studies of parity-violating electron scattering. To this end, for each nucleus the focus is placed on kinematic ranges where the signal (isospin-mixing effects on the parity-violating asymmetry) and the experimental figure-of-merit are maximized. Strangeness contributions to the asymmetry are also briefly discussed, since they and the isospin mixing contributions may play comparable roles for the nuclei being studied at the low momentum transfers of interest in the present work.Comment: 25 pages, 9 figure

Glass transition and polymer dynamics in silver/poly(methyl methacrylate) nanocomposites

Dynamic mechanical-thermal analysis (DMTA), differential scanning calorimetry (DSC), thermally stimulated depolarization currents (TSDC) and, mainly, broadband dielectric relaxation spectroscopy (DRS) were employed to investigate in detail glass transition and polymer dynamics in silver/poly(methyl methacrylate) (Ag/PMMA) nanocomposites. The nanocomposites were prepared by radical polymerization of MMA in the presence of surface modified Ag nanoparticles with a mean diameter of 5.6 nm dispersed in chloroform. The fraction of Ag nanoparticles in the final materials was varied between 0 and 0.5 wt%, the latter corresponding to 0.055 vol%. The results show that the nanoparticles have practically no effect on the time scale of the secondary ß and ¿ relaxations, whereas the magnitude of both increases slightly but systematically with increasing filler content. The segmental ¿ relaxation, associated with the glass transition, becomes systematically faster and stronger in the nanocomposites. The glass transition temperature T g decreases with increasing filler content of the nanocomposites up to about 10 °C, in good correlation by the four techniques employed. Finally, the elastic modulus decreases slightly but systematically in the nanocomposites, both in the glassy and in the rubbery state. The results are explained in terms of plasticization of the PMMA matrix, due to constraints imposed to packing of the chains by the Ag nanoparticles, and at the same time, of the absence of strong polymer-filler interactions, due to the surface modification of the Ag nanoparticles by oleylamine at the stage of preparation. © 2011 Elsevier Ltd. All rights reserved.JLGR acknowledges the support of the Spanish Ministry of Science and Innovation through project No. EUI2008-00126 and funding in the Centro de Investigacion Principe Felipe in the field of Regenerative Medicine through the collaboration agreement from the Conselleria de Sanidad (Generalitat Valenciana), and the Instituto de Salud Carlos III (Ministry of Science and Innovation).Pandis, C.; Logakis, E.; Kyritsis, A.; Pissis, P.; Vodnik, VV.; Dzunuzovic, E.; Nedeljkovic, JM.... (2011). Glass transition and polymer dynamics in silver/poly(methyl methacrylate) nanocomposites. EUROPEAN POLYMER JOURNAL. 47(8):1514-1525. https://doi.org/10.1016/j.eurpolymj.2011.06.001S1514152547