2,844 research outputs found
The isotope composition of water vapour: A powerful tool to study transport and chemistry of middle atmospheric water vapour
International audienceA one-dimensional chemistry model is applied to study the stable hydrogen (D) and stable oxygen isotope (17O, 18O) composition of water vapour in stratosphere and mesosphere. The stable isotope ratios of tropospheric H2O are determined by "physical'' fractionation effects, i.e. phase changes, diffusion processes, and mixing of air masses. Due to these processes water vapour entering the stratosphere (i) is mass-dependently fractionated (MDF), i.e. shifts in the isotope ratio 17O/16O are ~0.52 times of those of 18O/16O and (ii) shows isotope shifts in D/H, which are ~5 times of those in 18O/16O. In stratosphere and mesosphere "chemical'' fractionation, that are the oxidation of methane, re-cycling of H2O via the HOx family, and isotope exchange reactions are shown to considerably enhance the isotope ratios in the imported tropospheric H2O. Enrichments relative to the isotope ratios at the tropopause are used to derive the partitioning of tropospheric (unmodified), re-cycled and in situ generated H2O. The model reasonably predicts overall increases of the stable isotope ratios in H2O by ~23% for D/H, ~8.5% for 17O/16O, and ~14% for 18O/16O. The17O/16O and 18O/16O ratios in H2O are shown to be a measure of the partitioning of HOx that receives its O atom either from the reservoirs O2 or O3. In the entire middle atmosphere, MDF O2 is the major donator of oxygen atoms incorporated in OH and HO2 and thus in H2O. It is demonstrated that in the stratosphere mass-independent fractionation (MIF) in O3 in a first step is transferred to the NOx family and only in a second step to HOx and H2O. In contrast to CO2, O(1D) only plays a minor role in this MIF transfer. The major uncertainty in our calculation arises from the many badly quantified isotope exchange reactions and kinetic isotope fractionation factors
An Assessment of Integrated Flywheel System Technology
The current state of the technology in flywheel storage systems and ancillary components, the technology in light of future requirements, and technology development needs to rectify these shortfalls were identified. Technology efforts conducted in Europe and in the United States were reviewed. Results of developments in composite material rotors, magnetic suspension systems, motor/generators and electronics, and system dynamics and control were presented. The technology issues for the various disciplines and technology enhancement scenarios are discussed. A summary of the workshop, and conclusions and recommendations are presented
Prebiotically Plausible Organocatalysts Enabling a Selective Photoredox α‐Alkylation of Aldehydes on the Early Earth
Organocatalysis is a powerful approach to extend and (enantio‐) selectively modify molecular structures. Adapting this concept to the Early Earth scenario offers a promising solution to explain their evolution into a complex homochiral world. Herein, we present a class of imidazolidine‐4‐thione organocatalysts, easily accessible from simple molecules available on an Early Earth under highly plausible prebiotic reaction conditions. These imidazolidine‐4‐thiones are readily formed from mixtures of aldehydes or ketones in presence of ammonia, cyanides and hydrogen sulfide in high selectivity and distinct preference for individual compounds of the resulting catalyst library. These organocatalysts enable the enantioselective α‐alkylation of aldehydes under prebiotic conditions and show activities that correlate with the selectivity of their formation. Furthermore, the crystallization of single catalysts as conglomerates opens the pathway for symmetry breaking
Ultrafast Dynamics of Vibrational Symmetry Breaking in a Charge-ordered Nickelate
The ability to probe symmetry breaking transitions on their natural time
scales is one of the key challenges in nonequilibrium physics. Stripe ordering
represents an intriguing type of broken symmetry, where complex interactions
result in atomic-scale lines of charge and spin density. Although phonon
anomalies and periodic distortions attest the importance of electron-phonon
coupling in the formation of stripe phases, a direct time-domain view of
vibrational symmetry breaking is lacking. We report experiments that track the
transient multi-THz response of the model stripe compound
LaSrNiO, yielding novel insight into its electronic and
structural dynamics following an ultrafast optical quench. We find that
although electronic carriers are immediately delocalized, the crystal symmetry
remains initially frozen - as witnessed by time-delayed suppression of
zone-folded Ni-O bending modes acting as a fingerprint of lattice symmetry.
Longitudinal and transverse vibrations react with different speeds, indicating
a strong directionality and an important role of polar interactions. The hidden
complexity of electronic and structural coupling during stripe melting and
formation, captured here within a single terahertz spectrum, opens new paths to
understanding symmetry breaking dynamics in solids.Comment: 21 pages, 4 figures; updated version with journal re
Long-Term Potentiation: One Kind or Many?
Do neurobiologists aim to discover natural kinds? I address this question in this chapter via a critical analysis of classification practices operative across the 43-year history of research on long-term potentiation (LTP). I argue that this 43-year history supports the idea that the structure of scientific practice surrounding LTP research has remained an obstacle to the discovery of natural kinds
Classification and modelling of urban micro-climates using multisensoral and multitemporal remote sensing data
Remote sensing has widely been used in urban climatology since it has the advantage of a simultaneous synoptic view of the full
urban surface. Methods include the analysis of surface temperature patterns, spatial (biophysical) indicators for urban heat island
modelling, and flux measurements. Another approach is the automated classification of urban morphologies or structural types.
In this study it was tested, whether Local Climate Zones (a new typology of thermally 'rather' homogenous urban morphologies) can
be automatically classified from multisensor and multitemporal earth observation data. Therefore, a large number of parameters
were derived from different datasets, including multitemporal Landsat data and morphological profiles as well as windowed
multiband signatures from an airborne IFSAR-DHM.
The results for Hamburg, Germany, show that different datasets have high potential for the differentiation of urban morphologies.
Multitemporal thermal data performed very well with up to 96.3 % overall classification accuracy with a neuronal network
classifier. The multispectral data reached 95.1 % and the morphological profiles 83.2 %.The multisensor feature sets reached up to
97.4 % with 100 selected features, but also small multisensoral feature sets reached good results. This shows that microclimatic
meaningful urban structures can be classified from different remote sensing datasets.
Further, the potential of the parameters for spatiotemporal modelling of the mean urban heat island was tested. Therefore, a
comprehensive mobile measurement campaign with GPS loggers and temperature sensors on public buses was conducted in order to
gain in situ data in high spatial and temporal resolution
Antipersonnel Landmines Detection by Holographic Radar Imaging: An Experimental Study of Soil Effects
Permeability is the critical factor governing the life cycle environmental performance of drinking water treatment using living filtration membranes.
Living Filtration Membranes (LFMs) are a water filtration technology that was recently developed in the lab (Technology Readiness Level 4). LFMs have shown filtration performance comparable with that of ultrafiltration, far better fouling resistance than conventional polymer membranes, and good healing capabilities. These properties give LFMs promise to address two significant issues in conventional membrane filtration: fouling and membrane damage. To integrate environmental considerations into future technology development (i.e., Ecodesign), this study assesses the life cycle environmental performance of drinking water treatment using LFMs under likely design and operation conditions. It also quantitatively ranks the engineering design and operation factors governing the further optimization of LFM environmental performance using a global sensitivity analysis. The results suggest that LFMs' superior fouling resistance will reduce the life cycle environmental impacts of ultrafiltration by 25% compared to those of a conventional polymer membrane in most impact categories (e.g., acidification, global warming potential, and carcinogenics). The only exception is the eutrophication impact, where the need for growth medium and membrane regeneration offsets the benefits of LFMs' fouling resistance. Permeability is the most important factor that should be prioritized in future R&D to further improve the life cycle environmental performance of LFMs. A 1% improvement in the permeability will lead to a ∼0.7% improvement in LFMs' environmental performance in all the impact categories, whereas the same change in the other parameters investigated (e.g., LFM lifespan and regeneration frequency) typically only leads to a <0.2% improvement
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