Ciclostratigrafia e tuning astronomico delle alternanze calcareo-marnosi Maastrichtiane di Zumaia e Sopelana, Paesi Baschi, N-Spagna - Cyclostratigraphy and astronomical tuning of the Maastrichtian limestone-marl alternations of Zumaia and Sopelana, Basque country, N-Spain

We present an astronomical time scale for the Maastrichtian based on an integrated stratigraphy of the Zumaia and Sopelana sections in northern Spain. The cyclic alternations of hemipelagic limestones and marls at Sopelana and Zumaia display the range of periodicities of eccentricity-modulated precession. The rhythmic bedding pattern is primarily caused by variations in siliciclastic supply and to a lesser extent to variations in biological productivity, both of which controlled by eccentricity-modulated precession through its influence on the hydrological cycle. Together, the Zumaia and Sopelana sections span almost the entire Maastrichtian, and encompass thirteen 405-kyr cycles, spanning a total duration of 5.3 Myr. Consecutive 405-kyr minima in the lithological and geophysical data records are tuned to successive 405-kyr minima in the new La2011 eccentricity solution. Assuming a K/Pg boundary age of 65.97 Ma, we present orbitally tuned ages of biostratigraphic and magnetostratigraphic events. The bases of Chrons C29r and C30n have been reliably established at Zumaia and their astronomically tuned ages are in good agreement with previous studies. Data from Sopelana provide a refinement of the age of the base of Chron C31r. Planktonic foraminifera and calcareous nannoplankton data from Zumaia, and new calcareous nannoplankton data from Sopelana allow for worldwide correlation of the cyclostratigraphy of the Basque country. Additionally, the orbitally tuned bulk carbonate carbon isotope curve displays a remarkable amplitude of variation. Strong oscillations in δ13C seem regularly paced by the 405-kyr periodicity of eccentricity modulated precession. Additionally, sharp negative shifts associated with falls in sea-level occur at regular intervals of ~1.2 Myr. We present a new global correlation of carbon isotope stratigraphies with an astronomically tuned age model based on the cyclostratigraphy of Zumaia and Sopelana and site 762C (Exmouth Plateau). The Late Campanian/Maastrichtian carbon isotope correlation scheme displays a series of trends and excursions that can be observed across the different depositional settings. We propose that the 405-kyr cycle of eccentricity, and potentially longer periodicities, paced the latest Cretaceous climate and carbon cycle

A re‐evaluation of the Plenus Cold Event, and the links between CO2, temperature, and seawater chemistry during OAE 2

International audienceThe greenhouse world of the mid‐Cretaceous (~94 Ma) was punctuated by an episode of abrupt climatic upheaval: Oceanic Anoxic Event 2 (OAE 2). High‐resolution climate records reveal considerable changes in temperature, carbon cycling, and ocean chemistry during this climatic perturbation. In particular, an interval of cooling has been detected in the English Chalk on the basis of an invasive boreal fauna and bulk oxygen‐isotope excursions registered during the early stages of OAE 2—a phenomenon known as the Plenus Cold Event (PCE), which has tentatively been correlated with climatic shifts worldwide.Here we present new high‐resolution neodymium‐, carbon‐, and oxygen‐isotope data, as well as elemental chromium concentrations and cerium anomalies, from the English Chalk exposed at Dover, UK, which we evaluate in the context of >400 records from across the globe. A negative carbon‐isotope excursion that correlates with the original ‘PCE’ is consistently expressed worldwide, and CO2 proxy records, where available, indicate a rise and subsequent fall in CO2 over the Plenus interval. However, variability in the timing and expression of cooling at different sites suggests that, although sea‐surface paleo‐temperatures may reflect a response to global CO2 change, local processes likely played a dominant role at many sites. Variability in the timing and expression of changes in water‐mass character, and problems in determining the driver of observed proxy changes, suggest that no single simple mechanism can link the carbon cycle to oceanography during the Plenus interval and other factors including upwelling and circulation patterns were locally important. As such, it is proposed that the Plenus carbon‐isotope event is a more reliable stratigraphic marker to identify the Plenus interval, rather than any climatic shifts that may have been overprinted by local effects

Helium-isotope constraints on palaeoceanographic change and sedimentation rates during precession cycles (Cenomanian Scaglia Bianca Formation, central Italy)

For much of the pelagic sedimentary record, time control is limited to the resolution of precession cycles (ca 20 kyr): the Milankovitch parameter that forms the most detailed metronome for the Cenozoic and Mesozoic Eras. The influence of precession is often detected in lithological alternations, where the duration represented by individual lithologies is not well constrained. Here the novel technique of extraterrestrial helium abundance (3HeET) is used to investigate the sedimentation dynamics and palaeoceanography within individual precessional cycles. High-resolution 3HeET timescales were produced for four precession cycles from the rhythmically bedded Scaglia Bianca Formation, a sequence of Upper Cretaceous (Cenomanian) deep-marine pelagic limestones from central Italy that are well characterized by cyclostratigraphy. Using 3HeET concentrations as a proxy for sedimentation rate allows instantaneous sedimentation rates and organic-carbon mass accumulation rates to be calculated for each bed within a precession cycle. Eccentricity is known to modulate the amplitude of precession forcing, and precession cycles deposited under eccentricity maxima and minima were selected for comparison. Lithological changes through these chert–(black shale)–limestone cycles are explained using the concept of ‘palaeoenvironmental thresholds’; these timescale calculations indicate that when the amplitude of precessional insolation forcing was greatest (at eccentricity maxima) the palaeoenvironmental system spent longer in the more nutrient-rich environment under which siliceous and organic-rich sediments were deposited, reflecting increased time spent above a ‘threshold’ insolation level. Estimates of primary productivity are relatively elevated for organic-rich beds. An increase in the flux of terrestrial helium (4Heterr) during the deposition of cherts may have been coincident with an increase in terrestrially derived nutrients. The presented results indicate great potential for the use of 3HeET to understand past oceanographic, climatic and sedimentological processes at high temporal resolution

Integrated cyclostratigraphy of the Cau core (SE Spain) - a timescale for climate change during the early Aptian Anoxic Event (OAE 1a) and the late Aptian

We report a cyclostratigraphic study performed on the Cau core (Spain), which is considered an Aptian stratigraphic reference for global correlation and paleoenvironmental reconstruction. This investigation presents an astronomical timescale for the Aptian from Ap2a to Ap14 carbon-isotope stages. Based on the evaluation of a multiproxy dataset from the Cau core, we recalibrate the age and duration of the different biozones, bioevents, chemostratigraphic substages and horizons from the early and late Aptian, with special focus on the Selli Event, providing a new astronomical timescale framework for the Aptian climate. From the recognition of 14 long-eccentricity cycles, we propose a time span of 5.67 Ma for the Ap2a to top of Ap14 C-isotope segments, and ages of 120.82 Ma for the onset of the nannoconid crisis, and 120.20 Ma for the onset of the oceanic anoxic event (OAE) 1a. Calculations yield a duration of 1.47 Ma for the OAE 1a. We estimate the age for the onset of the main Os isotope non-radiogenic phase as 120.08 Ma, 120 ka after the onset of the OAE 1a. The high-resolution data from the Cau core provides further insights in the temporal constraints of the OAE 1a and other Aptian paleoclimatic events. The onset of the main Os-isotope non-radiogenic excursion occurring 120 ka after the onset of the OAE 1a reinforces the theory of rapid destabilization of methane hydrates as the trigger of the anoxic event, that preceded the onset of large-scale volcanism

A lower to middle Eocene astrochronology for the Mentelle Basin (Australia) and its implications for the geologic time scale

The geologic time scale for the Cenozoic Era has been notably improved over the last decades by virtue of integrated stratigraphy, combining high-resolution astrochronologies, biostratigraphy and magnetostratigraphy with high-precision radioisotopic dates. However, the middle Eocene remains a weak link. The so-called “Eocene time scale gap” reflects the scarcity of suitable study sections with clear astronomically-forced variations in carbonate content, primarily because large parts of the oceans were starved of carbonate during the Eocene greenhouse. International Ocean Discovery Program (IODP) Expedition 369 cored a carbonate-rich sedimentary sequence of Eocene age in the Mentelle Basin (Site U1514, offshore southwest Australia). The sequence consists of nannofossil chalk and exhibits rhythmic clay content variability. Here, we show that IODP Site U1514 allows for the extraction of an astronomical signal and the construction of an Eocene astrochronology, using 3-cm resolution X-Ray fluorescence (XRF) core scans. The XRF-derived ratio between calcium and iron content (Ca/Fe) tracks the lithologic variability and serves as the basis for our U1514 astrochronology. We present a 16 million-year-long (40-56 Ma) nearly continuous history of Eocene sedimentation with variations paced by eccentricity and obliquity. We supplement the high-resolution XRF data with low-resolution bulk carbon and oxygen isotopes, recording the long-term cooling trend from the Paleocene-Eocene Thermal Maximum (PETM – ca. 56 Ma) into the middle Eocene (ca. 40 Ma). Our early Eocene astrochronology corroborates existing chronologies based on deep-sea sites and Italian land sections. For the middle Eocene, the sedimentological record at U1514 provides a single-site geochemical backbone and thus offers a further step towards a fully integrated Cenozoic geologic time scale at orbital resolution

Заява Спілки Археологів України щодо проекту Закону України “Про відродження унікального Символу православ’я — церкви Богородиці (Десятинної) в місті Києві” (№ 9196)

The Milankovitch theory of climate change is widely accepted, but the registration of the climate changes in the stratigraphic record and their use in building high-resolution astronomically tuned timescales has been disputed due to the complex and fragmentary nature of the stratigraphic record. However, results of time series analysis and consistency with independent magnetobiostratigraphic and/or radio-isotopic age models show that Milankovitch cycles are recorded not only in deep marine and lacustrine successions, but also in ice cores and speleothems, and in eolian and fluvial successions. Integrated stratigraphic studies further provide evidence for continuous sedimentation at Milankovitch time scales (10^4 years up to 10^6 years). This combined approach also shows that strict application of statistical confidence limits in spectral analysis to verify astronomical forcing in climate proxy records is not fully justified and may lead to false negatives. This is in contrast to recent claims that failure to apply strict statistical standards can lead to false positives in the search for periodic signals. Finally, and contrary to the argument that changes in insolation are too small to effect significant climate change, seasonal insolation variations resulting from orbital extremes can be significant (20% and more) and, as shown by climate modelling, generate large climate changes that can be expected to leave a marked imprint in the stratigraphic record. The tuning of long and continuous cyclic successions now underlies the standard geological time scale for much of the Cenozoic and also for extended intervals of the Mesozoic. Such successions have to be taken into account to fully comprehend the (cyclic) nature of the stratigraphic record

Cyclostratigraphy and eccentricity tuning of the early Oligocene through early Miocene (30.1–17.1 Ma): Cibicides mundulus stable oxygen and carbon isotope records from Walvis Ridge Site 1264

Few astronomically calibrated high-resolution (≤5 kyr) climate records exist that span the Oligocene–Miocene time interval. Notably, available proxy records show responses varying in amplitude at frequencies related to astronomical forcing, and the main pacemakers of global change on astronomical time-scales remain debated. Here we present newly generated X-ray fluorescence core scanning and benthic foraminiferal stable oxygen and carbon isotope records from Ocean Drilling Program Site 1264 (Walvis Ridge, southeastern Atlantic Ocean). Complemented by data from nearby Site 1265, the Site 1264 benthic stable isotope records span a continuous ∼13-Myr interval of the Oligo-Miocene (30.1–17.1 Ma) at high resolution (∼3.0 kyr). Spectral analyses in the stratigraphic depth domain indicate that the largest amplitude variability of all proxy records is associated with periods of ∼3.4 m and ∼0.9 m, which correspond to 405- and ∼110-kyr eccentricity, using a magnetobiostratigraphic age model. Maxima in CaCO3 content, δ18O and δ13C are interpreted to coincide with ∼110 kyr eccentricity minima. The strong expression of these cycles in combination with the weakness of the precession- and obliquity-related signals allow construction of an astronomical age model that is solely based on tuning the CaCO3 content to the nominal (La2011_ecc3L) eccentricity solution. Very long-period eccentricity maxima (∼2.4-Myr) are marked by recurrent episodes of high-amplitude ∼110-kyr δ18O cycles at Walvis Ridge, indicating greater sensitivity of the climate/cryosphere system to short eccentricity modulation of climatic precession. In contrast, the responses of the global (high-latitude) climate system, cryosphere, and carbon cycle to the 405-kyr cycle, as expressed in benthic δ18O and especially δ13C signals, are more pronounced during ∼2.4-Myr minima. The relationship between the recurrent episodes of high-amplitude ∼110-kyr δ18O cycles and the ∼1.2-Myr amplitude modulation of obliquity is not consistent through the Oligo-Miocene. Identification of these recurrent episodes at Walvis Ridge, and their pacing by the ∼2.4-Myr eccentricity cycle, revises the current understanding of the main climate events of the Oligo-Miocene

The Cyclostratigraphy Intercomparison Project (CIP): consistency, merits and pitfalls

Cyclostratigraphy is an important tool for understanding astronomical climate forcing and reading geological time in sedimentary sequences, provided that an imprint of insolation variations caused by Earth’s orbital eccentricity, obliquity and/or precession is preserved (Milankovitch forcing). Numerous stratigraphic and paleoclimate studies have applied cyclostratigraphy, but the robustness of the methodology and its dependence on the investigator have not been systematically evaluated. We developed the Cyclostratigraphy Intercomparison Project (CIP) to assess the robustness of cyclostratigraphic methods using an experimental design of three artificial cyclostratigraphic case studies with known input parameters. Each case study is designed to address specific challenges that are relevant to cyclostratigraphy. Case 1 represents an offshore research vessel environment, as only a drill-core photo and the approximate position of a late Miocene stage boundary are available for analysis. In Case 2, the Pleistocene proxy record displays clear nonlinear cyclical patterns and the interpretation is complicated by the presence of a hiatus. Case 3 represents a Late Devonian proxy record with a low signal-to-noise ratio with no specific theoretical astronomical solution available for this age. Each case was analyzed by a test group of 17-20 participants, with varying experience levels, methodological preferences and dedicated analysis time. During the CIP 2018 meeting in Brussels, Belgium, the ensuing analyses and discussion demonstrated that most participants did not arrive at a perfect solution, which may be partly explained by the limited amount of time spent on the exercises (∼4.5 hours per case). However, in all three cases, the median solution of all submitted analyses accurately approached the correct result and several participants obtained the exact correct answers. Interestingly, systematically better performances were obtained for cases that represented the data type and stratigraphic age that were closest to the individual participants’ experience. This experiment demonstrates that cyclostratigraphy is a powerful tool for deciphering time in sedimentary successions and, importantly, that it is a trainable skill. Finally, we emphasize the importance of an integrated stratigraphic approach and provide flexible guidelines on what good practices in cyclostratigraphy should include. Our case studies provide valuable insight into current common practices in cyclostratigraphy, their potential merits and pitfalls. Our work does not provide a quantitative measure of reliability and uncertainty of cyclostratigraphy, but rather constitutes a starting point for further discussions on how to move the maturing field of cyclostratigraphy forward