10,440 research outputs found
^{63}Cu, ^{35}Cl, and ^{1}H NMR in the S=1/2 Kagom\'e Lattice ZnCu_{3}(OH)_{6}Cl_{2}
ZnCu(OH)Cl () is a promising new candidate for an
ideal Kagom\'e Heisenberg antiferromagnet, because there is no magnetic phase
transition down to 50 mK. We investigated its local magnetic and lattice
environments with NMR techniques. We demonstrate that the intrinsic local spin
susceptibility {\it decreases} toward T=0, but that slow freezing of the
lattice near 50 K, presumably associated with OH bonds, contributes to a
large increase of local spin susceptibility and its distribution. Spin dynamics
near T=0 obey a power-law behavior in high magnetic fields.Comment: Phys. Rev. Lett. (in press
Dynamics of a Quantum Reference Frame
We analyze a quantum mechanical gyroscope which is modeled as a large spin
and used as a reference against which to measure the angular momenta of
spin-1/2 particles. These measurements induce a back-action on the reference
which is the central focus of our study. We begin by deriving explicit
expressions for the quantum channel representing the back-action. Then, we
analyze the dynamics incurred by the reference when it is used to sequentially
measure particles drawn from a fixed ensemble. We prove that the reference
thermalizes with the measured particles and find that generically, the thermal
state is reached in time which scales linearly with the size of the reference.
This contrasts a recent conclusion of Bartlett et al. that this takes a
quadratic amount of time when the particles are completely unpolarized. We now
understand their result in terms of a simple physical principle based on
symmetries and conservation laws. Finally, we initiate the study of the
non-equilibrium dynamics of the reference. Here we find that a reference in a
coherent state will essentially remain in one when measuring polarized
particles, while rotating itself to ultimately align with the polarization of
the particles
MACiE: a database of enzyme reaction mechanisms.
SUMMARY: MACiE (mechanism, annotation and classification in enzymes) is a publicly available web-based database, held in CMLReact (an XML application), that aims to help our understanding of the evolution of enzyme catalytic mechanisms and also to create a classification system which reflects the actual chemical mechanism (catalytic steps) of an enzyme reaction, not only the overall reaction. AVAILABILITY: http://www-mitchell.ch.cam.ac.uk/macie/.EPSRC (G.L.H. and J.B.O.M.), the BBSRC (G.J.B. and J.M.T.—CASE studentship in association with Roche Products Ltd; N.M.O.B. and J.B.O.M.—grant BB/C51320X/1), the Chilean Government’s Ministerio de Planificacio´n y Cooperacio´n and
Cambridge Overseas Trust (D.E.A.) for funding and Unilever for supporting the Centre for Molecular Science Informatics.application note restricted to 2 printed pages web site: http://www-mitchell.ch.cam.ac.uk/macie
Recommendations for HER2 testing in the UK
Determining the HER2 status of breast carcinomas is a prerequisite for the use of the monoclonal antibody trastuzumab (Herceptin(R)), which has recently been licensed for the treatment of metastatic disease. This necessitates a test based on archival material. The preferred analyses are immunohistochemistry with fluorescent in situ hybridisation (FISH) as a follow up test for ambiguous results. Guidelines have been developed for standardised, well controlled procedures for the provision of reliable results. A group of three reference laboratories has been established to provide advice, quality assurance, and materials, where needed
Fractionation effects in phase equilibria of polydisperse hard sphere colloids
The equilibrium phase behaviour of hard spheres with size polydispersity is
studied theoretically. We solve numerically the exact phase equilibrium
equations that result from accurate free energy expressions for the fluid and
solid phases, while accounting fully for size fractionation between coexisting
phases. Fluids up to the largest polydispersities that we can study (around
14%) can phase separate by splitting off a solid with a much narrower size
distribution. This shows that experimentally observed terminal polydispersities
above which phase separation no longer occurs must be due to non-equilibrium
effects. We find no evidence of re-entrant melting; instead, sufficiently
compressed solids phase separate into two or more solid phases. Under
appropriate conditions, coexistence of multiple solids with a fluid phase is
also predicted. The solids have smaller polydispersities than the parent phase
as expected, while the reverse is true for the fluid phase, which contains
predominantly smaller particles but also residual amounts of the larger ones.
The properties of the coexisting phases are studied in detail; mean diameter,
polydispersity and volume fraction of the phases all reveal marked
fractionation. We also propose a method for constructing quantities that
optimally distinguish between the coexisting phases, using Principal Component
Analysis in the space of density distributions. We conclude by comparing our
predictions to perturbative theories for near-monodisperse systems and to Monte
Carlo simulations at imposed chemical potential distribution, and find
excellent agreement.Comment: 21 pages, 23 figures, 2 table
The finite size effect of galaxies on the cosmic virial theorem and the pairwise peculiar velocity dispersions
We discuss the effect of the finite size of galaxies on estimating
small-scale relative pairwise peculiar velocity dispersions from the cosmic
virial theorem (CVT). Specifically we evaluate the effect by incorporating the
finite core radius in the two-point correlation function of mass, i.e.
and the effective gravitational force
softening on small scales. We analytically obtain the lowest-order
correction term for which is in quantitative agreement with the
full numerical evaluation. With a nonzero and/or the cosmic virial
theorem is no longer limited to the case of . We present accurate
fitting formulae for the CVT predicted pairwise velocity dispersion for the
case of . Compared with the idealistic point-mass approximation
(), the finite size effect can significantly reduce the small-scale
velocity dispersions of galaxies at scales much larger than and .
Even without considering the finite size of galaxies, nonzero values for
are generally expected, for instance, for cold dark matter (CDM) models with a
scale-invariant primordial spectrum. For these CDM models, a reasonable force
softening r_s\le 100 \hikpc would have rather tiny effect. We present the CVT
predictions for the small-scale pairwise velocity dispersion in the CDM models
normalized by the COBE observation. The implication of our results for
confrontation of observations of galaxy pair-wise velocity dispersions and
theoretical predictions of the CVT is also discussed.Comment: 18 pages. LaTeX text and 8 postcript figures. submitted to Ap
Photon counting schemes and performance of non-deterministic nonlinear gates in linear optics
The performance of nondeterministic nonlinear gates in linear optics relies on the photon counting scheme being employed and the efficiencies of the detectors in such schemes. We assess the performance of the nonlinear sign gate, which is a critical component of linear optical quantum computing, for two standard photon counting methods: the double detector array and the visible light photon counter. Our analysis shows that the double detector array is insufficient to provide the photon counting capability for effective nondeterministic nonlinear transformations, and we determine the gate fidelity for both photon counting methods as a function of detector efficiencies
Dynamic Scaling in the Susceptibility of the Spin-1\2 Kagome Lattice Antiferromagnet Herbertsmithite
The spin-1/2 kagome lattice antiferromagnet herbertsmithite,
ZnCu(OH)Cl, is a candidate material for a quantum spin liquid
ground state. We show that the magnetic response of this material displays an
unusual scaling relation in both the bulk ac susceptibility and the low energy
dynamic susceptibility as measured by inelastic neutron scattering. The
quantity with can be expressed as a
universal function of or . This scaling is discussed in
relation to similar behavior seen in systems influenced by disorder or by the
proximity to a quantum critical point.Comment: 5 pages, 3 figures v2: updated to match published version
A new species of planthopper belonging to the genus Oecleus Stål, 1862 (Hemiptera: Fulgoroidea: Cixiidae) from coconut palm (Cocos nucifera L) in Jamaica.
A new species of cixiid planthopper (Hemiptera: Fulgoroidea) in the genus Oecleus Stål, Oecleus mackaspringi sp. n., is described from Spring Garden, Jamaica. This new taxon is associated with coconut palm (Cocos nucifera L.) and was found while surveying palm plots with active cases of lethal yellowing (LY). This is the first report of the genus Oecleus from Jamaica. Sequence data for the COI gene and 18S gene are also provided
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Backpropagation architecture optimization and an application in nuclear power plant diagnostics
This paper presents a Dynamic Node Architecture (DNA) scheme to optimize the architecture of backpropagation Artificial Neural Networks (ANNs). This network scheme is used to develop an ANN based diagnostic adviser capable of identifying the operating status of a nuclear power plant. Specifically, a ``root`` network is trained to diagnose if the plant is in a normal operating condition or not. In the event of an abnormal condition, and other ``classifier`` network is trained to recognize the particular transient taking place. these networks are trained using plant instrumentation data gathered during simulations of the various transients and normal operating conditions at the Iowa Electric Light and Power Company`s Duane Arnold Energy Center (DAEC) operator training simulator
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