Simulation par le modèle AgriFlux du devenir de l'atrazine et du dééthylatrazine dans un sol du Québec sous mais sucré

Les outils mathématiques sont de plus en plus utilisés pour simuler la contamination d'origine agricole des eaux souterraines. Le modèle AgriFlux permet, à l'aide du module PestiFlux, de simuler les processus responsables du devenir des pesticides dans le sol: ruissellement, volatilisation, adsorption/désorption rapide, adsorption/désorption lente, complexation par la matière organique dissoute, biodégradation en sous-produits, hydrolyse, drainage et lessivage. AgriFlux est utilisé pour simuler le devenir de l'atrazine et du dééthylatrazine sur une parcelle expérimentale de la région de Québec (Québec, Canada) cultivée en maïs sucré (Zea mays, L.) traité à l'atrazine. Des prélèvements d'eau interstitielle ont été réalisés (1986-1990) à l'aide de lysimètres avec succion (0,5 et 1,0 m de profondeur) et analysés pour leur contenu en atrazine et dééthylatrazine. De manière générale, AgriFlux reproduit bien l'évolution des concentrations mesurées, dans le temps et dans le profil de sol (r=0,76). Certains pics de concentrations observés sur le terrain ne sont toutefois pas représentés ou sont décalés dans le temps, ce qui pourrait être attribué à une sous-estimation de la variabilité spatiale des paramètres. Le rapport dééthylatrazine/atrazine est relativement bien simulé en 1988 à 0,5 m, mais est moins représentatif pour les autres données, ce qui pourrait être dû à une certaine imprécision dans la simulation de la biodégradation. Une analyse de sensibilité du modèle aux variations de différents paramètres a montré que le paramètre le plus influent dans les conditions testées est la constante de biodégradation. Les résultats obtenus montrent la pertinence d'AgriFlux (PestiFlux) dans la simulation du devenir des pesticides dans le sol et donc des risques de contamination des eaux souterraines en région agricole.Groundwater and surface water contamination by agricultural practices has become an increasingly preoccupying problem. Mathematical models are valuable tools to help prevent this type of pollution from non-point sources. AgriFlux is a mechanistic, stochastic model simulating the fate of agricultural contaminants in the unsaturated zone at the scale of the agricultural field. AgriFlux, through the PestiFlux module, now simulates pesticide transformations in the soil from their application to the field until their leaching with percolating water. The processes represented include volatilization, complexation by the soluble organic matter, instantaneous adsorption and desorption, slow adsorption and desorption to less available sites, biodegradation to by-products and hydrolysis to non-toxic compounds. The pesticide freely dissolved in solution or complexed with soluble organic matter can be mobilized with runoff, drainage and leaching waterAn application of PestiFlux to an experimental field near Quebec City (Quebec, Canada) is presented. The soil is a well-drained loamy sand cropped from 1986 to 1990 with sweet corn (Zea Mays, L.) receiving atrazine treatments (1.6 to 1.8 kg.ha-1 of active ingredient). Interstitial water was sampled using 12 suction lysimeters located at both the 0.5 and 1.0 m depths in the soil. All stations were sampled monthly in 1986 and 1987 and the collected water was analyzed for atrazine alone. In 1988, the sampling (every two weeks) was limited to the lysimeters which had previously shown the highest pesticide concentrations (two lysimeters at 0.5 m and one lysimeter at 1.0 m). The interstitial water was analyzed for atrazine and deethylatrazine. There was no sampling in 1989. In 1990, all stations were sampled on a weekly basis and a composite water sample obtained for each depth was analyzed for both compounds. Most of the pesticide-related parameters required to run PestiFlux were deduced from the literature, with the exception of the biodegradation rate coefficient which was estimated from field monitoring of atrazine. The parameters required to simulate water fluxes and plant uptake were the same as those used in a previous application of AgriFlux to the same experimental field for the simulation of nitrate fluxes (LAROCQUE and BANTON, 1995).Results show that PestiFlux generally represents well the measured atrazine and deethylatrazine concentrations in the interstitial water at 0.5 and 1.0 m. A linear regression using all measured and simulated concentrations indiscriminately gives a correlation coefficient of 0.76 when using the logarithm of concentrations. The temporal evolution of the pesticide concentrations is relatively well simulated, especially on the long term with an adequate representation of the increase in pesticide concentrations in the soil profile at 1.0 m. This increase is probably due to the fallow existing in 1985 which would have favored leaching of adsorbed pesticide below the soil profile, leaving only low residual pesticide concentrations. Over one growing season, the transport of atrazine and deethylatrazine is well represented by the model, although some peak concentrations are delayed or attenuated. This result could be due to an underestimation of the spatial variability of the different parameters. It is possible that the coefficient of variation of 10% adopted may not represent adequately the spatial variation of some parameters. Nevertheless, most measured concentrations of both compounds are within the mean simulated concentrations and included between two standard deviations. For 1988, most of the measured concentrations are located near the upper limit of the envelope curve which is consistent with the fact that the sampled lysimeters were those yielding the highest concentrations. The simulated concentrations show a generally good representation of the relative atrazine and deethylatrazine concentrations. The ratio of the mean deethylatrazine to atrazine concentrations provides a closer look at the adequacy between the simulated concentrations of both compounds. A comparison between the measured and the simulated ratios shows a good adequacy at 0.5 m in 1988 and both over- and under-estimation of the ratio for the other available data. This is probably due to an imprecision in the simulation of biodegradation rates during some periods. All the parameters used in the simulation have an important uncertainty, due to the significant spatial variation of the parameters in the field and to the imprecise knowledge of some pesticide characteristics. In order to identify the parameters which have the most important influence on the results, an analysis of the sensitivity of the cumulated leaching mass of both compounds at 1.0 m to variations of the different input parameters was performed. The results show that the biodegradation rate has the greatest influence on the results. This is probably due to the importance of this process in the simulated situation. This result confirms the importance of an adequate quantification of this parameter and of its spatial variation. PestiFlux offers a comprehensive representation of pesticide transformations in the soil and is easy to use. As a module of AgriFlux, it has the advantage of being integrated into a well-tested and reliable modeling environment. The presented simulation results show that, apart from some limits due to the quantification of some of the parameters, PestiFlux is a useful and comprehensive tool for estimating potential groundwater pollution by pesticides

Simplification rationnelle des outils hydrologiques de gestion : recommandations méthodologiques pour la construction de modèles semi-empiriques à origine mécaniste

Les modèles de simulation hydrologiques sont reconnus comme des outils mathématiques très performants mais généralement d'application difficile, principalement à cause du nombre élevé des paramètres requis. À l'inverse, les outils actuels de gestion sont généralement développés à l'aide d'approches empiriques limitant leur application. De plus, leurs paramètres ne sont pas des grandeurs mesurables et doivent être ajustés pour chaque situation. Une approche est proposée pour le développement d'outils semi empiriques de gestion. Elle consiste à simuler un grand nombre de scénarios en utilisant un modèle complexe de simulation puis à rationaliser l'information obtenue pour développer un nouveau modèle semi empirique. L'exemple illustrant cette approche concerne l'évaluation des flux d'eau ruisselée à la surface des champs, lessivée vers la nappe souterraine et drainée par les drains agricoles spécifiquement pour le contexte du Québec. À partir des résultats de simulation de 4500 scénarios, une simplification.rationalisation a permis de réduire à 120 le nombre de scénarios de référence à l'aide desquels peuvent être évalués tous les scénarios possibles par de simples interpolations linéaires. Une application de l'algorithme résultant sur un site du Québec a montré la bonne concordance entre les résultats calculés et mesurés. À la fois l'ordre de grandeur du ruissellement et du drainage et leur grandeur relative sont bien évalués.Considering the complexity of the water cycle in soil systems, models are used more than ever in parallel with field investigations to assist in the decision making process (KHAKURAL et ROBERT, 1993). Most available models are either too complicated (many non-measurable parameters) or too simple (empirical or site-specific) to be used as management tools. Such tools should conform to known theory and should be structured to enable efficient analysis of field situations with minimal requirements for parameters (CARSEL et al 1984). However, if the mechanistic models are very performing tools with regards to their representation of the processes and for the accuracy and reliability of their results, they are criticized for their complexity and for the large number of parameters they require. For this reason, their potential application as management tools cannot be recommended especially in preliminary investigations when the methodology has to be straight forward and rapidly implemented. On the other hand, existing management tools are often developed using an empirical approach for a specific context which considerably limits their transferability to different situations. Moreover, their empirical parameters often cannot be measured for the new situations, and must be adjusted for each new application. A new approach conciliating the qualities of both kinds of tools was elaborated for the development of management tools. This approach consists in using mechanistic models for simulating a set of possible situations and in rationalizing the information obtained by simulation through regression analyses or other methods. An example of this methodology is presented in this paper with the development of the hydrological part (runoff, leaching and drainage) of a management tool dedicated to the evaluation of nutrient losses related to manure applications. Developed for the Quebec conditions, 4500 theoretical situations were considered corresponding to ten climates, nine soil textures, 25 crops and two slope values. Independently, agricultural management practices and drainage were taken into account.For the mechanistic simulation of the water budget in the 4500 theoretical situations, the hydrologic module of the mechanistic-stochastic model AgriFlux was used (BANTON et al. 1993b). Because of the important field variability of most parameters, the stochastic AgriFlux model incorporates the variability resulting from field heterogeneity, measurement errors and intrinsic uncertainty related to parameter definition. The soil profile is divided in plot scale homogeneous horizons (or compartments) and a daily time step is used in the calculations. The water budget module in AgriFlux is named HydriFlux and simulates all the water-related processes (precipitations, snowmelt, infiltration, runoff, water uptake by plants, evaporation, percolation and drainage) using characteristic water contents and unsaturated hydraulic conductivity.In the example presented, the simulation results obtained by running HydriFlux have shown that the soil water fluxes (runoff and percolation) vary as linear functions of both the annual rain volume (the most important characteristic of the climate) and the logarithm of the saturated hydraulic conductivity (the most important characteristic of the soil type). A reduction of the number of crops could also be achieved by taking into account the water needs and the water uptake curves of the crops. This rationalization-simplification reduced the number of theoretical simulations to be stored in the management tool to 120 (2 climates x 3 textures x 10 crops x 2 slopes). These represent only 2.7% of the initial situations simulated by the mechanistic HydriFlux model. The different water fluxes are stored in the management tool as tables in which direct interpolations are performed to calculate the fluxes corresponding to all the potential intermediary situations. Such developed management tool presents good qualities at the same time for its calculation speed, for its easy parameterization, for the reliability of its evaluation (through the evaluation of the mechanistic model) and for its high transferability and applicability to various situations. The calculations are rapidly done and their programming can be very easily made by using a spreadsheet software.An application of this evaluation method has been done on an experimental site located in Quebec (ENRIGHT et MADRAMOOTOO, 1994), the only one for which both the runoff and the drainage have been measured during many years (1989 to 1991, April to December). The application on two fields (1.84 et 4.63 ha) has shown a good concordance between the calculated and measured results, as well for the magnitude of the fluxes than for the relative importance of these fluxes. Moreover, this application has shown that the variability of the measured values is higher than the calculated ones, attesting of the great influence of the variations in climatic, soil, crop and management conditions on the water budget. However, the good evaluation of the fluxes (for relative and absolute values) confirms the reliability of the proposed approach and of the simplification

Contamination nitratée des eaux souterraines d'un bassin versant agricole hétérogène 2. Évolution des concentrations dans la nappe

L'usage quasi systématique de fertilisants sur de grandes surfaces a conduit la majorité des aquifères superficiels à un grave niveau de contamination par les nitrates. Des essais de gestion environnementale de cette problématique agricole sont conduits à l'échelle du bassin versant afin d'estimer les flux de nitrates percolant vers la nappe. La présente étude reprend les résultats issus de la modélisation d'un bassin versant dans le but d'appréhender l'évolution de la concentration en nitrates dans les eaux de la nappe. L'importance des conditions hydrogéologiques dans les relations entre zones non saturée et saturée a été mise en évidence par la comparaison des concentrations calculées dans la zone non saturée et observées dans la nappe. En règle générale, les concentrations sont très semblables pour les zones proches des limites amont du bassin, et se différencient de plus en plus vers l'aval du système. Une dilution semble se produire entre les flux percolant des différentes zones non saturées et les flux d'eau et de nitrates s'écoulant dans l'aquifère. Afin de tester cette hypothèse, un modèle de dilution basé sur les flux d'eau et de nitrates dans les zones non saturée et saturée est développé. Appliqué sur l'axe d'écoulement principal du système, le modèle de dilution permet de reproduire adéquatement les concentrations observées dans la nappe à partir de celles calculées dans le sol avec une erreur maximale variant de 1 à 22%. Le couplage d'un modèle environnemental pour la zone racinaire du sol avec un modèle de dilution simple peut permettre le calcul des concentrations en nitrates dans la zone saturée. Toutefois, la prise en compte des conditions hydrogéologiques du système est nécessaire à un calcul de dilution efficace basé sur les valeurs des flux de percolation.Pesticides and nitrates represent the main sources of aquifer contamination in agricultural zones. In many regions, nitrate concentration levels reach and exceed the water quality criteria (50 mg NO3/L). The increasing use of mineral fertilizers (which has doubled during the 20 last years) and the intensive exploitation of the aquifers for crop irrigation (1,1 million ha in France) have led to groundwater contamination by nitrates. The dynamics (long-term persistence) and extensiveness (regional contamination) of this contamination make it a sensitive environmental issue. Comprehensive environmental management is needed in order to limit the increase of the concentration levels and to reduce the extent of the contaminated areas. During the last few years, research has been done in the field of watershed management, from laboratory experiments to field investigations. At the same time, numerous simulation models have been developed at different investigation scales. Banton et al. (1993) developed a model specifically devoted to environmental management. Their model, AgriFlux, is based on a mechanistic approach to the processes, using a stochastic method that takes into account the spatial variability of the parameters. AgriFlux calculates the nitrate concentrations as well as the water fluxes in the unsaturated zone. The concentrations in the unsaturated zone (obtained by modeling or measurement) are generally dissimilar to those observed in the saturated zone (i.e. in the aquifer) because the infiltration water is diluted in the aquifer water. This difference indicates that the concentrations in the unsaturated zone cannot be used to accurately evaluate the actual risk of groundwater contamination. Hydrogeological conditions such as the recharge limits, the flow direction and the flow rate should be incorporated into the evaluation. In this paper, the modeling results obtained previously (Dupuy et al., 1997) with AgriFlux for the La Jannerie watershed are used to determine the concentrations in the aquifer and to compare them with the concentrations measured in the observation wells. This watershed (160 ha) is used exclusively for agriculture. The fractured carbonate strata (Superior Oxfordian) constitute a phreatic aquifer with a vertical extension of about 20 m. First, the temporal evolution of the annual mean concentrations in the aquifer is compared with the evolution of the annual precipitation. The results show that the mean concentrations tend to follow precipitation levels. However, the differences observed at different locations in the watershed cannot be explained by these results. The spatial evolution of the concentrations from the upstream to the downstream part of the aquifer was studied in order to explain the concentration distribution in the watershed. On the main flow line, the concentrations observed from 1985 to 1989 show a decrease from the P7 well (upstream) to the P26 well (downstream). This phenomenon can be attributed to two factors. First, denitrification may occur in the aquifer during flow. However, it is recognized in literature that the denitrification rate is usually low and a long period of time is required to obtain a significant decrease in the nitrate level. The observed attenuation cannot be imputed to this factor alone. The second possible cause is related to the dilution of the nitrates in the water contained in the aquifer.In order to test this hypothesis, a dilution model was elaborated using the watershed division as indicated in Dupuy et al. (1997). In each area, the resulting concentration is obtained by diluting the fluxes of water and nitrate leaching in the unsaturated zone in the fluxes of water and nitrates flowing from the upstream area. The concentrations in the aquifer are calculated from upstream areas to downstream areas for the period between 1985 and 1989. The pattern of the concentration curves obtained in this manner agrees with the trend measured in the different wells. The results clearly show a decrease of the concentration in the aquifer water leached from the unsaturated zone. For the downstream area (well P26), the calculated concentrations are higher than the observed ones. This difference could be due to the fact that the lateral fluxes (flow convergence into the median part) are not taken into account and the concentrations may thus be overestimated. However, the mean resulting error (12%) remains low considering the lack of knowledge of the aquifer characteristics. It is therefore possible to accurately estimate the nitrate concentrations in the saturated zone from the concentrations simulated in the unsaturated zone using a simple dilution model. However, this method is only valid for simple hydrogeological conditions

Exportation saisonnière d'herbicides vers les cours d'eau mesurée sur six champs agricoles sous quelques pratiques culturales du maïs (Basses-Terres du St-Laurent)

L'identification de pratiques agricoles qui minimisent les risques de contamination des eaux de surface nécessite d'évaluer l'importance des voies de transfert des herbicides vers les cours d'eau. Le but de cette étude est d'évaluer à l'échelle du champ agricole et pour une saison de culture l'exportation effective de l'atrazine et du métolachlore par ruissellement de surface et par drainage, ceci pour des conditions pédo-climatiques et agronomiques représentatives de la culture intensive du maïs-grain dans les Basses-Terres du St-Laurent (Québec). Pour les deux premiers événements pluviaux d'importance suivant l'application des herbicides, seulement deux des six champs étudiés ont présenté un ruissellement quittant le champ : les concentrations en herbicides ont atteint 1200 mg/L et 2400 mg/L. La charge exportée en herbicides semble inférieure dans le cas du non travail du sol (semis direct), comparativement au labour conventionnel. Les concentrations en herbicides dans l'eau de drainage sont inférieures à 6 mg/L (pour la majorité inférieures à 1-2mg/L) pour quatre champs, alors que deux champs ont présenté des concentrations atteignant 40-60 mg/L. La charge exportée par drainage apparaît être faible dans le cas de l'application d'herbicides en bandes, comparativement à l'application en surface totale. La masse en herbicides exportée par ruissellement (estimée à partir de coefficients de ruissellement probables) serait supérieure à celle par drainage. Une démarche destinée à diminuer les masses en herbicides exportées devrait ainsi viser la principale voie de cette exportation, c'est-à-dire le ruissellement de surface.The use of pesticides in agriculture may result in the degradation of surface water quality. Since agricultural practices affect the transport of pesticides, there is a need to identify practices which minimize the contribution of the different transport paths to the streams, i.e. runoff and drainage. The aim of this study was to evaluate at the field scale and for one growing season the transport of the herbicides atrazine and metolachlor to surface water under soil, climatic and agricultural conditions representative of those encountered for intensive corn cropping in the St-Lawrence Lowlands (Quebec).Six agricultural fields (Figure 1) were studied in 1995. Previous agricultural practices in 1994 and soil texture are summarized in Tables 1 and 2, respectively. Conventional practices (tillage with moldboard plow and application of herbicides over the entire area of the field) and conservation practices (no-till and banded application of herbicides over the seeded row) were studied. Each field was solely and entirely drained by one subsurface drain. The commercial formulation used in 1995 contained a mass of metolachlor two times higher than that for atrazine. Herbicide concentrations in runoff and drainage waters were monitored during the two first important rainfall events that occurred after herbicide application (Table 3). Sampled runoff corresponded to the water reaching a drainage channel or a stream. Drainage water was also collected for 3.5 - 4.5 months following the initial application. A total of 164 water samples was obtained. After sediment removal, metolachlor, atrazine and its dealkylated metabolite deethylatrazine (DEA) were extracted using a liquid-solid extraction procedure and analyzed by gas chromatography.Only two fields produced runoff and the concentrations of parent-compounds (Figures 2 and 3) were high and varied during rainfall events between 60-500 mg/L (Field 2) or 130-2400 mg/L (Field 6). Concentrations found during the first rainfall event were higher than those encountered during the second event. The DEA/atrazine concentration ratio (DAR) was below or near 0.1, indicating runoff of recently applied atrazine (low degradation). These two fields present similar soil texture, pluviometry and sampling periods after herbicide application. Based on runoff coefficients observed for other agricultural fields (1-30%), it was estimated that the mass losses for herbicides (Table 4) would be higher under conventional tillage(Field 6) as compared to no-till (Field 2).Significant transport of herbicides by drainage was observed during the two rainfall events. The losses of herbicides that occurred after these events and during a dry growing season (little or no drainage flow) were low. The drainage losses (concentration or masses) during the two rainfall events for Field 1 (clay) were very low. This was attributed to the low drainage capacity of the soil, to the low rainfall intensities as well as to the important delay between the initial application and the subsequent rainfalls. For silty clay loam to loam soils, the drainage flow increased in the 6-12 h period following the onset of rainfall, as did the herbicide concentrations. Metolachlor concentrations were slightly higher or close to those for atrazine: this was attributed to its possible more rapid decay and to its stronger tendency to adsorb to the soil.During the rainfall events, four fields exhibited herbicide concentrations from drainage less than 6 mg/L (mostly < 1-2 mg/L). Fields 2 and 6 yielded parent-compound concentrations as high as 40-60 mg/L (Figures 4 and 5). The DAR values found for drainage water of Field 2 (0.1-0.5) were higher than those observed from runoff, indicating significant dealkylation of atrazine had occurred during its transport in the unsaturated zone. Field 6 allowed the monitoring of the DAR over the growing season and an inverse relationship was found between the DAR and atrazine concentration (Figure 6). This was attributed to the larger variation in atrazine concentration during a rainfall as compared to that of DEA. A DAR value near 1 was obtained at 1-2 months after application, indicating important degradation of atrazine.The total mass losses of parent-compounds (two rainfall events) were evaluated (Table 5) except for Fields 2 and 4 which present frequent submerged drains. Banded herbicide application (Field 5) results in consistent lower losses of herbicide masses than those obtained for application over the entire surface (e.g. Field 5 compared to Fields3 and 6). It should be noted that the higher export observed for the entire surface application may be partly attributed to a shorter delay between application and rainfalls (Fields 3 and 6) or to a higher rainfall intensity (Field 6).Although runoff reaching surface waters was limited, it was estimated that the total herbicide losses (Table 4) during the two rainfall events were higher than those from drainage (Table 5). In the perspective of reducing the herbicide loads reaching streams, it appears that remedial actions should focus on this main route of transport. Thus, complementary actions such as vegetated buffer strips to intercept crop land runoff may possibly be useful to limit herbicide transfer to streams in intensive agricultural zones

Contamination nitratée des eaux souterraines d'un bassin versant agricole hétérogène: 1. Évaluation des apports à la nappe (modèle Agriflux)

Au cours des dernières décennies, la hausse de la productivité agricole s'est accompagnée d'une forte augmentation des fertilisations azotées qui a entraîné l'augmentation des concentrations en nitrates dans les eaux souterraines. Récemment, les études sur la gestion des pollutions diffuses agricoles ont intégré l'échelle du bassin versant hydrologique. Dans cet article, une approche basée sur un découpage en secteurs pédologiquement et agronomiquement homogènes a été élaborée pour permettre l'utilisation d'un modèle d'évaluation (AgriFlux), et obtenir les flux d'eau et de nitrates sortant de la zone racinaire sur l'ensemble d'un bassin. La modélisation du bassin de La Jannerie a porté sur une période de quatre ans impliquant 19 zones de simulation. L'influence du cycle végétatif des cultures et leur nature sur l'évolution des flux de nitrates a été mise en évidence par des simulations préliminaires, de même que l'influence du type de sol. L'évolution des concentrations moyennes saisonnières en nitrates sortant de la zone racinaire montre que les fertilisations minérales ne sont pas les seules sources importantes de nitrates dans les sols. Les pratiques culturales, comme le retournement des prairies, l'enfouissement des résidus de récoltes ou l'assolement, ont une forte influence sur la dynamique spatiale et temporelle des flux de nitrates percolant vers la nappe.In agricultural regions, groundwater contamination by nitrogen compounds originating from fertilizers is one of the most significant environmental problems. Along with in situ monitoring, simulation models have been developed for non point pollution (nitrates, pesticides) in order to evaluate both the level and the extent of the contamination. Simulation models, originally intended for research purposes in relation to the dynamics of agricultural systems, have been adapted and applied to environmental management in order to quantify water volumes and contaminant masses likely to reach groundwater systems. Recently, mechanistic models such as Agriflux (Banton et al., 1993) have been developed for use in the field. Agriflux is based on a mechanistic approach to the processes and incorporates a stochastic analysis that takes into account the spatial variability of the parameters. lt. calculates nitrate concentrations as well as water fluxes in the unsaturated zone. In the present study, environmental management principles integrating heterogeneity in soils and agricultural practices were applied to an agricultural watershed in Poitou (France). Preliminary simulations were carried out in order to estimate the influence of various parameters on the nitrate and water fluxes. First, a three-year wheat mono-crop was simulated using the same fertilization rate for each year. The calculated nitrate concentrations follow a trend opposite to that of the seasonal growing crop. To estimate the influence of the soil characteristics on the nitrate concentrations, the four types of soil in the watershed were simulated using the same three-year crop rotation. The results show that the soil type directly influences the amount of nitrate leaching. Under different soils types, the evolution of the concentrations over time follows the same pattern, but the concentration levels are significantly different. To quantify the impact of crops on the nitrate concentrations, the main crop rotations were simulated for the same type of soil. This set of simulations underlines the environmental differences between winter and spring crops. lt. also shows the differences induced by the presence of residues. The La Jannerie watershed was divided into homogeneous zones for soil and crop characteristics. During a four-year period, seasonal and annual nitrate concentrations were calculated for each homogeneous zone from the daily water and nitrate fluxes simulated with Agriflux. The results demonstrate the influence of the agricultural practices on the calculated concentrations. Overall, nitrate levels remain quasi-constant during the periods when the crops are active but vary considerably during the winter when the crops are absent or inactive. This winter period corresponds to a peak in nitrate leaching because of the excess rainfall and the absence of nitrogen uptake by the plants. The incorporation of crop residues in the soil in the autumn generates a high production of nitrates during winter due to the mineralization of the organic nitrogen.Two different environmental approaches can be used jointly to evaluate agricultural practices. The first consists of a comparison between the nitrate flux that can reach the saturated area and the fertilizer rate. This approach provides an estimate of the amount of nitrogen lost to the aquifer. Simulations with Agriflux show that the nitrate fluxes are highest during the autumn when plant uptake is non-existent, except in fields with winter crops. The second approach compares the calculated nitrate concentrations that may occur in the aquifer with recognized water quality criteria. lt. is interesting and important to note that, during the simulated period, the calculated concentrations in the leach were often much lower than the water quality criterion (50 mg NO3/L). This result indicates that the fertilization practices applied in the watershed during this period tended to approach the real crop requirements (minimal requirements) and were more environmentally adequate (environmental optimum) than those used previously

Délimitation des périmètres de protection des puits de pompage en zone agricole à l'aide de la simulation mathématique

Un périmètre de protection de puits de pompage est la surface entourant le puits, dans laquelle des mesures sont prises pour empêcher des contaminants de migrer et de contaminer l'eau de ce puits. Dans l'établissement des périmètres de protection, de nombreux facteurs doivent être considérés, et une approche analytique systématique doit être adoptée. Les modèles mathématiques de simulation peuvent être employés en ce sens et sont souvent les seules méthodes capables de déterminer les périmètres de protection quand des critères quantitatifs sont utilisés. Une telle approche a été appliquée, en couplant un modèle de transport de contaminant en zone non saturée avec un modèle de transport en zone saturée. Le modèle en zone non saturée VULPEST évalue les concentrations de pesticide atteignant la nappe. Ces concentrations sont ensuite utilisées comme données d'entrée du modèle en zone saturée. Ce dernier considère les vitesses d'écoulement et l'influence de chaque puits. Les résultats quantitatifs permettent alors la détermination de périmètres de protection spécifiques à chaque contaminant potentiel. Cette application, réalisée sur un important site de culture de la pomme de terre du Québec, e permis de comparer favorablement les concentrations prédites à celles mesurées dans l'eau d'un puits, et de déterminer le périmètre de protection spécifique au pesticide utilisé. Le cas présenté est un exemple des applications possibles et futures d'une telle méthode pour la détermination des périmètres de protection des puits de pompage.A wellhead protection area is the surface and subsurface area surrounding a waterwell through which contaminants are reasonably likely to move toward and reach. In the past, various approaches have been taken to delineate wellhead protection areas : fixed circles or rings around the well; simplified variable shapes based on geo-hydrologic mapping and classification ; zones with prescribed minimum travel times. However, in establishing wellhead protection areas, many factors need to be considered : zone of influence around the well; well recharge area; flow paths; transport velocities; travel times; sources and types of contamination. To determine a site-specific wellhead protection area, a systematic analytic approach must be taken. Mathematical simulation models may be employed and are often the only method capable to determine the wellhead protection area when quantitative criteria are used.Such an approach can be used in agricultural zones, where pesticides are applied, by coupling a solute transport modal for the unsaturated zone with a saturated zone transport model. The (unsaturated zone) VULPEST model is an evaluation tool for the groundwater contamination by pesticides based on the transport modeling. Developed as a management tool, it permits the evaluation of the groundwater vulnerability to pesticides in terme of risk of contamination. It evaluates the concentrations of pesticide that reach the water table, taking into account the spatial variability of hydrodynamic, physical and physicochemical parameters of the soil. The variability of parameters is taken into account in the Monte Carlo approach. This approach consists of carrying out a sufficient number of simulations so that the distribution of values assigned to each parameter, these values being randomly selected from a chosen probability distribution, approximates the given distribution.The concentrations obtained from the VULPEST model are used as input data in the model which simulates the transport and the fate of the contaminant in the saturated zone. This model uses the finite difference technique to simulate flow and solute transport. It considers the flow velocities and the influence of each well. In steady state conditions, the linked transport models in unsaturated and saturated zones may be considered independent. The quantitative results obtained by these means determine the vulnerability level of the well. Finally, they permit the delineation of the wellhead protection area for a specific contaminant, that is a given pesticide.An application was performed to an important potato crop area in Quebec. Few years ago, this site has shown a contamination of the well water by the pesticide aldicarb. The cultivated soil consists of marine and fluvial sand with medium to coarse grain sizes, deposited on a sea clay with a thickness of about 20 m in some places. Potatoes are intensively grown in this region. In the eighties, a contamination by the pesticide aldicarb was noticed in some wells of this region. The granular form of aldicarb is applied during the sowing period (mid-May) at the recommended rate of 2.24 kg/ha. It has a high solubility (6 000 mg/l) and is leached by soil humidity. The aldicarb is transformed by oxidation to sulfoxide then to sulfone during its transit in the unsaturated zone. After a characterization of the soil physical parameters, calculations were run for both the unsaturated and the saturated zones. The depths of the well and the aquifer are 5 m and 3 m respectively. The thickness of the aquifer affected by pumping is about 2 m. The application of the pesticide aldicarb was done during 1982 and 1983.The predictive results obtained by modelling for the pesticide concentrations in the well water were favorably comparerd to the concentrations measured at the site. The concentrations of pesticide in the water reach their peaks 7 weeks after every application. The maximum concentrations reaching the water table were found to be about 0,5 mg/l. This level exceeds largely the water quality criterion of 9 µg/l set by Health and Welfare Canada, and the one of 10 µg/l of the US-EPA. The well concentrations are calculated by taking into account transport in the saturated zone and decay processes. The maximum concentrations obtained are near 24 µg/l for a decay rate of the pesticide in the aquifer of 0,003 d-1. This decay rate is the one corresponding of the hall-lite of 8 months found by other researchers for Florida soils. The analysis of the water well during this period shows concentrations of about 10 µg/l. Moreover, the leaching of the contaminant into the well, and its persistence in the soil and groundwater is still present over 3 years after the last application. Using the water quality criterion of 9 µg/l set by Health and Welfare Canada, calculations have provided the delineation of the wellhead protection area specific to the pesticide aldicarb. The boundary delineation of water well protection area is determined by the numerical technique of reverse path line. The maximum extension of the well protection area obtained by this mean is 110 meters. It corresponds to a peak arrival with a decay of 1.5 years after the application.The case study shows an example of the possible and future applications for such a method for the delineation of the wellhead protection areas. Such an approach permits to council the best use of pesticides with an appropriate groundwater protection scheme, indeed, agricultural managers can safely decide on the pesticide application rate and date, as on the choice between various pesticides, with regard to the groundwater quality protection. Through this way, regulators and scientists can base their decisions for the registration of new pesticides by testing, before their use, their possible impacts on groundwater. Comparisons can be easily doge between water quality criteria and predicted quantifies, and regulatory decisions can be taken in light of these results

Analyse de sensibilité paramétrique d'un modèle simulant le transport de pesticide dans le sol

Afin de protéger l'eau souterraine des pesticides épandus à la surface des sols agricoles, on doit être capable de prédire et d'évaluer a priori les risques de contamination. La modélisation mathématique, qui est basée sur la représentation des processus, s'avère être un outil à privilégier pour une telle prédiction. Cependant, la fiabilité des résultats de ces modèles est fonction de la précision et de la représentativité des différents paramètres d'entrée. A l'aide d'une analyse de sensibilité, il est possible d'évaluer l'impact de la variabilité de ces paramètres sur les résultats de la modélisation. Une étude de sensibilité menée avec le modèle Pesticide Rosit Zone Model (PRZM) a permis d'identifier les paramètres physiques d'entrée dont la variation apporte le plus de changements au niveau des principaux résultats, c'est-à-dire les paramètres d'entrée auxquels le modèle est le plus sensible. L'utilisation du coefficient de sensibilité relatif s'avère être à cet égard un outil de comparaison fort efficace dans le cadre d'une telle étude. Les paramètres d'apport en eau (précipitations) et en pesticide (taux d'application) sont ceux dont les variations provoquent le plus d'impact au niveau des résultais de la simulation. Egalement, les résultats des simulations sont aussi sensibles aux variations de la capacité au champ et de la densité du sol. La température, le point de flétrissement, ta profondeur d'évaporation et la dispersion sont des paramètres auxquels la modélisation est peu sensible.The ever increasing number of cases of groundwater contamination by pesticides has recently given rise to numerous experimental studies on the tale of these compounds within the soil-water system. In parallel with these experimental studies, the quick and intensive development of numerous simulation models bas emphasized the importance of the various factors and processes controlling the transport of pesticides in the unsaturated zone. The calibration and the validation of such deterministic models, which are especially used in groundwater management, requires the evaluation of several parameters related to the nature of the pesticide as well as to the pedologic and hydrogeological conditions of a given site. The reliability of results predicted by those models is mainly a function of the precision and the representativeness in the evaluation of those parameters at a specific site.The aim of this study was to evaluate the sensitivity of a simulation modes of pesticide movement in the unsaturated zone with regards to the variation in soil physical properties. More particularly, a sensitivity analysis was performed in order to determine the importance of the variation in these parameters with respect to simulation results obtained from the Pesticide Root Zone Model (PRZM). The spatial variability of the composition and structure of the soil, which comes from the site pedogenesis, is the main cause of the variability of the soil water distribution and of the soil transient properties. The sensitivity analysis of a model with respect to the variation in these parameters allows the evaluation of the impact of their representativeness on the model output results. Such an analysis thus allows the determination of an acceptable level of precision (or error) for which an increase of precision in the evaluation of a parameter does not anymore correspond to a significant gain in the representativeness of the model results. It also permits the estimation of the impact of a potential variation of a parameter on the prediction of pesticide transport in the unsaturated zone.The deterministic PRZM modal used in this study has been developed by the US-EPA and devoted to pesticide application on agricultural sites. This modal evaluates the pesticide leaching towards groundwater with respect to the type of culture and pesticide used, the climatic conditions, the soil characteristics and some agricultural practices. Output results from the model can he expressed in concentrations or masses of pesticide, in fluxes or cumulated quantities. Simulations were performed using characteristics and data of the Portneuf region (Quebec). This area of potato farming was until recently one of the Quebec most important sites for aldicarb application before the recommendation of its non use. Cultivated surfaces, which are rather homogeneous, consist of medium-size sand. Simulations were performed river a ten year period (1974 to 1984), implying one application of pesticide a1 the seed-time, and a trop for each year.The parameters of water and pesticide inputs (rain and application rates) are those that induce the higher impact on the simulation results. The simulation results were also influenced by the variation of the field capacity and of the soil bulk density. Temperature, wilting point, maximum evaporation depth and dispersion are the input parameters for which the PRZM model is the less sensitive. The simulation results of pesticide transport, which ultimately consist in predicting the groundwater contamination, are very sensitive to the variations of some physical parameters for which the precision and the representativeness in the measured values are thus very important for the reliability of the results. Considering the spatial variability of a site characteristics, the representativeness of these results is very uncertain if a limited number of data is used in order to determine the mean value. A particular attention has to be focused on the parameters that induce the higher sensitivity of the model. Finally, such a sensitivity analysis shows that a stochastic approach in modelling the solute transport through soil can be a good alternative to take into account the variability of parameters encountered in field situations

Hydrodynamic characterization of the Paleocene aquifer in the coastal sedimentary basin of Togo

The intense exploitation of shallow aquifers in the coastal basin of Togo provokes a rapid depletion of these reservoirs. The confined paleocene aquifer represents potential reserves that are yet little exploited. This paper presents the hydrodynamic characterization of this aquifer. Piezometric data established from 80 wells fluctuate between 1.17 and 3.42 m; and demonstrate the effect of pumping on groundwater level with a depression located in South-West of the study area. Major fluctuations higher than 2 m, are observed in some wells located in the North of the basin. These are a result of the recharging of the Paleocene by the shallow aquifer of the Continental terminal in the North of the basin where the two aquifers are in contact.Key words: Water table, aquifer, Paleocene, fluctuations, Togo

Mixed marriages and transnational families in the intercultural context : a case study of African-Spanish couples in Catalonia, Spain

Premi a l'excel·lència investigadora. Àmbit de les Ciències Socials. 2008One of the consequences of international migration and the permanent settlement of immigrants in southern EU countries is the growing number of inter-country marriages and the formation of transnational families. Using both quantitative and qualitative data, this article examines patterns of endogamy and exogamy (i.e. marriage within/outside a particular group or category) among African immigrants in Catalonia, focusing on bi-national Senegalese- and Gambian-Spanish couples. Socio-demographic profiles, transnationality, the dynamics of cultural change or retention, and the formation of transcultural identities are explored. The evidence presented suggests that social-class factors are more important than cultural origins in patterns of endogamy and exogamy, in the dynamics of living together and in the bringing-up of children of mixed unions. Such a conclusion negates culturalists' explanations of endogamy and exogamy while, at the same time, emphasising the role of social actors as active subjects in these processes. I further argue that mixed couples and their offspring deal-to a greater or lesser extent-with multiple localisations and cultural backgrounds (i.e. here and there), rather than experiencing a 'clash between two cultures'. Therefore, it would be a mistake to pretend that multicultural links do not exist and that they cannot be revitalised and functional. The paper starts and ends by addressing the complexities of processes of interculturalism, resisting an interpretation of hybridity and segregation as contradictory or exclusive realities

Steroid receptor coactivator-1 modulates the function of Pomc neurons and energy homeostasis

Hypothalamic neurons expressing the anorectic peptide Pro-opiomelanocortin (Pomc) regulate food intake and body weight. Here, we show that Steroid Receptor Coactivator-1 (SRC-1) interacts with a target of leptin receptor activation, phosphorylated STAT3, to potentiate Pomc transcription. Deletion of SRC-1 in Pomc neurons in mice attenuates their depolarization by leptin, decreases Pomc expression and increases food intake leading to high-fat diet-induced obesity. In humans, fifteen rare heterozygous variants in SRC-1 found in severely obese individuals impair leptin-mediated Pomc reporter activity in cells, whilst four variants found in non-obese controls do not. In a knock-in mouse model of a loss of function human variant (SRC-1L1376P), leptin-induced depolarization of Pomc neurons and Pomc expression are significantly reduced, and food intake and body weight are increased. In summary, we demonstrate that SRC-1 modulates the function of hypothalamic Pomc neurons, and suggest that targeting SRC-1 may represent a useful therapeutic strategy for weight loss.Peer reviewe