83 research outputs found
Brønsted Acid-Catalyzed Straightforward Synthesis of Benzo[b]carbazoles from 2,3-Unsubstituted Indoles
Described is a general and efficient synthesis of valuable benzo[b]carbazoles by Brønsted acid-catalyzed reactions between simple C-2,C-3-unsubstituted indoles and ortho-[α-(hydroxy)benzyl]benzaldehyde acetals. Highly selective migration processes are involved as key steps in the overall cascade sequence that involves the one-pot formation of two new bonds and a cycle in a regioselective fashion.Ministerio de Economia y Competitividad (MINECO) and FEDER (CTQ2010-15358) for financial suuport. P. G.-G. and M.A.F.-R. thank MINECO for "Juan de la Cierva" and "Ramon y Cajal" contractsThis is the peer reviewed version of the following article: Suárez, A., GarcĂa-GarcĂa, P., Fernández-RodrĂguez, M. A. and Sanz, R. (2014), Brønsted Acid-Catalyzed Straightforward Synthesis of Benzo[b]carbazoles from 2,3-Unsubstituted Indoles. Adv. Synth. Catal., 356: 374–382. doi: 10.1002/adsc.201300868, which has been published in final form at 10.1002/adsc.201300868. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Self-Archiving
Synthesis and characterisation of novel nopyl-derived phosphonium ionic liquids
A series of novel nopyl-derived chiral phosphonium ionic liquids have been successfully synthesised and characterised. Analysis of each novel ionic liquid was conducted in order to confirm structure, purity and thermal stability
Chemoenzymatic preparation of optically active 3-(1H-imidazol-1-yl)cyclohexanol-based ionic liquids: application in organocatalysis and toxicity studies
ChemInform Abstract: Phosphorus-Containing Radicals. Part 6. Novel 1-Phosphonyl Radicals Derived from 1-Mono- and 1,1-Diheterosubstituted 2- Oxoalkylphosphonates as Useful Phosphoroorganic Intermediates in Organic Synthesis.
ChemInform Abstract: Phosphorus Containing Radicals. Part 9. A Novel Synthesis of Diethyl 3-Iodoalkyl- and 3-Iodoalkenylphosphonates via the Iodine Atom Transfer Addition Reaction.
ChemInform Abstract: A Novel Application of Ammonium Formate/Palladium on Carbon for Selective Reduction of the Heterocyclic Ring in Quinolines and Isoquinolines.
ChemInform Abstract: Phosphorus-Containing Radicals. Part 1. Free Radical Reaction of . alpha.-Haloalkylphosphonates with Alkenes and Alkynes: A New Approach to Modified Phosphonates.
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