Low-ionization iron-rich Broad Absorption-Line Quasar SDSS J1652+2650: Physical conditions in the ejected gas from excited FeII and metastable HeI

We present high-resolution VLT/UVES spectroscopy and a detailed analysis of the unique Broad Absorption-Line system towards the quasar SDSS J165252.67+265001.96. This system exhibits low-ionization metal absorption lines from the ground states and excited energy levels of Fe II and Mn II, and the meta-stable 2^3S excited state of He I. The extended kinematics of the absorber encompasses three main clumps with velocity offsets of -5680, -4550, and -1770 km s$^{-1}$ from the quasar emission redshift, $z=0.3509\pm0.0003$, derived from [O II] emission. Each clump shows moderate partial covering of the background continuum source, $C_f \approx [0.53; 0.24; 0.81]$. We discuss the excitation mechanisms at play in the gas, which we use to constrain the distance of the clouds from the Active Galactic Nucleus (AGN) as well as the density, temperature, and typical sizes of the clouds. The number density is found to be $n_{\rm H} \sim 10^4\rm cm^{-3}$ and the temperature $T_e \sim 10^4\rm\,K$, with longitudinal cloudlet sizes of $\gtrsim0.01$ pc. Cloudy photo-ionization modelling of He I$^{*}$, which is also produced at the interface between the neutral and ionized phases, assuming the number densities derived from Fe II, constrains the ionization parameter to be $\log U \sim -3$. This corresponds to distances of a few 100 pc from the AGN. We discuss these results in the more general context of associated absorption-line systems and propose a connection between FeLoBALs and the recently-identified molecular-rich intrinsic absorbers. Studies of significant samples of FeLoBALs, even though rare per se, will soon be possible thanks to large dedicated surveys paired with high-resolution spectroscopic follow-ups.Comment: Accepted for publication in MNRAS, 27 pages, 21 Figure

Discovery of a Perseus-like cloud in the early Universe: HI-to-H2 transition, carbon monoxide and small dust grains at zabs=2.53 towards the quasar J0000+0048

We present the discovery of a molecular cloud at zabs=2.5255 along the line of sight to the quasar J0000+0048. We perform a detailed analysis of the absorption lines from ionic, neutral atomic and molecular species in different excitation levels, as well as the broad-band dust extinction. We find that the absorber classifies as a Damped Lyman-alpha system (DLA) with logN(HI)(cm^-2)=20.8+/-0.1. The DLA has super-Solar metallicity with a depletion pattern typical of cold gas and an overall molecular fraction ~50%. This is the highest f-value observed to date in a high-z intervening system. Most of the molecular hydrogen arises from a clearly identified narrow (b~0.7 km/s), cold component in which CO molecules are also found, with logN(CO)~15. We study the chemical and physical conditions in the cold gas. We find that the line of sight probes the gas deep after the HI-to-H2 transition in a ~4-5 pc-size cloud with volumic density nH~80 cm^-3 and temperature of only 50 K. Our model suggests that the presence of small dust grains (down to about 0.001 {\mu}m) and high cosmic ray ionisation rate (zeta_H a few times 10^-15 s^-1) are needed to explain the observed atomic and molecular abundances. The presence of small grains is also in agreement with the observed steep extinction curve that also features a 2175 A bump. The properties of this cloud are very similar to what is seen in diffuse molecular regions of the nearby Perseus complex. The high excitation temperature of CO rotational levels towards J0000+0048 betrays however the higher temperature of the cosmic microwave background. Using the derived physical conditions, we correct for a small contribution (0.3 K) of collisional excitation and obtain TCMB(z = 2.53)~9.6 K, in perfect agreement with the predicted adiabatic cooling of the Universe. [abridged]Comment: 24 pages, 24 figures, accepted for publication in A&

Interfacial behavior of lipid nanocapsules spread on model membrane monolayers

The lipid nanocapsules (LNCs) spread at the air–water interface (A/W) undergo destabilization and disaggregation leading to formation of a triglyceride (TG) surface film. The kinetics of reorganization and formation of TG surface film were followed by measuring either the change of surface pressure at constant area or the surface area at constant surface pressure. From the obtained experimental data were determined the effectiveness of TG spreading and the rate of LNC disaggregation at A/W interface covered with preformed model membrane monolayers of DPPC, Curosurf®, and mucus. Partial LNC stabilization due to their interaction with the model membrane monolayers was observed and characterized by atomic force microscopy (AFM). The obtained results demonstrated that the LNCs spread on mucus surface layer, which models the epithelial surface were more stable than if they were spread either on DPPC or Curosurf® surface layers, which emulate the alveolar surface

Quantum mechanical modeling of excited electronic states and their relationship to cathodoluminescence of BaZrO3

First-principles calculations set the comprehension over performance of novel cathodoluminescence (CL) properties of BaZrO3 prepared through microwave-assisted hydrothermal. Ground (singlet, s*) and excited (singlet s** and triplet t** ) electronic states were built from zirconium displacement of 0.2 Å in {001} direction. Each ground and excited states were characterized by the correlation of their corresponding geometry with electronic structures and Raman vibrational frequencies which were also identified experimentally. A kind of optical polarization switching was identified by the redistribution of 4dz2 and 4dxz (Zr) orbitals and 2pz O orbital. As a consequence, asymmetric bending and stretching modes theoretically obtained reveal a direct dependence with their polyhedral intracluster and/or extracluster ZrO6 distortions with electronic structure. Then, CL of the as-synthesized BaZrO3 can be interpreted as a result of stable triplet excited states, which are able to trap electrons, delaying the emission process due to spin multiplicity changes

HD/H2 Molecular Clouds in the Early Universe: The Problem of Primordial Deuterium

We have detected new HD absorption systems at high redshifts, z_abs=2.626 and z_abs=1.777, identified in the spectra of the quasars J0812+3208 and Q1331+170, respectively. Each of these systems consists of two subsystems. The HD column densities have been determined: log(N(HD),A)=15.70+/-0.07 for z_A=2.626443(2) and log(N(HD),B)=12.98+/-0.22 for z_B=2.626276(2) in the spectrum of J0812+3208 and log(N(HD),C)=14.83+/-0.15 for z_C=1.77637(2) and log(N(HD),D)=14.61+/-0.20 for z_D=1.77670(3) in the spectrum of Q1331+170. The measured HD/H2 ratio for three of these subsystems has been found to be considerably higher than its values typical of clouds in our Galaxy. We discuss the problem of determining the primordial deuterium abundance, which is most sensitive to the baryon density of the Universe \Omega_{b}. Using a well-known model for the chemistry of a molecular cloud, we have estimated the isotopic ratio D/H=HD/2H_2=(2.97+/-0.55)x10^{-5} and the corresponding baryon density \Omega_{b}h^2=0.0205^{+0.0025}_{-0.0020}. This value is in good agreement with \Omega_{b}h^2=0.0226^{+0.0006}_{-0.0006} obtained by analyzing the cosmic microwave background radiation anisotropy. However, in high-redshift clouds, under conditions of low metallicity and low dust content, hydrogen may be incompletely molecularized even in the case of self-shielding. In this situation, the HD/2H_2 ratio may not correspond to the actual D/H isotopic ratio. We have estimated the cloud molecularization dynamics and the influence of cosmological evolutionary effects on it

PKS 1413+135: OH and H i at z = 0.247 with MeerKAT

The BL Lac object PKS 1413+135 was observed by the Large Survey Project MeerKAT Absorption Line Survey (MALS) in the L-band, at 1139 MHz and 12931379 MHz, targeting the HI and OH lines in absorption at z=0.24671. The radio continuum might come from the nucleus of the absorbing galaxy or from a background object at redshift lower than 0.5, as suggested by the absence of gravitational images. The HI absorption line is detected at a high signal-To-noise ratio, with a narrow central component, and with a red wing, confirming previous results. The OH 1720 MHz line is clearly detected in (maser) emission, peaking at a velocity shifted by-10 to-15 km s-1 with respect to the HI peak. The 1612 MHz line is lost due to radio frequency interference. The OH 1667 MHz main line is tentatively detected in absorption, but not the 1665 MHz line. Over 30 years a high variability is observed in optical depths, due to the rapid changes of the line of sight caused by the superluminal motions of the radio knots. The HI line has varied by 20% in depth, while the OH-1720 MHz depth has varied by a factor of ∼3. The position of the central velocity and the widths also varied. The absorbing galaxy is an early-Type spiral (maybe S0) seen edge-on, with a prominent dust lane, covering the whole disk. Given the measured mass concentration and the radio continuum size at centimeter wavelengths (100 mas corresponding to 400 pc at z=0.25), the width of the absorption lines from the nuclear regions are expected up to 250 km s-1. The narrowness of the observed lines (< 15 km s-1) suggests that the absorption comes from an outer gas ring, as frequently observed in S0 galaxies. The millimetric lines are even narrower (< 1 km s-1), which corresponds to the continuum size restricted to the core. The radio core is covered by individual 1 pc molecular clouds, whose column density is a few 1022 cm-2, which is compatible with the gas screen detected in X-rays