109 research outputs found
Stigmatising the Poor Without Negative Images: Images of Extreme Poverty and the Formation of Welfare Attitudes.
In the past two decades, many studies have warned of the role the popular media might play in the stigmatisation of the poor. Media reports about poverty often include references to antisocial behaviour, which make the principle of deservingness particularly conspicuous and could also strengthen the effects of ethnic stereotypes. We argue, however, that it could be misleading to place all the blame for stigmatisation on direct references to 'undeserving' behaviour. Media images of extreme distress themselves could have a selective stigmatising effect. Thus, even benevolent portrayal of the poor could erode sympathy. This paper presents the results of a video-vignette experiment on a sample of Hungarian students. The subjects watched one of four versions of a video interview with a poor person (none of them contained any references to antisocial behaviour) and then expressed their attitudes towards welfare payments. We found that support for welfare was higher where a version highlighted signs of extreme distress. But this was only the case if there were no mention of ethnic minorities. If the video report emphasized that Roma (Gypsies), the largest disadvantaged minority group in Hungary, lived in the neighbourhood, signs of their extreme hardship lowered the support for welfare payments
SYNTHESIS AND APPLICATION OF CROWN ETHERS
Mono- and bis-benzo-15-crown-5-ether derivatives have been synthesized and determined
their potentiometric K+ selectivity factors. Of bis-crown ether urethanes highly selective Iigands
were found some of which was used as active ingredient in potassium selective membrane
electrode.
Sugar based crown ethers, aza-crowns and cryptands were also prepared and applied as
chiral catalyst in enantioselective reactions
On Dipole Moments and Hydrogen Bond Identification in Water Clusters
It is demonstrated that the localized orbitals calculated for
a water cluster have small delocalization tails along the
hydrogen bonds, that are crucial in determining the resulting
dipole moments of the system. (By cutting them, one gets much
smaller dipole moments for the individual monomersclose to
the values one obtains by using a Bader-type analysis.) This
means that the individual water monomers can be delimited
only in a quite fuzzy manner, and the electronic charge
density in a given point cannot be assigned completely to
that or another molecule. Thus, one arrives to the brink of
breaking the concept of a water cluster consisting of
individual molecules. The analysis of the tails of the
localized orbitals can also be
used to identify the pairs of water molecules actually
forming hydrogen bonds
Review on the start-up experiences of continuous fermentative hydrogen producing bioreactors
a b s t r a c t The start-up of continuous biohydrogen fermentations is a complex procedure and a key to acceptable hydrogen production performance and successful long-term operation. In this review article, the experiences gained and lessons learned from relevant literature studies dealing with various aspects of H 2 producing bioreactor start-up are comprehensively surveyed. Firstly, the importance of H 2 -forming biosystem start-up including its main steps is outlined. Afterwards, the role of main influencing factors and methods (e.g. strain selection, seed pretreatment and inocula stimulation, switch-over time, bioreactor design, operating conditions) in avoiding the deterioration of starting a reactor is analyzed and presented in detail. Finally, the so far suggested applicable start-up strategies and the corresponding findings are critically discussed pointing out the advantages and disadvantages of each strategy
Potassium acetate solution as a promising option to osmotic distillation for sour cherry (Prunus cerasus L.) juice concentration
Different osmotic agents (OA), such as potassium acetate (CH3COOK), potassium carbonate (K2CO3) and ammonium nitrate (NH4NO3), have been examined as alternatives to the traditionally used calcium chloride (CaCl2) for osmotic distillation concentrating of clarified and pre-concentrated sour cherry (Prunus cerasus L.) juice. Comparison of the process performances based on the permeate fluxes has been carried out. Regarding the permeate flux results, simplified estimation of the overall mass transfer coefficient of the most effective osmotic agent and the reference (CaCl2) solution has been also performed. Furthermore, analytical methods such as total antioxidant activity (TAA) and total polyphenolic content (TPC) using spectrophotometric assays have been also carried out to evaluate the effect of the osmotic distillation on the valuable compounds content of concentrated sour cherry juice. CH3COOK was found to be the most effective, resulted more than 25% higher permeate flux during the sour cherry juice concentration. K2CO3 and NH4NO3 were less effective. The simplified mass transfer estimation showed that the CH3COOK is more effective only at near saturated concentrations compared to the CaCl2. Regarding the TAA and TPC contents, a significant loss was found in case of all OAs during the concentration procedures
The Structure of Hyperalkaline Aqueous Solutions Containing High Concentrations of Gallium - a Solution X-ray Diffraction and Computational Study
Highly concentrated alkaline NaOH/Ga(OH)3 solutions with 1.18 M Ga(III)T 2.32 M and 2.4 M NaOHT 4.9 M (where the subscript T denotes total or analytical concentrations) have been prepared and investigated by solution X-ray diffraction and also by ab initio quantum chemical calculations. The data obtained are consistent with the presence of only one predominant Ga(III)-bearing species in these solutions, that is the tetrahedral hydroxo complex Ga(OH)4–. This finding is in stark contrast to that found for Al(III)-containing solutions of similar concentrations, in which, besides the monomeric complex, an oxo-bridged dimer was also found to form. From the solution X-ray diffraction measurements, the formation of the dimeric (OH)3Ga–O–Ga(OH)32– could not unambiguously be shown, however, from the comparison of experimental IR, Raman and 71Ga NMR spectra with calculated ones, its formation can be safely excluded. Moreover, higher mononuclear stepwise hydroxo complexes, like Ga(OH)63–, that have been claimed to exist by others in the literature, was not possible to experimentally detect in these solutions with any of the spectroscopic techniques used
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