Vector magnetic hysteresis of hard superconductors

Critical state problems which incorporate more than one component for the magnetization vector of hard superconductors are investigated. The theory is based on the minimization of a cost functional ${\cal C}[\vec{H}(\vec{x})]$ which weighs the changes of the magnetic field vector within the sample. We show that Bean's simplest prescription of choosing the correct sign for the critical current density $J_c$ in one dimensional problems is just a particular case of finding the components of the vector $\vec{J}_c$. $\vec{J}_c$ is determined by minimizing ${\cal C}$ under the constraint $\vec{J}\in\Delta (\vec{H},\vec{x})$, with $\Delta$ a bounded set. Upon the selection of different sets $\Delta$ we discuss existing crossed field measurements and predict new observable features. It is shown that a complex behavior in the magnetization curves may be controlled by a single external parameter, i.e.: the maximum value of the applied magnetic field $H_m$.Comment: 10 pages, 9 figures, accepted in Phys. Rev.

Critical state theory for nonparallel flux line lattices in type-II superconductors

Coarse-grained flux density profiles in type-II superconductors with non-parallel vortex configurations are obtained by a proposed phenomenological least action principle. We introduce a functional $C[H(x)]$, which is minimized under a constraint of the kind $J$ belongs to $Delta$ for the current density vector, where $Delta$ is a bounded set. This generalizes the concept of critical current density introduced by C. P. Bean for parallel vortex configurations. In particular, we choose the isotropic case ($Delta$ is a circle), for which the field penetration profiles $H(x,t)$ are derived when a changing external excitation is applied. Faraday's law, and the principle of minimum entropy production rate for stationary thermodynamic processes dictate the evolution of the system. Calculations based on the model can reproduce the physical phenomena of flux transport and consumption, and the striking effect of magnetization collapse in crossed field measurements.Comment: The compiled TeX document length is 10 pages. Two figures (one page each) are also included The paper is accepted for publication in Phys. Rev. Let

Las poéticas explícitas como género

La abundancia de textos ensayísticos donde los autores literarios describen aspectos de la literatura relacionados con el proceso de creación, la función de la literatura o la imagen del poeta contrasta con la escasez de estudios teóricos sobre el género. Este trabajo indaga en los orígenes y características de estas poéticas explícitas para plantear los rasgos imprescindibles que permiten reconocerlas como un tipo de texto particular.Despite the abundance of texts where writers explain the creation process, the function of literature or the image of the poet, there is a significant lack of studies on the subject. This paper goes into detailed analysis of explicit poetics, from his origin and main characteristics to the essential features that let us recognize explicit poetics as a genre

A variational approach to the macroscopic electrodynamics of anisotropic hard superconductors

We consider the Bean's critical state model for anisotropic superconductors. A variational problem solved by the quasi--static evolution of the internal magnetic field is obtained as the $\Gamma$-limit of functionals arising from the Maxwell's equations combined with a power law for the dissipation. Moreover, the quasi--static approximation of the internal electric field is recovered, using a first order necessary condition. If the sample is a long cylinder subjected to an axial uniform external field, the macroscopic electrodynamics is explicitly determined.Comment: 24 pages, 15 figure

Glyceraldehyde-3-phosphate dehydrogenase is posttranslationally modified by NAD+ in enterohemorrhagic Escherichia coli

Comunicaciones a congreso

Corrosion activity and solubility in polar oils of three bis(trifluoromethylsulfonyl) imide/bis(trifluoromethylsulfonyl) amide ([NTF2]) anion-based ionic liquids.

The corrosion behaviour and solubility of three bis(trifluoromethylsulfonyl)amide1 ([NTf2]) anion-based ionic liquids: 1-dodecyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ([C12MIM][NTf2]), tributylmethylammonium bis(trifluoromethylsulfonyl)amide ([N4441][NTf2]), and methyltrioctylammonium bis(trifluoromethylsulfonyl)amide ([N1888][NTf2]), as a component in a mixture with different base oils were analysed. Six polar oils suitable for use in lubrication were utilized as base oil. Solubility tests were performed by using turbidimetry, and corrosion was checked at 4 v/v% by examining the roughness and chemical composition of the surface after 21 days. The results showed that long carbon chains in the cation improve the solubility greatly in diesters and slightly in polyolesters. Corrosion was not detected at this concentration

Modelo de aprovechamiento de aguas lluvias en zonas de pobreza extrema

Las ventajas de captar agua lluvia en un entorno natural son: agua extremadamente limpia en comparación con otras fuentes de agua dulce disponibles, recurso esencialmente gratuito e independiente de empresas suministradoras habituales y que requiere de infraestructura sencilla para su captación, almacenamiento y distribución. El sistema de captación del agua lluvia permite almacenarla y posteriormente someter a tratamiento la que se utilizará para el consumo humano. A este sistema se le denomina CATDALL, que fue el prototipo resultado final del desarrollo del proyecto, gracias al apoyo del Fondo para la Investigación en Educación Superior (FIES) y la Universidad Tecnológica de El Salvador (UTEC). El prototipo puede ser replicable en otros centros escolares, que presenten escasez de agua bajo las circunstancias que fueren o como simple alternativa de ahorro aprovechando un recurso natural que es gratuito.Investigación desarrollada bajo el convenio FIES-UTEC, 2008-2009Universidad Tecnológica de El Salvado

General critical states in type-II superconductors

The magnetic flux dynamics of type-II superconductors within the critical state regime is posed in a generalized framework, by using a variational theory supported by well established physical principles. The equivalence between the variational statement and more conventional treatments, based on the solution of the differential Maxwell equations together with appropriate conductivity laws is shown. Advantages of the variational method are emphasized, focusing on its numerical performance, that allows to explore new physical scenarios. In particular, we present the extension of the so-called double critical state model to three dimensional configurations in which only flux transport (T-states), cutting (C-states) or both mechanisms (CT-states) occur. The theory is applied to several problems. First, we show the features of the transition from T to CT states. Second, we give a generalized expression for the flux cutting threshold in 3-D and show its relevance in the slab geometry. In addition, several models that allow to treat flux depinning and cutting mechanisms are compared. Finally, the longitudinal transport problem (current is applied parallel to the external magnetic field) is analyzed both under T and CT conditions. The complex interaction between shielding and transport is solved.Comment: 21 figures, submitted for publicatio

Cyclopalladated Benzophenone Imines: Synthesis, Antitumor Activity, Cell Accumulation, DNA Interaction, and Cathepsin B Inhibition.

The synthesis of the endo five-membered cyclo-ortho-palladated benzophenone imines [Pd{C6H4(Ph)C═NR}]2(μ-X)2 [1 (X = OAc), 2 (X = Cl), a (R = phenyl), b (R = 1-naphthyl), c (R = benzyl), d (R = α-methylbenzyl)], and trans-N,P-[Pd{C6H4(Ph)C═NR}X(PPh3)] [3 (X = OAc), 4 (X = Cl), a (R = phenyl), b (R = 1-naphthyl), c (R = benzyl), d (R = α-methylbenzyl)] and the X-ray molecular structure of 1a, 1c, 1d, 4a, 4b, and 4c are reported. The antitumor activity, DNA interaction, and cathepsin B inhibition of palladium compounds a-d were studied and compared with those previously reported for palladium compounds e with R = H and compound 4f analogous to 4e but with a platinum(II) center. The IC50 values against a panel of human cancer cell lines allowed the establishment of a qualitative relationship between their structure and antitumor activity. Compounds 3e, 4e, and 4f were the most active ones in relation to their in vitro anticancer activity. Compounds 3e and 4e were about 4 times more active than cisplatin against the MDA-MB-231 and MCF-7 breast human cancer lines, and compound 4f was about 4 times more active than cisplatin against the cisplatin-resistant HCT-116 colon human cancer cell line. In addition, compound 3e was 3 times less cytotoxic than cisplatin toward the quiescent HUVEC cells. Accumulation of palladium compounds e and b in the MDA-MB-231 cell line was considerably greater than that of cisplatin in the same cell line, but palladium compounds b were noncytotoxic. Some of these complexes altered the DNA tertiary structure in a similar way to cisplatin but at higher concentration, and most cytotoxic ones did not present a high efficiency as cathepsin B inhibitors