32 research outputs found

    Continental Magmatism and Uplift as the Primary Driver for First-Order Oceanic 87Sr/86Sr Variability with Implications for Global Climate and Atmospheric Oxygenation

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    Oceans cover 70% of Earth\u27s surface, setting it apart from the other terrestrial planets in the solar system, but the mechanisms driving oceanic chemical evolution through time remain an important unresolved problem. Imbalance in the strontium cycle, introduced, for example, by increases in continental weathering associated with mountain building, has been inferred from shifts in marine carbonate 87Sr/86Sr ratios. There are, however, uncertainties about the spatial and temporal patterns of crustal evolution in Earth\u27s past, particularly for the period leading up to the Cambrian explosion of life. Here we show that U-Pb age and trace element data from a global compilation of detrital zircons are consistent with marine carbonate 87Sr/86Sr ratios, suggesting changes in radiogenic continental input into Earth\u27s oceans over time. Increases in riverine Sr input were related to the break-up and dispersal of continents, with increased weathering and erosion of a higher proportion of radiogenic rocks and high-elevation continental crust. Tectonic processes exert a strong influence on the chemical evolution of the planet\u27s oceans over geologic time scales and may have been a key driver for concomitant increases in atmosphere-ocean oxygenation and global climate cooling

    Tuning mobility and stability of lithium ion conductors based on lattice dynamics

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    Lithium ion conductivity in many structural families can be tuned by many orders of magnitude, with some rivaling that of liquid electrolytes at room temperature. Unfortunately, fast lithium conductors exhibit poor stability against lithium battery electrodes. In this article, we report a fundamentally new approach to alter ion mobility and stability against oxidation of lithium ion conductors using lattice dynamics. By combining inelastic neutron scattering measurements with density functional theory, fast lithium conductors were shown to have low lithium vibration frequency or low center of lithium phonon density of states. On the other hand, lowering anion phonon densities of states reduces the stability against electrochemical oxidation. Olivines with low lithium band centers but high anion band centers are promising lithium ion conductors with high ion conductivity and stability. Such findings highlight new strategies in controlling lattice dynamics to discover new lithium ion conductors with enhanced conductivity and stability.United States. National Science Foundation. Graduate Research Fellowship Program (Grant 1122374)Taiwan. Ministry of Science and Technology (Grant 102-2917-I-564-006-A1)United States. National Science Foundation (Award DMR-0819762)United States. National Energy Research Scientific Computing Center (Contract DE-AC02-05CH11231)Extreme Science and Engineering Discovery Environment (Grant ACI-1548562

    The multiple facets of the Hsp90 machine

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    International audienceThe Ninth International Conference on the Hsp90 Chaperone Machine concluded in October 2018, in Leysin, Switzerland. The program highlighted findings in various areas, including integrated insight into molecular mechanism of Hsp90, cochaperones, and clients’ structure and function.Heat shock protein-90 (Hsp90) is a molecular chaperone critical for the folding, stability, and activity of client proteins 1. Hsp90 and its orthologs, including bacterial HtpG, mitochondrial TRAP1 and endoplasmic reticulum Grp94, exist as dimers, hydrolyze ATP, and cycle between distinct conformational states. Hsp90 preferentially binds proteins in near native states facilitating their remodeling for protein interactions and signaling. At the 9th International Conference on the Hsp90 Chaperone Machine approximately one-third of the attendees shared their data on Hsp90 structure and function through short talks (Figure 1). Here, we distill and summarize their finding
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