Erratum: The solar orbiter radio and plasma waves (RPW) instrument (Astronomy and Astrophysics (2020) 642 (A12) DOI: 10.1051/0004-6361/201936214)

The erratum concerns Fig. 9 entitled "Antenna radio-electrical properties" for which some of the parameters are not correct. The new figure with new parameters is provided in Fig. 1 of this corrigendum. Fig. 1. Corrected Antenna radio-electrical properties. (Figure Presented)

Influence of Molecular Dipole Orientations on Long-Range Exponential Interaction Forces at Hydrophobic Contacts in Aqueous Solutions

Strong and particularly long ranged (>100 nm) interaction forces between apposing hydrophobic lipid monolayers are now well understood in terms of a partial turnover of mobile lipid patches, giving rise to a correlated long-range electrostatic attraction. Here we describe similarly strong long-ranged attractive forces between self-assembled monolayers of carboranethiols, with dipole moments aligned either parallel or perpendicular to the surface, and hydrophobic lipid monolayers deposited on mica. We compare the interaction forces measured at very different length scales using atomic force microscope and surface forces apparatus measurements. Both systems gave a long-ranged exponential attraction with a decay length of 2.0 +/- 0.2 nm for dipole alignments perpendicular to the surface. The effect of dipole alignment parallel to the surface is larger than for perpendicular dipoles, likely due to greater lateral correlation of in-plane surface dipoles. The magnitudes and range of the measured interaction forces also depend on the surface area of the probe used: At extended surfaces, dipole alignment parallel to the surface leads to a stronger attraction due to electrostatic correlations of freely rotating surface dipoles and charge patches on the apposing surfaces. In contrast, perpendicular dipoles at extended surfaces, where molecular rotation cannot lead to large dipole correlations, do not depend on the scale of the probe used. Our results may be important to a range of scale-dependent interaction phenomena related to solvent/water structuring on dipolar and hydrophobic surfaces at interfaces

Acid-Base Control of Valency within Carboranedithiol Self-Assembled Monolayers: Molecules Do the Can-Can.

We use simple acid-base chemistry to control the valency in self-assembled monolayers of two different carboranedithiol isomers on Au{111}. Monolayer formation proceeds via Au-S bonding, where manipulation of pH prior to or during deposition enables the assembly of dithiolate species, monothiol/monothiolate species, or combination. Scanning tunneling microscopy (STM) images identify two distinct binding modes in each unmodified monolayer, where simultaneous spectroscopic imaging confirms different dipole offsets for each binding mode. Density functional theory calculations and STM image simulations yield detailed understanding of molecular chemisorption modes and their relation with the STM images, including inverted contrast with respect to the geometric differences found for one isomer. Deposition conditions are modified with controlled equivalents of either acid or base, where the coordination of the molecules in the monolayers is controlled by protonating or deprotonating the second thiol/thiolate on each molecule. This control can be exercised during deposition to change the valency of the molecules in the monolayers, a process that we affectionately refer to as the "can-can." This control enables us to vary the density of molecule-substrate bonds by a factor of 2 without changing the molecular density of the monolayer

Solar Orbiter Radio and Plasma Waves – Time Domain Sampler: In-flight performance and first results

International audienceContext. The Radio and Plasma Waves (RPW) instrument on board Solar Orbiter has been operating nearly continuously since the launch in February 2020. The Time Domain Sampler (TDS) receiver of the RPW instrument is dedicated to waveform measurements of plasma waves and dust impact signatures in an intermediate frequency range from 0.2 to 200 kHz.Aims. This article presents the first data from the RPW-TDS receiver and discusses the in-flight performance of the instrument and, in particular, the on-board wave and dust detection algorithm. We present the TDS data products and its scientific operation. We demonstrate the content of the dataset on several examples. In particular, we study the distribution of solar Langmuir waves in the first year of observations and one Type III burst event.Methods. The on-board detection algorithm is described in detail in this article and classifies the observed waveform snapshots, identifying plasma waves and dust impacts based on the ratio of their maximum amplitude to their median and on the spectral bandwidth. The algorithm allows TDS to downlink the most scientifically relevant waveforms and to perform an on-board statistical characterization of the processed data.Results. The detection algorithm of TDS is shown to perform very well in its detection of plasma waves and dust impacts with a high accuracy. The initial analysis of statistical data returned by TDS shows that sporadic Langmuir waves that are not associated with Type III events are routinely observed in the inner heliosphere, with a clear increase in occurrence rate closer to the Sun. We also present an example of RPW observations during an encounter of the source region of a Type III burst, which exploits the on-board calculated histograms data