Processing of laser formed SiC powder

Superior SiC characteristics can be achieved through the use of ideal constituent powders and careful post-synthesis processing steps. High purity SiC powders of approx. 1000 A uniform diameter, nonagglomerated and spherical were produced. This required major revision of the particle formation and growth model from one based on classical nucleation and growth to one based on collision and coalescence of Si particles followed by their carburization. Dispersions based on pure organic solvents as well as steric stabilization were investigated. Although stable dispersions were formed by both, subsequent part fabrication emphasized the pure solvents since fewer problems with drying and residuals of the high purity particles were anticipated. Test parts were made by the colloidal pressing technique; both liquid filtration and consolidation (rearrangement) stages were modeled. Green densities corresponding to a random close packed structure (approx. 63%) were achieved; this highly perfect structure has a high, uniform coordination number (greater than 11) approaching the quality of an ordered structure without introducing domain boundary effects. After drying, parts were densified at temperatures ranging from 1800 to 2100 C. Optimum densification temperatures will probably be in the 1900 to 2000 C range based on these preliminary results which showed that 2050 C samples had experienced substantial grain growth. Although overfired, the 2050 C samples exhibited excellent mechanical properties. Biaxial tensile strengths up to 714 MPa and Vickers hardness values of 2430 kg/sq mm 2 were both more typical of hot pressed than sintered SiC. Both result from the absence of large defects and the confinement of residual porosity (less than 2.5%) to small diameter, uniformly distributed pores

Processing of laser formed SiC powder

Processing research was undertaken to demonstrate that superior SiC characteristics could be achieved through the use of ideal constituent powders and careful post-synthesis processing steps. Initial research developed the means to produce approximately 1000 A uniform diameter, nonagglomerated, spherical, high purity SiC powders. Accomplishing this goal required major revision of the particle formation and growth model from one based on classical nucleation and growth to one based on collision and coalescence of Si particles followed by their carburization. Dispersions based on pure organic solvents as well as steric stabilization were investigated. Test parts were made by the colloidal pressing technique; both liquid filtration and consolidation (rearrangement) stages were modeled. Green densities corresponding to a random close packed structure were achieved. After drying, parts were densified at temperatures ranging from 1800 to 2100 C. This research program accomplished all of its major objectives. Superior microstructures and properties were attained by using powders having ideal characteristics and special post-synthesis processing procedures

Direct observation of a highly spin-polarized organic spinterface at room temperature

The design of large-scale electronic circuits that are entirely spintronics-driven requires a current source that is highly spin-polarised at and beyond room temperature, cheap to build, efficient at the nanoscale and straightforward to integrate with semiconductors. Yet despite research within several subfields spanning nearly two decades, this key building block is still lacking. We experimentally and theoretically show how the interface between Co and phthalocyanine molecules constitutes a promising candidate. Spin-polarised direct and inverse photoemission experiments reveal a high degree of spin polarisation at room temperature at this interface. We measured a magnetic moment on the molecules's nitrogen pi orbitals, which substantiates an ab-initio theoretical description of highly spin-polarised charge conduction across the interface due to differing spinterface formation mechanims in each spin channel. We propose, through this example, a recipe to engineer simple organic-inorganic interfaces with remarkable spintronic properties that can endure well above room temperature

Trace Element Composition of Stream Sediments an Integrating Factor for Water Quality

Bottom sediments, suspended sediments, and water were sampled along 130 miles of the Buffalo River in northern Arkansas. The water and acid extracts of the suspended sediments and the minus 95 mesh fraction of the bottom sediments were analyzed by atomic absorption spectrometry. All samples were analyzed for Na, K, Mg, Ca, Zn, Cd, Cu, Pb, Fe, Co, Cr, Ni, and Mn. Selected bottom samples also were analyzed by As, Hg, and Zr. Zr was determined by x-ray fluorescence. Li and Sr were determined for selected water and suspended sediment samples. There is a general decrease downstream in Fe, Cu, Cr, Ni, Mn, Pb, K, and Na in the bottom sediments as the drainage area increases in carbonate rock and decreases in shale. The elements Mg, Ca, Zn, and Cd increase in bottom sediments downstream. The values for these elements in the water, especially the major elements, also correspond closely with the geology of the region. Tributaries are sites of abrupt rise and fall of metal values, within a few miles, from background to anomalously high values to background, especially tributaries draining Zn and Pb mineralized areas. The bottom sediments are mainly quartz and chert grains. These grains apparently are coated with hydrous iron oxide which acts as a sorbent for many of the elements and is a dominant transport mechanism for acid extractable Co, Cr, Ni, Cu, Mn, and K. Other acid extractable metals, particularly Mg, Ca, Zn, Cd, and Pb, are mostly in clastic grains. Graphic representation of the Langmuir equation for Mn is consistent with adsorption of Mn by iron in both bottom sediments and suspended sediments. On the basis of the volume of water collected, all the elements except Fe are more concentrated in the water than in the suspended sediments. Fe concentration of the suspended sediments increases with increasing flow because the suspended load is increased. The Mn/Fe ratio of the suspended sediments is approximately equal to or greater than that of the bottom sediments. The Mn/Fe ratio of suspended sediments relative to that of the bottom sediments increases downstream, possibly because of an autocatalytic effect of Mn precipitation. The relationship between sediment and water concentrations is not clear from the data because of the restricted concentration ranges for some elements in the suspended sediment and water. The sediment from the Buffalo River can be used to estimate grossly the concentration of elements in the water

Teleportation as a Depolarizing Quantum Channel, Relative Entropy and Classical Capacity

We show that standard teleportation with an arbitrary mixed state resource is equivalent to a generalized depolarizing channel with probabilities given by the maximally entangled components of the resource. This enables the usage of any quantum channel as a generalized depolarizing channel without additional twirling operations. It also provides a nontrivial upper bound on the entanglement of a class of mixed states. Our result allows a consistent and statistically motivated quantification of teleportation success in terms of the relative entropy and this quantification can be related to a classical capacity.Comment: Version published in Phys. Rev. Let

Squeezed light at sideband frequencies below 100 kHz from a single OPA

Quantum noise of the electromagnetic field is one of the limiting noise sources in interferometric gravitational wave detectors. Shifting the spectrum of squeezed vacuum states downwards into the acoustic band of gravitational wave detectors is therefore of challenging demand to quantum optics experiments. We demonstrate a system that produces nonclassical continuous variable states of light that are squeezed at sideband frequencies below 100 kHz. A single optical parametric amplifier (OPA) is used in an optical noise cancellation scheme providing squeezed vacuum states with coherent bright phase modulation sidebands at higher frequencies. The system has been stably locked for half an hour limited by thermal stability of our laboratory.Comment: 3 pages, 3 figure

"It\u27s all their words, it\u27s just not necessarily all of the words": Balancing Authenticity and Authority in Participatory Heritage Projects

Participatory heritage approaches have the potential to create more democratic forms of local history and a relational commons around this material. This paper presents an interview-based study with volunteers from a community oral history organisation, to explore their current working practices, particularly around editing and publishing material and to consider volunteers’ feelings and concerns around openness and control of archive material. From the interviews, tensions were found between the desire for openness and concerns around the need for structure, highlighting challenges to address for future work in designing systems for participatory local history projects

Electrospray synthesis of PLGA TIPS microspheres

We successfully demonstrate the synthesis of polymer microspheres using a single electrospray source, and show their physical characterisation. Electrospray has proven to be a versatile method to manufacture particles, giving tight control over size with quasi-monodisperse size distributions. It is a liquid atomisation technique that generates a monodisperse population of highly charged liquid droplets over a broad size range (nanometres to tens of microns). The droplets contain liquid precursors for the in-flight synthesis of particles, and control over the trajectory of these droplets can be precisely manipulated with the use of electric fields to drive them to a grounded substrate. This study reports a method to synthesize poly(lactic-co-glycolic) acid (PLGA) microspheres using the electrospray and thermally induced phase separation (TIPS) techniques, followed by subsequent freeze-drying, for particle production. These microspheres are of interest as vehicles for controlled drug release systems

New evidence as to the nature of the incoming cosmic rays, their absorbability in the atmosphere, and the secondary character of the penetrating rays found in such abundance at sea level and below

The intensity of latitude-sensitive cosmic rays as would be measured by an electroscope placed just outside the atmosphere has been calculated. The ionization due to incoming electrons of 10 billion electron volts energy in this same electroscope placed 1/20th of an atmosphere beneath the top is found to be 13 times that outside. Electrons do not become penetrating by virtue of high energies even up to 17 billion electron volts. Neither protons nor other penetrating particles of any sort enter the atmosphere in significant numbers from outside the atmosphere. The observed penetrating particles and all other cosmic-ray effects, latitude-sensitive and non-latitude-sensitive, found in the lower atmosphere are practically all secondary effects—splashes from the absorption of electrons, or photons, or both taking place in the outer layers of the atmosphere

A very high altitude survey of the effect of latitude upon cosmic-ray intensities - and an attempt at a general interpretation of cosmic-ray phenomena

The results of a very high altitude geographical survey extending in airplanes from Northern Canada to Peru, to altitudes of 22,000 feet, and, in three stratosphere flights made within the United States, to altitudes of 60,000 feet, are interpreted in the light of (1) the Epstein and the Lemaitre-Vallarta analysis of the effect of the earth's magnetic field, and (2) the Bowen-Millikan proof that the immediate agents responsible for the ionization of the atmosphere are electrons (+ and -), rather than protons or heavier nuclei. The main conclusions reached are: (1) that the resistance of the atmosphere to incoming electrons is 1 billion volts because of extranuclear encounters, 5 billion volts because of nuclear encounters; (2) that nuclear electron encounters produce only very soft secondaries, both photons and electrons; (3) that incoming photons produce most of the ionization found at sea-level or at sub-sea-level depths; (4) that nearly all of the non-field sensitive part of the ionization of the atmosphere above sea-level is due to photons of energy 200±170 million electron volts; (5) that in the equatorial belt a small part of the ionization is due to incoming secondary electrons of energies as high as 10 billion volts; (6) that these are responsible for the east-west effect and the longitude effect found in the equatorial belt; (7) that the field sensitive part of the ionization increases rapidly with increasing latitude in going from Panama to Spokane because incoming secondaries of energies decreasing from 8 billion to 2 billion volts get through the blocking effect of the field in rapidly increasing numbers with increasing latitude and add greatly in northern latitudes to the underlying ionization of the upper-air produced by the incoming photons; (8) that the only source now in sight of the observed cosmic-ray energies is matter-annihilation; (9) that the softest components of the cosmic rays have the energies corresponding to the partial annihilation or atom building hypothesis, while the hardest components have energies corresponding to the complete atom-annihilation hypothesis; (10) that these processes may conceivably be taking place (1) because of the very low temperatures that facilitate the clustering of hydrogen in interstellar space, or (2) because of such extreme temperature conditions of the opposite sort as are found in novae, as suggested by Zwicky