Ozone mediated depolymerization and solvolysis of technical lignins under ambient conditions in ethanol

Technical lignins are highly available and inexpensive feedstocks derived from current large scale biomass utilizing industries. Their valorization represents a bottleneck in the development of biorefineries, as the inherently complex lignin structure often suffers severe condensation during isolation, leading to their current application as low value fuel. Processes able to depolymerize technical lignins into value-added (intermediate) molecules are of great interest for the development of integrated, viable routes aiming at the full valorization of lignocellulosic biomass. Here, we report an effective ozone mediated depolymerization of four technical lignins (Indulin-AT Kraft, ball-milled Indulin-AT Kraft, Alcell organosolv and Fabiola organosolv) in ethanol under ambient conditions without the need for catalysts. 52–87 wt% of these nearly ethanol insoluble lignins was broken down into soluble fragments upon ozone exposure. The average molecular weight of the soluble fragments was shown to have decreased by 40–75% compared to the parent materials. A range of (di)carboxylic acids and (di)ethyl esters was identified, accounting for up to 40 wt% of the ozonated lignin oils. These products are the result of phenol ring-opening reactions as well as oxidative cleavage of unsaturated linking motifs followed by partial esterification. Reactivity varied substantially among the lignin feedstocks. For instance, lower particle sizes and higher degradation of the native lignin structure were shown to be beneficial for the effective action of the ozone. Our results show that a straightforward ozonation process under ambient conditions can depolymerize recalcitrant lignins into oxygenated fragments and low molecular weight products soluble in ethanol. These can potentially be used for the synthesis of high-value drop-in chemicals

Survival-extinction phase transition in a bit-string population with mutation

A bit-string model for the evolution of a population of haploid organisms, subject to competition, reproduction with mutation and selection is studied, using mean field theory and Monte Carlo simulations. We show that, depending on environmental flexibility and genetic variability, the model exhibits a phase transtion between extinction and survival. The mean-field theory describes the infinite-size limit, while simulations are used to study quasi-stationary properties.Comment: 11 pages, 5 figure

Variáveis e modelos para estimativa da produtividade do cafeeiro a partir de índices de vegetação derivados de imagens Landsat.

Abstract. Coffee fields present a specific pattern of productivity resulting in high and low production in alternated years. Branches grown the first phenological year will produce coffee beans the second phenological year. In high-production years a plant works mostly to grain-filling to the detriment of new branches which will be responsible for production the following year. In low-production years the plant works rather to grow new branches which will produce beans the subsequent year. This feature can be related to the foliar biomass, which can be estimated through remote sensing derived vegetation indices. Several studies report this feature must be incorporated in modeling coffee yield coupled with agrometeorogical models. In this paper we derived Landsat vegetation indices related to coffee plots in order to obtain relationships to yield of the same coffee plots. Biophisical variables and yield data were colected in interviews with farmers from four locations in the whole largest Brazilian coffee-exporting province. Vegetation indices and biophysical variables were selected through stepwise regression in order to obtain the best regression models to estimate coffee yield. Outcomes showed that general models and specific models obtained for Mundo Novo variety presented Pearson's correlation coeficients (r) from 0,64 to 0,71 while models for Catuaí variety showed better results (r = 0,85). Although coffee yield cannot be estimated exclusively from these models, they can be usefull coupled with agrometeorogical models for estimating coffee yield

Evolution of Coordination in Social Networks: A Numerical Study

Coordination games are important to explain efficient and desirable social behavior. Here we study these games by extensive numerical simulation on networked social structures using an evolutionary approach. We show that local network effects may promote selection of efficient equilibria in both pure and general coordination games and may explain social polarization. These results are put into perspective with respect to known theoretical results. The main insight we obtain is that clustering, and especially community structure in social networks has a positive role in promoting socially efficient outcomes.Comment: preprint submitted to IJMP

Forest fires and other examples of self-organized criticality

We review the properties of the self-organized critical (SOC) forest-fire model. The paradigm of self-organized criticality refers to the tendency of certain large dissipative systems to drive themselves into a critical state independent of the initial conditions and without fine-tuning of the parameters. After an introduction, we define the rules of the model and discuss various large-scale structures which may appear in this system. The origin of the critical behavior is explained, critical exponents are introduced, and scaling relations between the exponents are derived. Results of computer simulations and analytical calculations are summarized. The existence of an upper critical dimension and the universality of the critical behavior under changes of lattice symmetry or the introduction of immunity are discussed. A survey of interesting modifications of the forest-fire model is given. Finally, several other important SOC models are briefly described.Comment: 37 pages RevTeX, 13 PostScript figures (Figs 1, 4, 13 are of reduced quality to keep download times small

Wiki: integrando conhecimento, gestão e comunicação nas atividades do LabInfo da Embrapa Informática Agropecuária.

Wiki é um termo havaino que significa rápido e, na web, é usado para designar uma coleção de documentos no formato de hipertexto (WIKIPEDIA, 2009). Um wiki pode ser utilizado em web sites dinâmicos, como ferramenta de gestão de projetos ou, ainda, como uma base de conhecimento, potencializando a cultura do trabalho coletivo. Entre suas principais vantagens (HASAN & PFAFF, 2006), os wiki's se caracterizam por serem multiplataformas; apresentarem recursos para edição de textos amigáveis, intuitivos e descomplicados, além de poderem guardar um histórico das alterações de edição; também possuem sintaxe própria; código fonte aberto; navegação não linear e sistema de busca, no texto completo ou no título da página, cuja construção, quando bem feita, funciona como um sistema de indexação.Trabalho apresentado na V Mostra de Trabalhos de Estagiários e Bolsistas, Campinas, out. 2009

Time evolution of the Partridge-Barton Model

The time evolution of the Partridge-Barton model in the presence of the pleiotropic constraint and deleterious somatic mutations is exactly solved for arbitrary fecundity in the context of a matricial formalism. Analytical expressions for the time dependence of the mean survival probabilities are derived. Using the fact that the asymptotic behavior for large time $t$ is controlled by the largest matrix eigenvalue, we obtain the steady state values for the mean survival probabilities and the Malthusian growth exponent. The mean age of the population exhibits a $t^{-1}$ power law decayment. Some Monte Carlo simulations were also performed and they corroborated our theoretical results.Comment: 10 pages, Latex, 1 postscript figure, published in Phys. Rev. E 61, 5664 (2000

Strategies for the evolution of sex

We find that the hypothesis made by Jan, Stauffer and Moseley [Theory in Biosc., 119, 166 (2000)] for the evolution of sex, namely a strategy devised to escape extinction due to too many deleterious mutations, is sufficient but not necessary for the successful evolution of a steady state population of sexual individuals within a finite population. Simply allowing for a finite probability for conversion to sex in each generation also gives rise to a stable sexual population, in the presence of an upper limit on the number of deleterious mutations per individual. For large values of this probability, we find a phase transition to an intermittent, multi-stable regime. On the other hand, in the limit of extremely slow drive, another transition takes place to a different steady state distribution, with fewer deleterious mutations within the asexual population.Comment: RevTeX, 11 pages, multicolumn, including 12 figure

Tactical Voting in Plurality Elections

How often will elections end in landslides? What is the probability for a head-to-head race? Analyzing ballot results from several large countries rather anomalous and yet unexplained distributions have been observed. We identify tactical voting as the driving ingredient for the anomalies and introduce a model to study its effect on plurality elections, characterized by the relative strength of the feedback from polls and the pairwise interaction between individuals in the society. With this model it becomes possible to explain the polarization of votes between two candidates, understand the small margin of victories frequently observed for different elections, and analyze the polls' impact in American, Canadian, and Brazilian ballots. Moreover, the model reproduces, quantitatively, the distribution of votes obtained in the Brazilian mayor elections with two, three, and four candidates.Comment: 7 pages, 4 figure