Nitrogen superfractionation in dense cloud cores

We report new calculations of interstellar 15N fractionation. Previously, we have shown that large enhancements of 15N/14N can occur in cold, dense gas where CO is frozen out, but that the existence of an NH + N channel in the dissociative recombination of N2H+ severely curtails the fractionation. In the light of recent experimental evidence that this channel is in fact negligible, we have reassessed the 15N chemistry in dense cloud cores. We consider the effects of temperatures below 10 K, and of the presence of large amounts of atomic nitrogen. We also show how the temporal evolution of gas-phase isotope ratios is preserved as spatial heterogeneity in ammonia ice mantles, as monolayers deposited at different times have different isotopic compositions. We demonstrate that the upper layers of this ice may have 15N/14N ratios an order of magnitude larger than the underlying elemental value. Converting our ratios to delta-values, we obtain delta(15N) > 3,000 per mil in the uppermost layer, with values as high as 10,000 per mil in some models. We suggest that this material is the precursor to the 15N `hotspots' recently discovered in meteorites and IDPsComment: accepted by MNRA

Small scale structure in diffuse molecular gas from repeated FUSE and visible spectra of HD 34078

We present preliminary results from an ongoing program devoted to a study of small scale structure in the spatial distribution of molecular gas. Our work is based on multi-epoch FUSE and visible observations of HD34078. A detailed comparison of H2, CH and CH+ absorption lines is performed. No short term variations are seen (except for highly excited H2) but long-term changes in N(CH) are clearly detected when comparing our data to spectra taken about 10 years ago.Comment: 4 pages, 2 figures, To appear in the Proceedings of the XVII IAP Colloquium "Gaseous Matter in Galaxies and Intergalactic Space

Dual mobility hip arthroplasty wear measurement: Experimental accuracy assessment using radiostereometric analysis (RSA)

SummaryIntroductionThe use of dual mobility cups is an effective method to prevent dislocations. However, the specific design of these implants can raise the suspicion of increased wear and subsequent periprosthetic osteolysis.HypothesisUsing radiostereometric analysis (RSA), migration of the femoral head inside the cup of a dual mobility implant can be defined to apprehend polyethylene wear rate.Study objectivesThe study aimed to establish the precision of RSA measurement of femoral head migration in the cup of a dual mobility implant, and its intra- and interobserver variability.Material and methodsA total hip prosthesis phantom was implanted and placed under weight loading conditions in a simulator. Model-based RSA measurement of implant penetration involved specially machined polyethylene liners with increasing concentric wear (no wear, then 0.25, 0.5 and 0.75mm). Three examiners, blinded to the level of wear, analyzed (10 times) the radiostereometric films of the four liners. There was one experienced, one trained, and one inexperienced examiner. Statistical analysis measured the accuracy, precision, and intra- and interobserver variability by calculating Root Mean Square Error (RMSE), Concordance Correlation Coefficient (CCC), Intra Class correlation Coefficient (ICC), and Bland-Altman plots.ResultsOur protocol, that used a simple geometric model rather than the manufacturer's CAD files, showed precision of 0.072mm and accuracy of 0.034mm, comparable with machining tolerances with low variability. Correlation between wear measurement and true value was excellent with a CCC of 0.9772. Intraobserver reproducibility was very good with an ICC of 0.9856, 0.9883 and 0.9842, respectively for examiners 1, 2 and 3. Interobserver reproducibility was excellent with a CCC of 0.9818 between examiners 2 and 1, and 0.9713 between examiners 3 and 1.DiscussionQuantification of wear is indispensable for the surveillance of dual mobility implants. This in vitro study validates our measurement method. Our results, and comparison with other studies using different measurement technologies (RSA, standard radiographs, Martell method) make model-based RSA the reference method for measuring the wear of total hip prostheses in vivo.Level of evidenceLevel 3. Prospective diagnostic study

Clustering of scene repeats for essential rushes preview

This paper focuses on a specific type of unedited video content, called rushes, which are used for movie editing and usually present a high-level of redundancy. Our goal is to automatically extract a summarized preview, where redundant material is diminished without discarding any important event. To achieve this, rushes content has been first analysed and modeled. Then different clustering techniques on shot key-frames are presented and compared in order to choose the best representative segments to enter the preview. Experiments performed on TRECVID data are evaluated by computing the mutual information between the obtained results and a manually annotated ground-truth

The Nineteenth Century Engagement Between Geological and Adventist Thought and its Bearing on the Twentieth Century Flood Geology Movement

The Seventh-day Adventist Church has from the early years of its existence reacted to the perceived challenge of geological thought to their nascent theology. In particular, the Sabbath of the fourth Commandment in Genesis 2 and the catastrophic global Flood described in Genesis 7 and 8 were targeted. The nineteenth century Adventist response has been one of shifting focus, changing strategies, and increasing intensity. Ellen White, the church’s co-founder and prophetess, was one of the first to sound a warning on theological implications of geology. Her perception of geology contained many pre-nineteenth century concepts disconnected from contemporary geological thinking. Long-time editor Uriah Smith used external documents, notably Presbyterian writings to guide the Adventist congregation with ways of responding to geological thought as it impacted on their faith. The first authentic Adventist evaluation of geology and its perceived link with evolution by Alonzo Jones took place in the mid-1880s. With his spirited response, Jones criticised geological stratigraphic concepts in order to neutralise the threat of burgeoning theistic evolutionary thought. His searching in the geological literature involved the use of contextomy. George McCready Price next ventured to nullify the established stratigraphic principles of geology in order to justify a single, global flood-based hypothesis to explain all fossiliferous sedimentary formations. To achieve this, he presented from established scientists selected citations out of their intended context. A special case is presented on Price’s questionable use of the reports of American field geologists McConnell and Willis on thrust faults in the Rocky Mountains. Price modified diagrams and failed to convey unmistakable evidence of a dynamic cause of complex stratigraphy to present his case for the global existence of reverse sequences of rock strata. He argued that since the geologists’ evidence for a fossil sequence of life in the rock stratigraphy is so greatly flawed, there must have been a single catastrophic event that better explained this. Adventist engagement with geological thought during this period saw a noticeable increase in the disregard of intellectual integrity. This study argues that intellectual dishonesty is not a valid way to support a preconceived interpretation of the scriptural narrative. History provides several examples where skewed accounts of events due to questionable intellectual sincerity have eventually been corrected. This research provides access points for interested persons to further investigate the historical aspects of the nineteenth century geology and Adventist thought engagement

Shock excitation of H2_2 in the James Webb Space Telescope era

(Abridged) H2 is the most abundant molecule in the Universe. Thanks to its widely spaced energy levels, it predominantly lights up in warm gas, T > 100 K, such as shocked regions, and it is one of the key targets of JWST observations. These include shocks from protostellar outflows, all the way up to starburst galaxies and AGN. Shock models are able to simulate H2 emission. We aim to explore H2 excitation using such models, and to test over which parameter space distinct signatures are produced in H2 emission. We present simulated H2 emission using the Paris-Durham shock code over an extensive grid of 14,000 plane-parallel stationary shock models, a large subset of which are exposed to an external UV radiation field. The grid samples 6 input parameters: preshock density, shock velocity, transverse magnetic field strength, UV radiation field strength, cosmic-ray-ionization rate, and PAH abundance. Physical quantities, such as temperature, density, and width, have been extracted along with H2 integrated line intensities. The strength of the transverse magnetic field, set by the scaling factor, b, plays a key role in the excitation of H2. At low values of b (<~ 0.3, J-type shocks), H2 excitation is dominated by vibrationally excited lines; at higher values (b >~ 1, C-type shocks), rotational lines dominate the spectrum for shocks with an external radiation field comparable to (or lower than) the solar neighborhood. Shocks with b >= 1 can be spatially resolved with JWST for nearby objects. When the input kinetic energy flux increases, the excitation and integrated intensity of H2 increases similarly. An external UV field mainly serves to increase the excitation, particularly for shocks where the input radiation energy is comparable to the input kinetic energy flux. These results provide an overview of the energetic reprocessing of input kinetic energy flux and the resulting H2 line emission.Comment: Published in A&

Sports video: Fine-grained action detection and classification of table tennis strokes from videos for MediaEval 2021

This paper presents the baseline method proposed for the Sports Video task part of the MediaEval 2021 benchmark. This task proposes a stroke detection and a stroke classification subtasks. This baseline addresses both subtasks. The spatio-temporal CNN architecture and the training process of the model are tailored according to the addressed subtask. The method has the purpose of helping the participants to solve the task and is not meant to reach stateof-the-art performance. Still, for the detection task, the baseline is performing better than the other participants, which stresses the difficulty of such a task

Validation of a FFQ for estimating whole-grain cereal food intake

Estimation of whole-grain (WG) food intake in epidemiological and nutritional studies is normally based on general diet FFQ, which are not designed to specifically capture WG intake. To estimate WG cereal intake, we developed a forty-three-item FFQ focused on cereal product intake over the past month. We validated this questionnaire against a 3-d-weighed food record (3DWFR) in thirty-one subjects living in the French-speaking part of Switzerland (nineteen female and twelve male). Subjects completed the FFQ on day 1 (FFQ1), the 3DWFR between days 2 and 13 and the FFQ again on day 14 (FFQ2). The subjects provided a fasting blood sample within 1 week of FFQ2. Total cereal intake, total WG intake, intake of individual cereals, intake of different groups of cereal products and alkylresorcinol (AR) intake were calculated from both FFQ and the 3DWFR. Plasma AR, possible biomarkers for WG wheat and rye intake were also analysed. The total WG intake for the 3DWFR, FFQ1, FFQ2 was 26 (sd 22), 28 (sd 25) and 21 (sd 16)g/d, respectively. Mean plasma AR concentration was 55·8 (sd 26·8)nmol/l. FFQ1, FFQ2 and plasma AR were correlated with the 3DWFR (r 0·72, 0·81 and 0·57, respectively). Adjustment for age, sex, BMI and total energy intake did not affect the results. This FFQ appears to give a rapid and adequate estimate of WG cereal intake in free-living subject