Geologic application of thermal inertia imaging using HCMM data

Three test sites in the western US were selected to discriminate among surface geologic materials on the basis of their thermal properties as determined from HCMM data. Attempts to determine quantitatively accurate thermal inertia values from HCMM digital data met with only partial success due to the effects of sensor miscalibrations, radiative transfer in the atmosphere, and varying meteorology and elevation across a scene. In most instances, apparent thermal inertia was found to be an excellent qualitative representation of true thermal inertia. Computer processing of digital day and night HCMM data allowed construction of geologically useful images. At some test sites, more information was provided by data than LANDSAT data. Soil moisture effects and differences in spectrally dark materials were more effectively displayed using the thermal data

Evaluation of thermal data for geologic applications

Sensitivity studies using thermal models indicated sources of errors in the determination of thermal inertia from HCMM data. Apparent thermal inertia, with only simple atmospheric radiance corrections to the measured surface temperature, would be sufficient for most operational requirements for surface thermal inertia. Thermal data does have additional information about the nature of surface material that is not available in visible and near infrared reflectance data. Color composites of daytime temperature, nighttime temperature, and albedo were often more useful than thermal inertia images alone for discrimination of lithologic boundaries. A modeling study, using the annual heating cycle, indicated the feasibility of looking for geologic features buried under as much as a meter of alluvial material. The spatial resolution of HCMM data is a major limiting factor in the usefulness of the data for geologic applications. Future thermal infrared satellite sensors should provide spatial resolution comparable to that of the LANDSAT data

Yield Reserve Program Costs in the Virginia Coastal Plain

A proposed Yield Reserve Program designed to compensate farmers for any reduced yields resulting from nitrogen (N) application rates reduced to below recommended rates is evaluated. Assuming that farmers currently follow Extension recommendations for applying N, Yield Reserve Program participation reduces expected net revenue by $10 to$13/ha. The Yield Reserve Program reduces expected net revenue by $17 to$20/ha for farmers who apply N to maximize expected net revenue. Farmers’ costs of participation increase with lower probabilities of inadequate rainfall and higher corn prices and decline with higher N prices. The Yield Reserve Program can significantly reduce N applications to cropland, which may reduce N content of surface waters, but the costs to taxpayers and farmers will depend on how the program is implemented.compliance cost, nitrogen fertilizer, nonpoint source pollution, policy, yield response function, Agricultural and Food Policy, Crop Production/Industries,

Seismic observations of transient subglacial water-flow beneath MacAyeal Ice Stream, West Antarctica

New seismic observations of harmonic tremors beneath MacAyeal Ice Stream, West Antarctica are reported. Each of the two tremor events that we recorded during a six week period had sustained arrival of 3 Hz energy for approximately 10 minutes. During that time the source location migrated a few kilometers. The harmonic nature of the tremors is interpreted as the result of resonance in subglacial water-filled cracks and conduits. The duration, monochromatic nature, and movement of the tremor indicate that the source mechanism is likely flow in the subglacial water system resulting from the discharge from a small subglacial lake. Our results suggest that the subglacial water system produces repeated, small outburst floods, with possible implications for ice-stream dynamics

Conformational Preferences of 3-(Dimethylazinoyl)propanoic Acid as a Function of pH and Solvent; Intermolecular versus Intramolecular Hydrogen Bonding

The conformational equilibrium of 3-(dimethylazinoyl)propanoic acid (DMAPA, azinoyl = N^+(O^−) has a weak pH-dependence in D_2O, with a slight preference for trans in alkaline solutions. The acid ionization constants of the protonated amine oxide and carboxylic functional groups as determined by NMR spectroscopy were 7.9 × 10^(−4) and 6.3 × 10^(−6), respectively. The corresponding value of K_1/K_2 of 1.3 × 10^2 is not deemed large enough to provide experimental NMR evidence for a significant degree of intramolecular hydrogen bonding in D_2O. Conformational preferences of DMAPA are mostly close to statistical (gauche/trans = 2/1) in other protic solvents, e.g., alcohols. However, the un-ionized form of DMAPA appears to be strongly intramolecularly hydrogen-bonded and gauche in aprotic solvents

Cosmological test of the Yilmaz theory of gravity

We test the Yilmaz theory of gravitation by working out the corresponding Friedmann-type equations generated by assuming the Friedmann-Robertson-Walker cosmological metrics. In the case that space is flat the theory is consistent only with either a completely empty universe or a negative energy vacuum that decays to produce a constant density of matter. In both cases the total energy remains zero at all times, and in the latter case the acceleration of the expansion is always negative. To obtain a more flexible and potentially more realistic cosmology, the equation of state relating the pressure and energy density of the matter creation process must be different from the vacuum, as for example is the case in the steady-state models of Gold, Bondi, Hoyle and others. The theory does not support the cosmological principle for curved space K =/= 0 cosmological metrics

Nucleation and seismic tremor associated with the glacial earthquakes of Whillans Ice Stream, Antarctica

The ability to monitor transient motion along faults is critical to improving our ability to understand many natural phenomena such as landslides and earthquakes. Here, we usedata from a GPS and seismometer network that were deployed to monitor the regularly repeating glacial earthquakes of Whillans Ice Stream, West Antarctica to show that a unique pattern of precursory slip precedes complete rupture along the bed of the ice stream. Additionally, we show that rupture can be independently tracked by increased levels of microseismic activity, including harmonic tremor, that are coincident with the onset of slip at any location, thus providing a remote means of monitoring stress and rupture propagation during the glacial earthquakes

Regional CO2 Inversion Through Ensemble-Based Simultaneous State and Parameter Estimation: TRACE Framework and Controlled Experiments

Atmospheric inversions provide estimates of carbon dioxide (CO2) fluxes between the surface and atmosphere based on atmospheric CO2 concentration observations. The number of CO2 observations is projected to increase severalfold in the next decades from expanding in situ networks and next-generation CO2-observing satellites, providing both an opportunity and a challenge for inversions. This study introduces the TRACE Regional Atmosphere-Carbon Ensemble (TRACE) system, which employ an ensemble-based simultaneous state and parameter estimation (ESSPE) approach to enable the assimilation of large volumes of observations for constraining CO2 flux parameters. TRACE uses an online full-physics mesoscale atmospheric model and assimilates observations serially in a coupled atmosphere-carbon ensemble Kalman filter. The data assimilation system was tested in a series of observing system simulation experiments using in situ observations for a regional domain over North America in summer. Under ideal conditions with known prior flux parameter error covariances, TRACE reduced the error in domain-integrated monthly CO2 fluxes by about 97% relative to the prior flux errors. In a more realistic scenario with unknown prior flux error statistics, the corresponding relative error reductions ranged from 80.6% to 88.5% depending on the specification of prior flux parameter error correlations. For regionally integrated fluxes on a spatial scale of 10(6) km(2), the sum of absolute errors was reduced by 34.5%-50.9% relative to the prior flux errors. Moreover, TRACE produced posterior uncertainty estimates that were consistent with the true errors. These initial experiments show that the ESSPE approach in TRACE provides a promising method for advancing CO2 inversion techniques