Ion specificity and the theory of stability of colloidal suspensions

A theory is presented which allow us to accurately calculate the critical coagulation concentration (CCC) of hydrophobic colloidal suspensions. For positively charged particles the CCC's follow the Hofmeister (lyotropic) series. For negatively charged particles the series is reversed. We find that strongly polarizable chaotropic anions are driven towards the colloidal surface by electrostatic and hydrophobic forces. Within approximately one ionic radius from the surface, the chaotropic anions loose part of their hydration sheath and become strongly adsorbed. The kosmotropic anions, on the other hand, are repelled from the hydrophobic surface. The theory is quantitatively accurate without any adjustable parameters. We speculate that the same mechanism is responsible for the Hofmeister series that governs stability of protein solutions.Comment: Phys. Rev. Lett. (in press

Cultivo da soca de arroz irrigado.

A soca de arroz oferece oportunidade para aumentar a produção de grãos por unidade de área cultivada pois apresenta menor duração de crescimento que um novo cultivo. A sua importância como uma alternativa para aumentar a produção sem acrescer a área de cultivo e com menor custo de produção deve ser enfatizada.bitstream/CNPAF/19416/1/circ_40.pd

Influence of chirping the Raman lasers in an atom gravimeter: phase shifts due to the Raman light shift and to the finite speed of light

We present here an analysis of the influence of the frequency dependence of the Raman laser light shifts on the phase of a Raman-type atom gravimeter. Frequency chirps are applied to the Raman lasers in order to compensate gravity and ensure the resonance of the Raman pulses during the interferometer. We show that the change in the Raman light shift when this chirp is applied only to one of the two Raman lasers is enough to bias the gravity measurement by a fraction of $\mu$Gal ($1~\mu$Gal~=~$10^{-8}$~m/s$^2$). We also show that this effect is not compensated when averaging over the two directions of the Raman wavevector $k$. This thus constitutes a limit to the rejection efficiency of the $k$-reversal technique. Our analysis allows us to separate this effect from the effect of the finite speed of light, which we find in perfect agreement with expected values. This study highlights the benefit of chirping symmetrically the two Raman lasers

On quasiparticle lifetimes and transport in ordered and disordered metals

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Disordered two-dimensional superconductors: roles of temperature and interaction strength

We have considered the half-filled disordered attractive Hubbard model on a square lattice, in which the on-site attraction is switched off on a fraction $f$ of sites, while keeping a finite $U$ on the remaining ones. Through Quantum Monte Carlo (QMC) simulations for several values of $f$ and $U$, and for system sizes ranging from $8\times 8$ to $16\times 16$, we have calculated the configurational averages of the equal-time pair structure factor $P_s$, and, for a more restricted set of variables, the helicity modulus, $\rho_s$, as functions of temperature. Two finite-size scaling {\it ansatze} for $P_s$ have been used, one for zero-temperature and the other for finite temperatures. We have found that the system sustains superconductivity in the ground state up to a critical impurity concentration, $f_c$, which increases with $U$, at least up to U=4 (in units of the hopping energy). Also, the normalized zero-temperature gap as a function of $f$ shows a maximum near $f\sim 0.07$, for $2\lesssim U\lesssim 6$. Analyses of the helicity modulus and of the pair structure factor led to the determination of the critical temperature as a function of $f$, for $U=3,$ 4 and 6: they also show maxima near $f\sim 0.07$, with the highest $T_c$ increasing with $U$ in this range. We argue that, overall, the observed behavior results from both the breakdown of CDW-superconductivity degeneracy and the fact that free sites tend to "push" electrons towards attractive sites, the latter effect being more drastic at weak couplings.Comment: 9 two-column pages, 14 figures, RevTe