Phase Diagram and Quantum Order by Disorder in the Kitaev K1K_1-K2K_2 Honeycomb Magnet

We show that the topological Kitaev spin liquid on the honeycomb lattice is extremely fragile against the second-neighbor Kitaev coupling $K_2$, which has recently been shown to be the dominant perturbation away from the nearest-neighbor model in iridate Na$_2$IrO$_3$, and may also play a role in $\alpha$-RuCl$_3$ and Li$_2$IrO$_3$. This coupling naturally explains the zigzag ordering (without introducing unrealistically large longer-range Heisenberg exchange terms) and the special entanglement between real and spin space observed recently in Na$_2$IrO$_3$. Moreover, the minimal $K_1$-$K_2$ model that we present here holds the unique property that the classical and quantum phase diagrams and their respective order-by-disorder mechanisms are qualitatively different due to the fundamentally different symmetries of the classical and quantum counterparts.Comment: Published version (9+13 pages

Crystallographically oriented magnetic ZnFe2O4 nanoparticles synthesized by Fe implantation into ZnO

In this paper, a correlation between structural and magnetic properties of Fe implanted ZnO is presented. High fluence Fe^+ implantation into ZnO leads to the formation of superparamagnetic alpha-Fe nanoparticles. High vacuum annealing at 823 K results in the growth of alpha-Fe particles, but the annealing at 1073 K oxidized the majority of the Fe nanoparticles. After a long term annealing at 1073 K, crystallographically oriented ZnFe2O4 nanoparticles were formed inside ZnO with the orientation relationship of ZnFe2O4(111)[110]//ZnO(0001)[1120]. These ZnFe2O4 nanoparticles show a hysteretic behavior upon magnetization reversal at 5 K.Comment: 21 pages, 7 figures, accepted by J. Phys. D: Appl. Phy

Ground-state properties of the spin-1/2 antiferromagnetic Heisenberg model on the triangular lattice: A variational study based on entangled-plaquette states

We study, on the basis of the general entangled-plaquette variational ansatz, the ground-state properties of the spin-1/2 antiferromagnetic Heisenberg model on the triangular lattice. Our numerical estimates are in good agreement with available exact results and comparable, for large system sizes, to those computed via the best alternative numerical approaches, or by means of variational schemes based on specific (i.e., incorporating problem dependent terms) trial wave functions. The extrapolation to the thermodynamic limit of our results for lattices comprising up to N=324 spins yields an upper bound of the ground-state energy per site (in units of the exchange coupling) of $-0.5458(2)$ [$-0.4074(1)$ for the XX model], while the estimated infinite-lattice order parameter is $0.3178(5)$ (i.e., approximately 64% of the classical value).Comment: 8 pages, 3 tables, 2 figure

Fe-implanted ZnO: Magnetic precipitates versus dilution

Nowadays ferromagnetism is often found in potential diluted magnetic semiconductor systems. However, many authors argue that the observed ferromagnetism stems from ferromagnetic precipitates or spinodal decomposition rather than from carrier mediated magnetic impurities, as required for a diluted magnetic semiconductor. In the present paper we answer this question for Fe-implanted ZnO single crystals comprehensively. Different implantation fluences and temperatures and post-implantation annealing temperatures have been chosen in order to evaluate the structural and magnetic properties over a wide range of parameters. Three different regimes with respect to the Fe concentration and the process temperature are found: 1) Disperse Fe$^{2+}$ and Fe$^{3+}$ at low Fe concentrations and low processing temperatures, 2) FeZn$_2$O$_4$ at very high processing temperatures and 3) an intermediate regime with a co-existence of metallic Fe (Fe$^0$) and ionic Fe (Fe$^{2+}$ and Fe$^{3+}$). Ferromagnetism is only observed in the latter two cases, where inverted ZnFe$_2$O$_4$ and $\alpha$-Fe nanocrystals are the origin of the observed ferromagnetic behavior, respectively. The ionic Fe in the last case could contribute to a carrier mediated coupling. However, their separation is too large to couple ferromagnetically due to the lack of p-type carrier. For comparison investigations of Fe-implanted epitaxial ZnO thin films are presented.Comment: 14 pages, 17 figure

The spin state transition in LaCoO3_{3}; revising a revision

Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-$L_{2,3}$ edge we reveal that the spin state transition in LaCoO$_{3}$ can be well described by a low-spin ground state and a triply-degenerate high-spin first excited state. From the temperature dependence of the spectral lineshapes we find that LaCoO$_{3}$ at finite temperatures is an inhomogeneous mixed-spin-state system. Crucial is that the magnetic circular dichroism signal in the paramagnetic state carries a large orbital momentum. This directly shows that the currently accepted low-/intermediate-spin picture is at variance. Parameters derived from these spectroscopies fully explain existing magnetic susceptibility, electron spin resonance and inelastic neutron data

Anisotropic susceptibilities in the honeycomb Kitaev system α−RuCl3

The magnetic insulator α−RuCl3 is a promising candidate to realize Kitaev interactions on a quasi-two-dimensional honeycomb lattice. We perform extensive susceptibility measurements on single crystals of α−RuCl3, including angle dependence of the in-plane longitudinal and transverse susceptibilities, which reveal a unidirectional anisotropy within the honeycomb plane. By comparing the experimental results to a high-temperature expansion of a Kitaev-Heisenberg-Γ spin Hamiltonian with bond anisotropy, we find excellent agreement with the observed phase shift and periodicity of the angle-resolved susceptibilities. Within this model, we show that the pronounced difference between in-plane and out-of-plane susceptibilities as well as the finite transverse susceptibility are rooted in strong symmetric off-diagonal Γ spin exchange. The Γ couplings and relationships between other terms in the model Hamiltonian are quantified by extracting relevant Curie-Weiss intercepts from the experimental data

Anisotropic Susceptibility of La_2-xSr_xCoO_4 related to the Spin States of Cobalt

We present a study of the magnetic susceptibility of La_2-xSr_xCoO_4 single crystals in a doping range 0.3<=x<=0.8. Our data shows a pronounced magnetic anisotropy for all compounds. This anisotropy is in agreement with a low-spin ground state (S=0) of Co^3+ for x>=0.4 and a high-spin ground state (S=3/2) of Co^2+. We compare our data with a crystal-field model calculation assuming local moments and find a good description of the magnetic behavior for x>=0.5. This includes the pronounced kinks observed in the inverse magnetic susceptibility, which result from the anisotropy and low-energy excited states of Co^2+ and are not related to magnetic ordering or temperature-dependent spin-state transitions

Direct Evidence for Dominant Bond-directional Interactions in a Honeycomb Lattice Iridate Na2IrO3

Heisenberg interactions are ubiquitous in magnetic materials and have been prevailing in modeling and designing quantum magnets. Bond-directional interactions offer a novel alternative to Heisenberg exchange and provide the building blocks of the Kitaev model, which has a quantum spin liquid (QSL) as its exact ground state. Honeycomb iridates, A2IrO3 (A=Na,Li), offer potential realizations of the Kitaev model, and their reported magnetic behaviors may be interpreted within the Kitaev framework. However, the extent of their relevance to the Kitaev model remains unclear, as evidence for bond-directional interactions remains indirect or conjectural. Here, we present direct evidence for dominant bond-directional interactions in antiferromagnetic Na2IrO3 and show that they lead to strong magnetic frustration. Diffuse magnetic x-ray scattering reveals broken spin-rotational symmetry even above Neel temperature, with the three spin components exhibiting nano-scale correlations along distinct crystallographic directions. This spin-space and real-space entanglement directly manifests the bond-directional interactions, provides the missing link to Kitaev physics in honeycomb iridates, and establishes a new design strategy toward frustrated magnetism.Comment: Nature Physics, accepted (2015

Potential of Van de Ven’s (2007) concept of engaged scholarship to enhance the sustainability and appropriateness of management consultancy and university knowledge exchange projects recommendations to challenge the widespread hype of newness (Smil, 2022)

This paper will outline some emerging thoughts on the potential applicability of Van de Ven’s Engaged Scholarship concept in consultancy and knowledge exchange projects. To structure this paper the questions posed at an event titled “Putting Engaged Scholarship to Work: Projects, Partners and Progress” hosted by Ram (2019 cited by Kapasi) at Aston University will be summarised. The original definition of Engaged Scholarship offered by Van de Ven (2007) is that it is “a participative form of research for obtaining the advice and perspectives of key stakeholders (researchers, users, clients, sponsors, and practitioners) to understand a complex social problem” The commentary will be illustrated by some wider evidence drawn from industry analysis, professional bodies and academic research on Organisational Transformation and Digital Transformation Projects. These sources are frequently conducted independently where concentration on individual technical, and often siloed, aspects of consultancy and knowledge exchange project recommendations do not address the necessary breadth of understanding to improve the sustainability of such projects and therefore challenge the hype (Smil, 2022) that is associated with complex and expensive societal challenge of the typically high failure rates of Organisational Transformation and Digital Transformation investments. It is proposed by Neal et al (2023) that role frequently referred to as “Brokers, intermediaries, and boundary spanners (BIBS)” can offer a “… bridge (to) research and policy or practice and can elevate the role of evidence in decision making” (op cit)

Potential of Van de Ven’s (2007) concept of engaged scholarship to enhance the sustainability and appropriateness of management consultancy and university knowledge exchange projects recommendations to challenge the widespread hype of newness (Smil, 2022)

This paper will outline some emerging thoughts on the potential applicability of Van de Ven’s Engaged Scholarship concept in consultancy and knowledge exchange projects. To structure this paper the questions posed at an event titled “Putting Engaged Scholarship to Work: Projects, Partners and Progress” hosted by Ram (2019 cited by Kapasi) at Aston University will be summarised. The original definition of Engaged Scholarship offered by Van de Ven (2007) is that it is “a participative form of research for obtaining the advice and perspectives of key stakeholders (researchers, users, clients, sponsors, and practitioners) to understand a complex social problem” The commentary will be illustrated by some wider evidence drawn from industry analysis, professional bodies and academic research on Organisational Transformation and Digital Transformation Projects. These sources are frequently conducted independently where concentration on individual technical, and often siloed, aspects of consultancy and knowledge exchange project recommendations do not address the necessary breadth of understanding to improve the sustainability of such projects and therefore challenge the hype (Smil, 2022) that is associated with complex and expensive societal challenge of the typically high failure rates of Organisational Transformation and Digital Transformation investments. It is proposed by Neal et al (2023) that role frequently referred to as “Brokers, intermediaries, and boundary spanners (BIBS)” can offer a “… bridge (to) research and policy or practice and can elevate the role of evidence in decision making” (op cit)